The anionic coordination polymer {K₂[Pt^II₂Ag^I₈(2,2′-bipyridine)₂(O₂CCF₃)₁₄]}_n

The trimetallic compound catena-poly[dipotassium(I) [bis­(2,2′-bipyridine)di-μ₃-trifluoro­acetato-dodeca-μ₂-trifluoro­acetato-diplatinum(II)octa­silver(I)]], K₂[Pt₂Ag₈(C₂F₃O₂)₁₄(C₁₀H₈N₂)₂], forms an extended structure in the solid state. Electrostatic inter­actions involving the K⁺ ions play a key role in the formation of the extended structure in three dimensions. The Ag^I ions form one-dimensional coordination polymers, with alternating Ag₂ and Ag₆ units linked by CF₃CO₂⁻ ligands. Pt...Pt inter­actions perpendicular to the one-dimensional polymerization axis provide another element of long-range order, and electrostatic inter­actions with K⁺ ions provide connectivity between adjacent polymeric structures.

S1. Comment

Coordination polymers are of current interest in materials science due to their potential applications as, for example, luminescent materials (Brandys & Puddephatt, 2001; Shyu et al., 2009), catalysts (Bordoloi et al., 2007) and materials for hydrogen storage (Jeon et al., 2008). Nonetheless, controlling the chemical structure of extended heterometallic networks remains a challenge. Aggregates of Ag(O₂CR) are well documented in the literature, and are known to form [Ag(O₂CR)]_n aggregates via bridging carboxylate moieties (see, for example, Karpova et al., 1999; Zhao et al., 2003; Zhao & Mak, 2005). We have recently reported the synthesis and structural characterization of several bimetallic complexes with the Ag^I:Pt^II ratio ranging from 1:1 to 3:1, in which Pt(2,2'-bipy) acts as a terminator for aggregates of Ag(O₂CCF₃) (Sun et al., 2009). Therein we have demonstrated that by controlling the stoichiometry of the reaction between Pt(2,2'-bipy)(O₂CCF₃)₂ and Ag(O₂CCF₃), bimetallic structures with well defined geometries may be synthesized reproducibly.

Notably, none of the previously reported Pt(bipy)–Ag(O₂CCF₃) bimetallic complexes form extended one- or two-dimensional structures via the carboxylate bridging ligand, due to the terminating effect of the Pt(bipy) group. Instead, they form one-dimensional extended structures via intramolecular Pt···Pt interactions. In addition, despite the use of large excesses of Ag(O₂CCF₃) relative to Pt^II, complexes with an Ag:Pt ratio greater than 3:1 were not achieved. We have since discovered the title compound, (I), with the formula K₂[Pt₂Ag₈(2,2'-bipy)₂(O₂CCF₃)₁₄], obtained serendipitously from the reaction of Pt(2,2'-bipy)(O₂CCF₃)₂ with Ag(O₂CCF₃) in the presence of KCl. We have found that the presence of K⁺ ions drastically alters the crystal structure of the coordination polymer, forming structures that are extended in three dimensions as opposed to only one. The repeat unit of (I) is illustrated in the scheme, and consists of two asymmetric units of K[PtAg₄(bipy)(O₂CCF₃)₇] related by an inversion centre.

The structure of the asymmetric unit is shown in Fig. 1, where the Pt^II centre is in a typical square-planar environment, with normal Pt—O and Pt—N bond lengths. However, the O1—Pt1—O13 and N1—Pt1—N2 bond angles [83.5 (1) and 81.0 (1)°, respectively] do show significant deviation from an ideal square-planar geometry. The Ag4···Ag4A separation distance of 2.8671 (7) Å is approximately equal to the Ag—Ag distance in metallic silver (2.889 Å; Emsley, 1991), indicative of metal–metal bonding interactions. Meanwhile, the Ag1···Ag2 and Ag2···Ag3 distances are 3.3140 (5) and 2.9702 (5) Å, respectively, and thus represent only weak interactions between these metal centres. The coordination numbers around the Ag^I centres vary considerably, with Ag1 and Ag2 in distorted tetrahedral geometries, Ag3 in a distorted trigonal–bipyramidal geometry, and Ag4 adopting a distorted trigonal-planar geometry.

In the repeat unit of the [Pt₂Ag₈(2,2'-bipy)₂(O₂CCF₃)₁₄]^2- anion of (I), six Ag^I ions and two Pt^II ions are joined together by ten carboxylate ligands, as shown in Fig. 2(a). Four of the ten carboxylate ligands adopt a µ₂,η²-bridging mode, four adopt a µ₃,η²-bridging mode and the remaining two adopt an uncommon µ₄,η²-bridging mode. This Pt₂Ag₆ unit is quite different from the neutral Pt₂Ag₆(bipy)₂(O₂CCF₃)₁₀ complex, (II), which we reported earlier (Sun et al., 2009), in terms of the Ag₆ arrangement and carboxylate coordination modes. In (II), four carboxylates act as µ₃,η²-bridging ligands while the rest are µ₂,η²-type ligands. Interestingly, the Pt₂Ag₆ unit in (I) is further linked to an Ag₂(O₂CCF₃)₂ unit via a µ₂,η²-carboxylate group that binds to Ag3 and Ag4A, forming an extended one-dimensional coordination polymer, as shown in Fig. 2(b). This extra µ₂,η²-carboxylate associated with the K⁺ cation thus allows the anionic cluster to form extended structures with a Pt:Ag ratio of 1:4.

Neighbouring polymer chains in this system are held together by two distinct interactions. First, chains stack on top of one another via attractive Pt···Pt interactions, in a similar manner to those observed previously by our group (Sun et al., 2009). The Pt···Pt separation distance in this case is 3.4804 (3) Å, which is typical of previously reported one-dimensional Pt^II chains (Du et al., 2008; Wadas et al., 2004). These interactions are shown in Fig. 3. In addition, electrostatic interactions with K⁺ ions join adjacent chains together in a direction perpendicular to the 110 plane, as shown in Fig. 4. These K⁺ ions are found in an octahedral coordination environment, depicted in Fig. 5.

In summary, we have reported a unique Pt^II–Ag^I coordination polymer supported by ^-O₂CCF₃ bridging ligands and K⁺ ions. We have also demonstrated that the presence of K⁺ ions has a significant impact on the formation of Pt^II–Ag^I heterometallic complexes. While previously reported complexes of this type form linear chains, the introduction of K⁺ causes these compounds to exhibit long-range order in three dimensions. Future avenues for research include the use of alternative cations to synthesize a wider variety of coordination polymers and metal–organic frameworks.

S2. Experimental

Pt(2,2'-bipyridine)Cl₂ (20 mg) was treated with Ag(O₂CCF₃) (42 mg) (\sim 1:4 ratio) in the presence of KCl (3.6 mg, ~1 equivalent) in CH₂Cl₂ (20 ml). The reaction mixture was stirred for 2 h at room temperature in the dark. After filtration, the yellow solution was evaporated slowly to give yellow crystals of (I) as a minor product.

S3. Refinement

The disorder associated with atoms F7, F8 and F9 was modelled as two orientations with occupancies which summed to unity, of 0.617 (7) and 0.383 (7) for parts A and B, respectively. Atoms F13, F14 and F15 were modelled similarly, with occupancies of 0.542 (7) and 0.458 (7) for parts A and B, respectively. Atoms F10, F11 and F12 were modelled as three orientations with occupancies which summed to unity, of 0.460 (9), 0.306 (7) and 0.234 (9) for F10/F11/F12 parts A, B and C, respectively. The C—F bond lengths for atom F10–F15 were restrained to 1.330 (5) Å to stabilize the refinement, and F atoms from all three disordered –CF₃ groups were each constrained to common displacement parameters. F···F distances in these cases were further modelled using distance restraints [SADI, FLAT (SHELXL97; Sheldrick, 2008)] as necessary. All H atoms were assigned to geometrically idealized positions with C—H bond lengths of 0.93 Å, and were constrained to ride on their parent C atoms with U_iso(H) = 1.2U_eq(C).

Computing details

Data collection: SMART (Bruker, 2007); cell refinement: SMART (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008) and Mercury (Macrae et al., 2006); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures

	Fig. 1. The asymmetric unit of (I), with the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level at ca 296 K and H atoms are shown as small spheres of arbitrary radii. The minor components of the disordered F atoms have been omitted.
	Fig. 2. (a) The structure of the Pt2Ag6 cluster. (b) The Ag2(O2CCF3)2 bridge. F atoms have been omitted for clarity. Pt and Ag atoms are depicted as small spheres. Thin lines denote intermetallic interactions. Primed atoms are generated by the symmetry operator (?, ?, ?) [Please check and complete]
	Fig. 3. The extended structure of (I), showing the Pt···Pt interactions, projected in the 110 plane. Pt and Ag atoms are depicted as small spheres. F atoms have been omitted.
	Fig. 4. Packing diagram showing the coordination polymer structure of (I), with K^+ ions shown as small spheres. F atoms have been omitted.
	Fig. 5. The coordination environment of the K^+ ion, depicted as a small sphere. Interactions with six nearby O2CCF3 groups are shown.

catena-poly[dipotassium(I) [bis(2,2'-bipyridine)di-µ₃-trifluoroacetato-dodeca-µ₂-trifluoroacetato-diplatinum(II)octasilver(I)]]

Crystal data

K2[Pt2Ag8(C10H8N2)2(C2F3O2)14]	Z = 1
Mr = 3225.98	F(000) = 1504
Triclinic, P1	Dx = 2.705 Mg m^−3
a = 11.9829 (6) Å	Mo Kα radiation, λ = 0.71073 Å
b = 12.4737 (6) Å	Cell parameters from 9980 reflections
c = 14.4368 (7) Å	θ = 2.4–27.9°
α = 77.378 (1)°	µ = 5.73 mm^−1
β = 70.132 (1)°	T = 296 K
γ = 86.305 (1)°	Block, yellow
V = 1980.28 (17) Å^3	0.10 × 0.10 × 0.05 mm

Data collection

Bruker SMART CCD area-detector diffractometer	7748 independent reflections
Radiation source: sealed tube	7189 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.018
ϕ and ω scans	θmax = 26.0°, θmin = 1.5°
Absorption correction: multi-scan (SADABS; Bruker, 2008)	h = −14→14
Tmin = 0.598, Tmax = 0.763	k = −15→15
20732 measured reflections	l = −17→17

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.024	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.058	H-atom parameters constrained
S = 1.03	w = 1/[σ^2(Fo^2) + (0.0247P)^2 + 5.4864P] where P = (Fo^2 + 2Fc^2)/3
7748 reflections	(Δ/σ)max = 0.011
609 parameters	Δρmax = 0.97 e Å^−3
112 restraints	Δρmin = −1.24 e Å^−3

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Pt1	0.508344 (14)	0.462548 (13)	0.120846 (12)	0.02291 (5)
K1	0.71700 (8)	0.09964 (8)	0.32322 (7)	0.0294 (2)
Ag1	0.50746 (3)	0.33688 (3)	0.31804 (3)	0.03095 (8)
Ag2	0.45421 (3)	0.16602 (3)	0.53951 (3)	0.03641 (9)
Ag3	0.40367 (3)	0.38620 (3)	0.59063 (3)	0.03883 (9)
Ag4	0.11801 (3)	−0.04212 (3)	0.48116 (3)	0.03432 (9)
C1	0.4210 (5)	0.6544 (4)	0.2127 (4)	0.0364 (11)
H1A	0.5005	0.6706	0.1989	0.044*
C2	0.3344 (5)	0.7209 (4)	0.2613 (4)	0.0453 (13)
H2A	0.3555	0.7805	0.2812	0.054*
C3	0.2178 (5)	0.6991 (4)	0.2800 (4)	0.0420 (12)
H3A	0.1590	0.7443	0.3115	0.050*
C4	0.1881 (4)	0.6096 (4)	0.2517 (4)	0.0358 (11)
H4A	0.1089	0.5935	0.2643	0.043*
C5	0.2765 (4)	0.5437 (4)	0.2044 (3)	0.0274 (9)
C6	0.2584 (4)	0.4466 (4)	0.1694 (3)	0.0276 (9)
C7	0.1491 (4)	0.4064 (4)	0.1790 (4)	0.0372 (11)
H7A	0.0797	0.4415	0.2095	0.045*
C8	0.1442 (5)	0.3148 (5)	0.1431 (4)	0.0447 (13)
H8A	0.0713	0.2864	0.1498	0.054*
C9	0.2478 (5)	0.2646 (4)	0.0970 (4)	0.0406 (12)
H9A	0.2455	0.2025	0.0718	0.049*
C10	0.3550 (4)	0.3075 (4)	0.0887 (3)	0.0306 (10)
H10A	0.4251	0.2740	0.0571	0.037*
C11	0.7974 (5)	0.2539 (5)	0.0205 (4)	0.0486 (14)
C12	0.6888 (4)	0.2978 (4)	0.0955 (3)	0.0297 (10)
C13	0.3730 (5)	0.0708 (4)	0.2911 (4)	0.0378 (11)
C14	0.3921 (4)	0.0600 (4)	0.3928 (3)	0.0280 (9)
C15	0.1169 (4)	0.3183 (3)	0.4796 (3)	0.0383 (11)
C16	0.2513 (4)	0.3222 (4)	0.4586 (4)	0.0310 (10)
C17	−0.0114 (4)	0.0384 (3)	0.7861 (4)	0.0491 (14)
C18	−0.0074 (4)	0.0223 (4)	0.6826 (4)	0.0334 (10)
C19	0.3244 (4)	0.0900 (4)	0.8708 (4)	0.0554 (16)
C20	0.3595 (4)	0.1486 (4)	0.7593 (4)	0.0357 (11)
C21	0.8005 (4)	0.3563 (4)	0.4246 (4)	0.0353 (11)
C22	0.6650 (4)	0.3463 (4)	0.4570 (3)	0.0269 (9)
C23	0.8241 (4)	0.5726 (5)	0.1532 (4)	0.0409 (12)
C24	0.6953 (4)	0.5311 (4)	0.1865 (4)	0.0302 (10)
N1	0.3926 (3)	0.5676 (3)	0.1853 (3)	0.0259 (8)
N2	0.3602 (3)	0.3960 (3)	0.1250 (3)	0.0249 (7)
O1	0.6232 (3)	0.3549 (3)	0.0505 (2)	0.0309 (7)
O2	0.6786 (3)	0.2775 (3)	0.1848 (2)	0.0324 (7)
O3	0.4766 (3)	0.1142 (3)	0.3910 (2)	0.0333 (7)
O4	0.3205 (3)	−0.0008 (3)	0.4652 (3)	0.0444 (9)
O5	0.3101 (3)	0.3469 (3)	0.3685 (3)	0.0499 (10)
O6	0.2820 (3)	0.2963 (3)	0.5336 (3)	0.0454 (9)
O7	0.0758 (3)	−0.0349 (3)	0.6416 (3)	0.0401 (8)
O8	−0.0877 (3)	0.0675 (3)	0.6532 (2)	0.0359 (8)
O9	0.3728 (4)	0.0859 (3)	0.7002 (3)	0.0454 (9)
O10	0.3731 (3)	0.2486 (3)	0.7426 (3)	0.0429 (9)
O11	0.6306 (3)	0.2661 (3)	0.4343 (2)	0.0318 (7)
O12	0.6067 (3)	0.4149 (3)	0.5036 (2)	0.0332 (7)
O13	0.6597 (3)	0.5364 (3)	0.1117 (2)	0.0308 (7)
O14	0.6440 (3)	0.4944 (3)	0.2755 (2)	0.0334 (7)
F1	0.8703 (3)	0.3362 (3)	−0.0368 (3)	0.0692 (11)
F2	0.8565 (4)	0.1821 (4)	0.0679 (3)	0.0849 (14)
F3	0.7661 (3)	0.2044 (3)	−0.0397 (2)	0.0631 (10)
F4	0.4565 (3)	0.1324 (3)	0.2148 (2)	0.0546 (8)
F5	0.2691 (3)	0.1174 (3)	0.2945 (3)	0.0567 (9)
F6	0.3717 (4)	−0.0255 (3)	0.2677 (3)	0.0633 (10)
F7B	0.0821 (9)	0.2171 (5)	0.4859 (8)	0.0581 (10)	0.383 (7)
F8B	0.0545 (8)	0.3464 (8)	0.5667 (5)	0.0581 (10)	0.383 (7)
F9B	0.0806 (9)	0.3859 (7)	0.4107 (6)	0.0581 (10)	0.383 (7)
F7A	0.0902 (5)	0.2382 (4)	0.4422 (5)	0.0581 (10)	0.62
F8A	0.0522 (5)	0.2993 (5)	0.5765 (3)	0.0581 (10)	0.62
F9A	0.0800 (6)	0.4128 (4)	0.4365 (5)	0.0581 (10)	0.62
F10A	0.0838 (8)	0.0011 (10)	0.8108 (7)	0.0623 (13)	0.460 (9)
F11A	−0.0153 (11)	0.1460 (4)	0.7871 (6)	0.0623 (13)	0.460 (9)
F12A	−0.1102 (7)	−0.0031 (9)	0.8583 (5)	0.0623 (13)	0.460 (9)
F10B	0.1004 (6)	0.0386 (11)	0.7888 (9)	0.0623 (13)	0.306 (8)
F11B	−0.0558 (12)	0.1303 (8)	0.8137 (9)	0.0623 (13)	0.306 (8)
F12B	−0.0592 (12)	−0.0494 (7)	0.8577 (6)	0.0623 (13)	0.306 (8)
F10C	0.0326 (18)	−0.0455 (11)	0.8353 (10)	0.0623 (13)	0.234 (9)
F11C	0.0293 (15)	0.1363 (8)	0.7805 (10)	0.0623 (13)	0.234 (9)
F12C	−0.1270 (6)	0.0424 (17)	0.8429 (10)	0.0623 (13)	0.234 (9)
F13B	0.3643 (8)	−0.0125 (5)	0.8879 (6)	0.0692 (12)	0.458 (7)
F14B	0.3815 (8)	0.1445 (6)	0.9136 (7)	0.0692 (12)	0.458 (7)
F15B	0.2127 (6)	0.0941 (7)	0.9279 (7)	0.0692 (12)	0.458 (7)
F13A	0.3060 (8)	−0.0178 (4)	0.8807 (5)	0.0692 (12)	0.54
F14A	0.3965 (7)	0.1056 (6)	0.9176 (6)	0.0692 (12)	0.54
F15A	0.2151 (5)	0.1245 (6)	0.9160 (6)	0.0692 (12)	0.54
F16	0.8556 (3)	0.3324 (3)	0.3356 (3)	0.0653 (10)
F17	0.8387 (3)	0.2843 (3)	0.4909 (3)	0.0541 (8)
F18	0.8387 (3)	0.4544 (3)	0.4208 (3)	0.0624 (10)
F19	0.8969 (3)	0.4935 (3)	0.1213 (3)	0.0719 (11)
F20	0.8508 (3)	0.5955 (3)	0.2279 (3)	0.0626 (10)
F21	0.8486 (3)	0.6605 (3)	0.0799 (3)	0.0635 (10)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pt1	0.02069 (8)	0.02421 (9)	0.02130 (8)	0.00181 (6)	−0.00703 (6)	−0.00005 (6)
K1	0.0294 (5)	0.0276 (5)	0.0322 (5)	0.0048 (4)	−0.0126 (4)	−0.0058 (4)
Ag1	0.02294 (16)	0.03481 (19)	0.02878 (17)	−0.00196 (13)	−0.00763 (13)	0.00529 (14)
Ag2	0.0409 (2)	0.0391 (2)	0.02886 (18)	−0.00081 (16)	−0.00902 (15)	−0.01014 (15)
Ag3	0.0392 (2)	0.0329 (2)	0.0426 (2)	−0.00174 (16)	−0.01206 (17)	−0.00598 (16)
Ag4	0.02935 (18)	0.0429 (2)	0.03540 (19)	0.00666 (15)	−0.01387 (15)	−0.01473 (16)
C1	0.038 (3)	0.026 (2)	0.047 (3)	0.000 (2)	−0.018 (2)	−0.005 (2)
C2	0.055 (3)	0.031 (3)	0.054 (3)	0.007 (2)	−0.020 (3)	−0.017 (2)
C3	0.050 (3)	0.035 (3)	0.041 (3)	0.019 (2)	−0.014 (2)	−0.014 (2)
C4	0.029 (2)	0.040 (3)	0.035 (3)	0.009 (2)	−0.009 (2)	−0.005 (2)
C5	0.028 (2)	0.031 (2)	0.023 (2)	0.0040 (18)	−0.0120 (18)	−0.0007 (18)
C6	0.026 (2)	0.031 (2)	0.024 (2)	0.0019 (18)	−0.0104 (18)	−0.0001 (18)
C7	0.029 (2)	0.045 (3)	0.037 (3)	−0.005 (2)	−0.014 (2)	−0.003 (2)
C8	0.037 (3)	0.055 (3)	0.047 (3)	−0.008 (2)	−0.023 (2)	−0.005 (3)
C9	0.058 (3)	0.036 (3)	0.035 (3)	−0.007 (2)	−0.026 (2)	−0.005 (2)
C10	0.040 (3)	0.027 (2)	0.025 (2)	0.0008 (19)	−0.013 (2)	−0.0017 (18)
C11	0.048 (3)	0.050 (3)	0.035 (3)	0.024 (3)	−0.007 (2)	−0.001 (3)
C12	0.027 (2)	0.027 (2)	0.029 (2)	−0.0002 (18)	−0.0044 (19)	0.0001 (18)
C13	0.044 (3)	0.036 (3)	0.035 (3)	−0.008 (2)	−0.018 (2)	−0.002 (2)
C14	0.028 (2)	0.026 (2)	0.031 (2)	0.0051 (18)	−0.0133 (19)	−0.0055 (18)
C15	0.030 (2)	0.041 (3)	0.037 (3)	−0.002 (2)	−0.005 (2)	−0.003 (2)
C16	0.030 (2)	0.027 (2)	0.037 (3)	−0.0005 (19)	−0.014 (2)	−0.0039 (19)
C17	0.056 (3)	0.053 (3)	0.038 (3)	0.028 (3)	−0.017 (3)	−0.015 (3)
C18	0.035 (3)	0.033 (2)	0.032 (2)	0.004 (2)	−0.011 (2)	−0.006 (2)
C19	0.082 (5)	0.037 (3)	0.036 (3)	−0.006 (3)	−0.001 (3)	−0.012 (2)
C20	0.043 (3)	0.034 (3)	0.031 (2)	−0.003 (2)	−0.012 (2)	−0.007 (2)
C21	0.028 (2)	0.036 (3)	0.040 (3)	0.003 (2)	−0.011 (2)	−0.007 (2)
C22	0.027 (2)	0.027 (2)	0.026 (2)	−0.0008 (18)	−0.0124 (18)	0.0023 (18)
C23	0.028 (2)	0.054 (3)	0.039 (3)	−0.011 (2)	−0.016 (2)	0.005 (2)
C24	0.028 (2)	0.023 (2)	0.037 (3)	−0.0013 (18)	−0.012 (2)	0.0008 (19)
N1	0.0266 (18)	0.0249 (18)	0.0256 (18)	0.0033 (15)	−0.0107 (15)	−0.0021 (15)
N2	0.0256 (18)	0.0276 (19)	0.0194 (17)	−0.0001 (15)	−0.0081 (14)	0.0004 (14)
O1	0.0280 (16)	0.0364 (18)	0.0259 (16)	0.0104 (13)	−0.0095 (13)	−0.0036 (13)
O2	0.0335 (17)	0.0319 (17)	0.0283 (17)	0.0065 (14)	−0.0102 (14)	−0.0010 (13)
O3	0.0309 (17)	0.0386 (18)	0.0335 (17)	−0.0029 (14)	−0.0111 (14)	−0.0120 (14)
O4	0.0366 (19)	0.058 (2)	0.0352 (19)	−0.0107 (17)	−0.0165 (16)	0.0068 (17)
O5	0.0274 (18)	0.073 (3)	0.039 (2)	0.0029 (17)	−0.0082 (16)	0.0047 (19)
O6	0.050 (2)	0.047 (2)	0.047 (2)	0.0044 (17)	−0.0269 (18)	−0.0088 (17)
O7	0.0387 (19)	0.051 (2)	0.0352 (18)	0.0203 (17)	−0.0163 (15)	−0.0184 (16)
O8	0.0328 (17)	0.0426 (19)	0.0363 (18)	0.0130 (15)	−0.0137 (15)	−0.0164 (15)
O9	0.066 (2)	0.0370 (19)	0.0316 (18)	−0.0085 (17)	−0.0092 (17)	−0.0125 (15)
O10	0.064 (2)	0.0292 (18)	0.0376 (19)	−0.0118 (16)	−0.0207 (18)	−0.0017 (15)
O11	0.0334 (17)	0.0272 (16)	0.0357 (18)	−0.0002 (13)	−0.0119 (14)	−0.0078 (14)
O12	0.0315 (17)	0.0300 (17)	0.0366 (18)	0.0046 (14)	−0.0081 (14)	−0.0102 (14)
O13	0.0248 (15)	0.0373 (18)	0.0273 (16)	−0.0042 (13)	−0.0097 (13)	0.0025 (13)
O14	0.0367 (18)	0.0313 (17)	0.0299 (17)	−0.0090 (14)	−0.0115 (14)	0.0018 (14)
F1	0.0355 (18)	0.080 (3)	0.064 (2)	0.0046 (17)	0.0084 (16)	−0.001 (2)
F2	0.082 (3)	0.097 (3)	0.061 (2)	0.068 (2)	−0.021 (2)	−0.011 (2)
F3	0.085 (3)	0.055 (2)	0.0394 (18)	0.0247 (19)	−0.0071 (17)	−0.0181 (16)
F4	0.061 (2)	0.066 (2)	0.0328 (16)	−0.0203 (17)	−0.0163 (15)	0.0063 (15)
F5	0.054 (2)	0.067 (2)	0.054 (2)	0.0038 (16)	−0.0371 (17)	0.0065 (17)
F6	0.094 (3)	0.050 (2)	0.059 (2)	−0.0105 (19)	−0.034 (2)	−0.0236 (17)
F7B	0.0400 (13)	0.059 (2)	0.067 (2)	−0.0038 (14)	−0.0103 (14)	−0.0076 (15)
F8B	0.0400 (13)	0.059 (2)	0.067 (2)	−0.0038 (14)	−0.0103 (14)	−0.0076 (15)
F9B	0.0400 (13)	0.059 (2)	0.067 (2)	−0.0038 (14)	−0.0103 (14)	−0.0076 (15)
F7A	0.0400 (13)	0.059 (2)	0.067 (2)	−0.0038 (14)	−0.0103 (14)	−0.0076 (15)
F8A	0.0400 (13)	0.059 (2)	0.067 (2)	−0.0038 (14)	−0.0103 (14)	−0.0076 (15)
F9A	0.0400 (13)	0.059 (2)	0.067 (2)	−0.0038 (14)	−0.0103 (14)	−0.0076 (15)
F10A	0.069 (3)	0.082 (3)	0.043 (2)	0.030 (2)	−0.025 (2)	−0.0246 (19)
F11A	0.069 (3)	0.082 (3)	0.043 (2)	0.030 (2)	−0.025 (2)	−0.0246 (19)
F12A	0.069 (3)	0.082 (3)	0.043 (2)	0.030 (2)	−0.025 (2)	−0.0246 (19)
F10B	0.069 (3)	0.082 (3)	0.043 (2)	0.030 (2)	−0.025 (2)	−0.0246 (19)
F11B	0.069 (3)	0.082 (3)	0.043 (2)	0.030 (2)	−0.025 (2)	−0.0246 (19)
F12B	0.069 (3)	0.082 (3)	0.043 (2)	0.030 (2)	−0.025 (2)	−0.0246 (19)
F10C	0.069 (3)	0.082 (3)	0.043 (2)	0.030 (2)	−0.025 (2)	−0.0246 (19)
F11C	0.069 (3)	0.082 (3)	0.043 (2)	0.030 (2)	−0.025 (2)	−0.0246 (19)
F12C	0.069 (3)	0.082 (3)	0.043 (2)	0.030 (2)	−0.025 (2)	−0.0246 (19)
F13B	0.100 (2)	0.055 (2)	0.0388 (15)	−0.0058 (18)	−0.0148 (15)	0.0073 (15)
F14B	0.100 (2)	0.055 (2)	0.0388 (15)	−0.0058 (18)	−0.0148 (15)	0.0073 (15)
F15B	0.100 (2)	0.055 (2)	0.0388 (15)	−0.0058 (18)	−0.0148 (15)	0.0073 (15)
F13A	0.100 (2)	0.055 (2)	0.0388 (15)	−0.0058 (18)	−0.0148 (15)	0.0073 (15)
F14A	0.100 (2)	0.055 (2)	0.0388 (15)	−0.0058 (18)	−0.0148 (15)	0.0073 (15)
F15A	0.100 (2)	0.055 (2)	0.0388 (15)	−0.0058 (18)	−0.0148 (15)	0.0073 (15)
F16	0.0357 (17)	0.102 (3)	0.050 (2)	0.0014 (18)	0.0008 (15)	−0.023 (2)
F17	0.0382 (17)	0.059 (2)	0.065 (2)	0.0098 (15)	−0.0288 (16)	0.0025 (17)
F18	0.0377 (17)	0.0452 (19)	0.105 (3)	−0.0101 (14)	−0.0281 (19)	−0.0073 (19)
F19	0.0286 (17)	0.083 (3)	0.100 (3)	0.0053 (17)	−0.0149 (18)	−0.024 (2)
F20	0.054 (2)	0.086 (3)	0.054 (2)	−0.0278 (18)	−0.0305 (17)	0.0004 (18)
F21	0.0496 (19)	0.076 (2)	0.055 (2)	−0.0338 (18)	−0.0228 (16)	0.0268 (18)

Geometric parameters (Å, º)

Pt1—N1	1.982 (4)	C12—O1	1.272 (5)
Pt1—N2	1.985 (4)	C13—F6	1.320 (6)
Pt1—O1	2.034 (3)	C13—F5	1.330 (6)
Pt1—O13	2.038 (3)	C13—F4	1.336 (6)
Pt1—Ag1	2.9315 (4)	C13—C14	1.538 (6)
K1—O2	2.772 (3)	C14—O4	1.238 (6)
K1—O3	2.718 (3)	C14—O3	1.243 (5)
K1—O4^i	2.923 (4)	C15—F8A	1.325 (4)
K1—O7^i	2.738 (3)	C15—F7B	1.330 (5)
K1—O9^i	2.745 (4)	C15—F9A	1.331 (4)
K1—O11	2.829 (3)	C15—F9B	1.331 (5)
K1—F10A^i	2.926 (7)	C15—F8B	1.334 (5)
K1—F10B^i	2.950 (11)	C15—F7A	1.337 (4)
K1—F10C^i	3.232 (17)	C15—C16	1.536 (6)
Ag1—O5	2.230 (3)	C16—O5	1.230 (6)
Ag1—O14	2.474 (3)	C16—O6	1.231 (6)
Ag1—O2	2.490 (3)	C17—F11B	1.316 (5)
Ag1—O11	2.578 (3)	C17—F10C	1.318 (5)
Ag1—Ag2	3.3140 (5)	C17—F11C	1.321 (5)
Ag2—O9	2.215 (3)	C17—F12A	1.326 (5)
Ag2—O3	2.298 (3)	C17—F12B	1.334 (5)
Ag2—O11	2.379 (3)	C17—F10A	1.334 (5)
Ag2—O6	2.556 (4)	C17—F11A	1.343 (5)
Ag2—Ag3	2.9702 (5)	C17—F12C	1.352 (5)
Ag3—O12	2.337 (3)	C17—F10B	1.354 (5)
Ag3—O6	2.344 (4)	C17—C18	1.535 (7)
Ag3—O10	2.405 (3)	C18—O8	1.235 (5)
Ag3—O12^ii	2.573 (3)	C18—O7	1.244 (6)
Ag3—O14^ii	2.584 (3)	C19—F14A	1.310 (5)
Ag4—O8^iii	2.181 (3)	C19—F15B	1.317 (5)
Ag4—O7	2.218 (3)	C19—F13B	1.337 (5)
Ag4—O4	2.436 (3)	C19—F15A	1.340 (5)
Ag4—Ag4^iii	2.8671 (7)	C19—F13A	1.345 (5)
C1—N1	1.331 (6)	C19—F14B	1.357 (5)
C1—C2	1.381 (7)	C19—C20	1.539 (7)
C1—H1A	0.9300	C20—O10	1.228 (6)
C2—C3	1.363 (8)	C20—O9	1.245 (6)
C2—H2A	0.9300	C21—F18	1.317 (6)
C3—C4	1.375 (7)	C21—F16	1.318 (6)
C3—H3A	0.9300	C21—F17	1.342 (6)
C4—C5	1.380 (6)	C21—C22	1.534 (6)
C4—H4A	0.9300	C22—O12	1.236 (5)
C5—N1	1.363 (6)	C22—O11	1.252 (5)
C5—C6	1.465 (6)	C23—F21	1.316 (6)
C6—N2	1.357 (6)	C23—F20	1.316 (6)
C6—C7	1.385 (6)	C23—F19	1.328 (7)
C7—C8	1.366 (8)	C23—C24	1.540 (6)
C7—H7A	0.9300	C24—O14	1.217 (5)
C8—C9	1.377 (8)	C24—O13	1.277 (5)
C8—H8A	0.9300	O4—K1^i	2.923 (4)
C9—C10	1.381 (7)	O7—K1^i	2.738 (3)
C9—H9A	0.9300	O8—Ag4^iii	2.181 (3)
C10—N2	1.336 (6)	O9—K1^i	2.745 (4)
C10—H10A	0.9300	O12—Ag3^ii	2.573 (3)
C11—F2	1.324 (6)	O14—Ag3^ii	2.584 (3)
C11—F1	1.325 (7)	F10A—K1^i	2.926 (7)
C11—F3	1.327 (7)	F10B—K1^i	2.950 (11)
C11—C12	1.541 (7)	F10C—K1^i	3.232 (17)
C12—O2	1.223 (5)
N1—Pt1—N2	81.04 (15)	C9—C8—H8A	120.2
N1—Pt1—O1	177.55 (13)	C8—C9—C10	119.2 (5)
N2—Pt1—O1	97.16 (14)	C8—C9—H9A	120.4
N1—Pt1—O13	98.17 (14)	C10—C9—H9A	120.4
N2—Pt1—O13	177.49 (13)	N2—C10—C9	121.4 (5)
O1—Pt1—O13	83.56 (13)	N2—C10—H10A	119.3
N1—Pt1—Ag1	90.97 (10)	C9—C10—H10A	119.3
N2—Pt1—Ag1	95.74 (10)	F2—C11—F1	108.3 (5)
O1—Pt1—Ag1	90.87 (8)	F2—C11—F3	107.7 (5)
O13—Pt1—Ag1	86.64 (8)	F1—C11—F3	107.8 (5)
O3—K1—O7^i	150.09 (11)	F2—C11—C12	111.4 (4)
O3—K1—O9^i	72.60 (11)	F1—C11—C12	109.9 (5)
O7^i—K1—O9^i	105.10 (12)	F3—C11—C12	111.7 (5)
O3—K1—O2	78.09 (10)	O2—C12—O1	129.8 (4)
O7^i—K1—O2	128.61 (11)	O2—C12—C11	118.9 (4)
O9^i—K1—O2	108.54 (11)	O1—C12—C11	111.3 (4)
O3—K1—O11	66.03 (9)	F6—C13—F5	106.9 (4)
O7^i—K1—O11	104.37 (10)	F6—C13—F4	107.2 (4)
O9^i—K1—O11	136.71 (11)	F5—C13—F4	107.3 (4)
O2—K1—O11	75.30 (9)	F6—C13—C14	112.1 (4)
O3—K1—O4^i	82.77 (10)	F5—C13—C14	110.2 (4)
O7^i—K1—O4^i	67.36 (10)	F4—C13—C14	112.8 (4)
O9^i—K1—O4^i	90.44 (11)	O4—C14—O3	129.1 (4)
O2—K1—O4^i	147.23 (11)	O4—C14—C13	115.4 (4)
O11—K1—O4^i	72.68 (11)	O3—C14—C13	115.5 (4)
O3—K1—F10A^i	143.6 (2)	F8A—C15—F7B	83.3 (5)
O7^i—K1—F10A^i	54.81 (14)	F8A—C15—F9A	106.9 (5)
O9^i—K1—F10A^i	73.9 (3)	F7B—C15—F9A	127.9 (6)
O2—K1—F10A^i	99.6 (2)	F8A—C15—F9B	121.7 (7)
O11—K1—F10A^i	149.3 (3)	F7B—C15—F9B	107.8 (6)
O4^i—K1—F10A^i	111.47 (19)	F7B—C15—F8B	106.6 (6)
O3—K1—F10B^i	138.2 (2)	F9A—C15—F8B	85.5 (5)
O7^i—K1—F10B^i	54.23 (18)	F9B—C15—F8B	105.0 (6)
O9^i—K1—F10B^i	66.3 (2)	F8A—C15—F7A	106.5 (4)
O2—K1—F10B^i	107.8 (3)	F9A—C15—F7A	108.0 (5)
O11—K1—F10B^i	155.70 (19)	F9B—C15—F7A	85.1 (5)
O4^i—K1—F10B^i	104.2 (2)	F8B—C15—F7A	126.6 (6)
F10A^i—K1—F10B^i	10.0 (3)	F8A—C15—C16	114.3 (4)
O3—K1—F10C^i	153.3 (3)	F7B—C15—C16	110.5 (5)
O7^i—K1—F10C^i	51.7 (2)	F9A—C15—C16	110.8 (4)
O9^i—K1—F10C^i	87.4 (4)	F9B—C15—C16	114.2 (6)
O2—K1—F10C^i	92.24 (16)	F8B—C15—C16	112.4 (6)
O11—K1—F10C^i	135.9 (4)	F7A—C15—C16	110.1 (4)
O4^i—K1—F10C^i	115.69 (15)	O5—C16—O6	131.1 (5)
O3—K1—Ag1	46.86 (7)	O5—C16—C15	113.7 (4)
O7^i—K1—Ag1	142.91 (8)	O6—C16—C15	115.1 (4)
O9^i—K1—Ag1	111.70 (9)	F11B—C17—F10C	129.1 (9)
O2—K1—Ag1	41.46 (6)	F10C—C17—F11C	115.9 (8)
O11—K1—Ag1	43.25 (6)	F11B—C17—F12A	81.8 (7)
O4^i—K1—Ag1	107.11 (8)	F10C—C17—F12A	80.1 (8)
F10A^i—K1—Ag1	141.0 (2)	F11C—C17—F12A	121.3 (8)
F10B^i—K1—Ag1	148.6 (2)	F11B—C17—F12B	111.6 (7)
F10C^i—K1—Ag1	132.89 (17)	F10C—C17—F12B	46.0 (9)
O3—K1—Ag2^i	63.55 (7)	F11C—C17—F12B	137.5 (9)
O7^i—K1—Ag2^i	96.84 (8)	F11B—C17—F10A	115.6 (8)
O9^i—K1—Ag2^i	35.25 (7)	F11C—C17—F10A	84.6 (8)
O2—K1—Ag2^i	132.33 (7)	F12A—C17—F10A	110.8 (5)
O11—K1—Ag2^i	110.24 (7)	F12B—C17—F10A	80.2 (7)
O4^i—K1—Ag2^i	56.33 (7)	F10C—C17—F11A	131.6 (8)
F10A^i—K1—Ag2^i	95.7 (3)	F12A—C17—F11A	104.4 (5)
F10B^i—K1—Ag2^i	85.9 (2)	F12B—C17—F11A	131.8 (7)
F10C^i—K1—Ag2^i	109.2 (3)	F10A—C17—F11A	105.1 (6)
Ag1—K1—Ag2^i	110.38 (3)	F11B—C17—F12C	60.0 (9)
O3—K1—Ag2	36.72 (7)	F10C—C17—F12C	105.4 (8)
O7^i—K1—Ag2	118.53 (8)	F11C—C17—F12C	102.9 (7)
O9^i—K1—Ag2	98.76 (8)	F12B—C17—F12C	61.9 (9)
O2—K1—Ag2	93.41 (7)	F10A—C17—F12C	131.5 (8)
O11—K1—Ag2	38.65 (6)	F11A—C17—F12C	82.3 (8)
O4^i—K1—Ag2	56.57 (8)	F11B—C17—F10B	103.3 (7)
F10A^i—K1—Ag2	166.6 (2)	F10C—C17—F10B	57.3 (11)
F10B^i—K1—Ag2	156.9 (3)	F11C—C17—F10B	65.5 (10)
F10C^i—K1—Ag2	169.9 (3)	F12A—C17—F10B	129.3 (7)
Ag1—K1—Ag2	51.970 (15)	F12B—C17—F10B	101.8 (7)
Ag2^i—K1—Ag2	72.78 (2)	F11A—C17—F10B	87.6 (8)
O5—Ag1—O14	124.99 (14)	F12C—C17—F10B	143.1 (9)
O5—Ag1—O2	141.28 (13)	F11B—C17—C18	118.2 (6)
O14—Ag1—O2	80.29 (11)	F10C—C17—C18	112.8 (7)
O5—Ag1—O11	125.17 (12)	F11C—C17—C18	111.6 (7)
O14—Ag1—O11	79.09 (10)	F12A—C17—C18	111.8 (5)
O2—Ag1—O11	84.91 (10)	F12B—C17—C18	110.8 (6)
O5—Ag1—Pt1	87.19 (9)	F10A—C17—C18	114.2 (5)
O14—Ag1—Pt1	74.04 (7)	F11A—C17—C18	109.9 (5)
O2—Ag1—Pt1	71.18 (7)	F12C—C17—C18	107.3 (7)
O11—Ag1—Pt1	146.44 (7)	F10B—C17—C18	109.5 (6)
O5—Ag1—Ag2	82.91 (9)	O8—C18—O7	129.9 (5)
O14—Ag1—Ag2	118.65 (7)	O8—C18—C17	115.2 (4)
O2—Ag1—Ag2	112.13 (7)	O7—C18—C17	114.9 (4)
O11—Ag1—Ag2	45.55 (7)	F14A—C19—F15B	111.3 (9)
Pt1—Ag1—Ag2	167.005 (15)	F14A—C19—F13B	81.2 (6)
O5—Ag1—K1	132.74 (11)	F15B—C19—F13B	109.8 (6)
O14—Ag1—K1	101.17 (8)	F14A—C19—F15A	110.6 (6)
O2—Ag1—K1	47.48 (7)	F13B—C19—F15A	126.2 (6)
O11—Ag1—K1	48.75 (7)	F14A—C19—F13A	111.1 (5)
Pt1—Ag1—K1	117.771 (19)	F15B—C19—F13A	87.0 (6)
Ag2—Ag1—K1	64.676 (17)	F15A—C19—F13A	102.2 (5)
O9—Ag2—O3	133.48 (12)	F15B—C19—F14B	102.5 (7)
O9—Ag2—O11	137.93 (13)	F13B—C19—F14B	102.9 (6)
O3—Ag2—O11	80.53 (11)	F15A—C19—F14B	96.5 (7)
O9—Ag2—O6	95.43 (13)	F13A—C19—F14B	131.9 (6)
O3—Ag2—O6	95.45 (12)	F14A—C19—C20	115.6 (5)
O11—Ag2—O6	106.31 (12)	F15B—C19—C20	117.9 (6)
O9—Ag2—Ag3	90.59 (9)	F13B—C19—C20	115.4 (5)
O3—Ag2—Ag3	129.37 (8)	F15A—C19—C20	106.1 (5)
O11—Ag2—Ag3	77.88 (8)	F13A—C19—C20	110.3 (4)
O6—Ag2—Ag3	49.50 (8)	F14B—C19—C20	106.3 (5)
O9—Ag2—Ag1	162.57 (10)	O10—C20—O9	130.5 (5)
O3—Ag2—Ag1	55.10 (8)	O10—C20—C19	115.4 (4)
O11—Ag2—Ag1	50.66 (8)	O9—C20—C19	114.1 (4)
O6—Ag2—Ag1	67.42 (9)	F18—C21—F16	106.8 (4)
Ag3—Ag2—Ag1	76.010 (14)	F18—C21—F17	107.3 (4)
O9—Ag2—K1^i	45.67 (9)	F16—C21—F17	106.5 (4)
O3—Ag2—K1^i	87.90 (8)	F18—C21—C22	114.0 (4)
O11—Ag2—K1^i	152.19 (8)	F16—C21—C22	113.0 (4)
O6—Ag2—K1^i	99.87 (9)	F17—C21—C22	108.9 (4)
Ag3—Ag2—K1^i	127.79 (2)	O12—C22—O11	129.8 (4)
Ag1—Ag2—K1^i	137.293 (19)	O12—C22—C21	116.5 (4)
O9—Ag2—K1	134.06 (10)	O11—C22—C21	113.6 (4)
O3—Ag2—K1	45.01 (8)	F21—C23—F20	107.5 (4)
O11—Ag2—K1	47.96 (8)	F21—C23—F19	107.9 (5)
O6—Ag2—K1	129.10 (9)	F20—C23—F19	106.5 (4)
Ag3—Ag2—K1	124.95 (2)	F21—C23—C24	113.6 (4)
Ag1—Ag2—K1	63.354 (17)	F20—C23—C24	112.3 (4)
K1^i—Ag2—K1	107.22 (2)	F19—C23—C24	108.7 (4)
O12—Ag3—O6	122.40 (12)	O14—C24—O13	129.1 (4)
O12—Ag3—O10	110.06 (12)	O14—C24—C23	118.8 (4)
O6—Ag3—O10	93.80 (12)	O13—C24—C23	112.0 (4)
O12—Ag3—O12^ii	82.14 (11)	C1—N1—C5	120.0 (4)
O6—Ag3—O12^ii	100.62 (12)	C1—N1—Pt1	124.7 (3)
O10—Ag3—O12^ii	152.04 (11)	C5—N1—Pt1	115.2 (3)
O12—Ag3—O14^ii	104.20 (11)	C10—N2—C6	119.6 (4)
O6—Ag3—O14^ii	132.21 (12)	C10—N2—Pt1	125.0 (3)
O10—Ag3—O14^ii	78.46 (11)	C6—N2—Pt1	115.4 (3)
O12^ii—Ag3—O14^ii	74.09 (10)	C12—O1—Pt1	118.8 (3)
O12—Ag3—Ag2	83.13 (8)	C12—O2—Ag1	123.8 (3)
O6—Ag3—Ag2	56.01 (9)	C12—O2—K1	136.9 (3)
O10—Ag3—Ag2	70.58 (8)	Ag1—O2—K1	91.06 (10)
O12^ii—Ag3—Ag2	137.12 (7)	C14—O3—Ag2	114.7 (3)
O14^ii—Ag3—Ag2	148.76 (7)	C14—O3—K1	135.9 (3)
O8^iii—Ag4—O7	157.85 (13)	Ag2—O3—K1	98.27 (11)
O8^iii—Ag4—O4	117.26 (12)	C14—O4—Ag4	126.1 (3)
O7—Ag4—O4	84.82 (13)	C14—O4—K1^i	139.8 (3)
O8^iii—Ag4—Ag4^iii	80.91 (8)	Ag4—O4—K1^i	92.61 (11)
O7—Ag4—Ag4^iii	81.33 (8)	C16—O5—Ag1	120.3 (3)
O4—Ag4—Ag4^iii	144.66 (10)	C16—O6—Ag3	131.4 (3)
O8^iii—Ag4—K1^i	152.68 (8)	C16—O6—Ag2	122.2 (3)
O7—Ag4—K1^i	43.33 (8)	Ag3—O6—Ag2	74.50 (10)
O4—Ag4—K1^i	48.65 (8)	C18—O7—Ag4	120.4 (3)
Ag4^iii—Ag4—K1^i	124.59 (2)	C18—O7—K1^i	132.1 (3)
N1—C1—C2	121.0 (5)	Ag4—O7—K1^i	102.90 (12)
N1—C1—H1A	119.5	C18—O8—Ag4^iii	123.3 (3)
C2—C1—H1A	119.5	C20—O9—Ag2	113.8 (3)
C3—C2—C1	119.8 (5)	C20—O9—K1^i	143.3 (3)
C3—C2—H2A	120.1	Ag2—O9—K1^i	99.08 (12)
C1—C2—H2A	120.1	C20—O10—Ag3	131.0 (3)
C2—C3—C4	119.3 (5)	C22—O11—Ag2	121.9 (3)
C2—C3—H3A	120.4	C22—O11—Ag1	108.9 (3)
C4—C3—H3A	120.4	Ag2—O11—Ag1	83.80 (10)
C3—C4—C5	119.6 (5)	C22—O11—K1	141.6 (3)
C3—C4—H4A	120.2	Ag2—O11—K1	93.39 (10)
C5—C4—H4A	120.2	Ag1—O11—K1	88.00 (9)
N1—C5—C4	120.2 (4)	C22—O12—Ag3	120.1 (3)
N1—C5—C6	114.1 (4)	C22—O12—Ag3^ii	119.8 (3)
C4—C5—C6	125.6 (4)	Ag3—O12—Ag3^ii	97.86 (11)
N2—C6—C7	120.8 (4)	C24—O13—Pt1	123.9 (3)
N2—C6—C5	114.2 (4)	C24—O14—Ag1	116.9 (3)
C7—C6—C5	125.0 (4)	C24—O14—Ag3^ii	122.3 (3)
C8—C7—C6	119.3 (5)	Ag1—O14—Ag3^ii	115.14 (12)
C8—C7—H7A	120.4	C17—F10A—K1^i	122.4 (5)
C6—C7—H7A	120.4	C17—F10B—K1^i	119.9 (7)
C7—C8—C9	119.7 (5)	C17—F10C—K1^i	106.0 (9)
C7—C8—H8A	120.2

Symmetry codes: (i) −x+1, −y, −z+1; (ii) −x+1, −y+1, −z+1; (iii) −x, −y, −z+1.