(4-Chlorobenzenethiolato-S)(η⁵-cyclopentadienyl)(triphenylphosphine-P)nickel(II)

The Ni atom in [Ni(C₆H₄ClS)(C₅H₅)(C₁₈H₁₅P)] has a distorted trigonal geometry with bond angles Cp—Ni—S 132.3 (1)°, Cp—Ni—P 135.3 (5)° and P—Ni—S 92.4 (1)°, where Cp represents the centroid of the C₅H₅ ring. The bond distances Cp—Ni, Ni—S and Ni—P are 1.763 (1), 2.190 (1) and 2.144 (1) Å, respectively, close to distances in similar compounds. A structural model with disorded cyclopentadienyl ligands was used.

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