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The 5-phenyl­tetra­zolate anion in the title compound, [Ag(C7H5N4)]n, uses three of its four N atoms to link silver cations into a linear ribbon structure; the Ag atom shows a trigonal planar coordination.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S160053680605029X/gk2043sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S160053680605029X/gk2043Isup2.hkl
Contains datablock I

CCDC reference: 629687

Key indicators

  • Single-crystal X-ray study
  • T = 294 K
  • Mean [sigma](C-C) = 0.007 Å
  • R factor = 0.036
  • wR factor = 0.092
  • Data-to-parameter ratio = 13.4

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT061_ALERT_3_B Tmax/Tmin Range Test RR' too Large ............. 0.75
Alert level C ABSTM02_ALERT_3_C The ratio of expected to reported Tmax/Tmin(RR') is < 0.90 Tmin and Tmax reported: 0.446 0.774 Tmin(prime) and Tmax expected: 0.574 0.764 RR(prime) = 0.766 Please check that your absorption correction is appropriate. PLAT062_ALERT_4_C Rescale T(min) & T(max) by ..................... 0.99 PLAT250_ALERT_2_C Large U3/U1 Ratio for Average U(i,j) Tensor .... 2.27
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 3 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 1 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2006).

catena-Poly[silver(I)-µ3-5-phenyl-1,2,3,4-tetrazolato-κ3N1:N2:N3] top
Crystal data top
[Ag(C7H5N4)]F(000) = 488
Mr = 253.02Dx = 2.303 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybcCell parameters from 1797 reflections
a = 10.433 (2) Åθ = 3.5–26.4°
b = 6.275 (1) ŵ = 2.70 mm1
c = 11.894 (2) ÅT = 294 K
β = 110.388 (2)°Block, colorless
V = 729.9 (2) Å30.20 × 0.18 × 0.10 mm
Z = 4
Data collection top
Bruker SMART 1K area-detector
diffractometer
1459 independent reflections
Radiation source: fine-focus sealed tube1138 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.047
φ and ω scansθmax = 26.4°, θmin = 3.5°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 1212
Tmin = 0.446, Tmax = 0.774k = 67
3709 measured reflectionsl = 814
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.036Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.092H-atom parameters constrained
S = 0.98 w = 1/[σ2(Fo2) + (0.0544P)2]
where P = (Fo2 + 2Fc2)/3
1459 reflections(Δ/σ)max = 0.001
109 parametersΔρmax = 1.16 e Å3
0 restraintsΔρmin = 1.37 e Å3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag10.45223 (4)0.64448 (5)0.65057 (3)0.0374 (2)
N10.3817 (3)0.9693 (5)0.5734 (3)0.0216 (8)
N20.4378 (3)1.1403 (5)0.6450 (3)0.0236 (8)
N30.4137 (4)1.3089 (5)0.5785 (3)0.0275 (8)
N40.3444 (4)1.2630 (6)0.4645 (3)0.0282 (8)
C10.3250 (4)1.0513 (6)0.4628 (4)0.020 (1)
C20.2462 (4)0.9371 (7)0.3531 (4)0.024 (1)
C30.2160 (4)1.0412 (7)0.2432 (4)0.028 (1)
C40.1412 (5)0.9424 (9)0.1389 (4)0.037 (1)
C50.0955 (5)0.7372 (9)0.1409 (5)0.041 (1)
C60.1239 (5)0.6325 (7)0.2481 (5)0.040 (1)
C70.2004 (4)0.7296 (7)0.3545 (4)0.031 (1)
H30.24721.17950.24110.033*
H40.12111.01380.06630.045*
H50.04520.66960.06960.049*
H60.09130.49480.24910.048*
H70.22110.65640.42660.037*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0623 (3)0.0126 (2)0.0260 (2)0.0028 (2)0.0010 (2)0.0003 (1)
N10.031 (2)0.009 (2)0.024 (2)0.001 (1)0.009 (2)0.001 (1)
N20.032 (2)0.010 (2)0.023 (2)0.004 (1)0.003 (2)0.002 (1)
N30.042 (2)0.011 (2)0.024 (2)0.001 (1)0.003 (2)0.001 (2)
N40.041 (2)0.013 (2)0.023 (2)0.003 (2)0.001 (2)0.002 (2)
C10.022 (2)0.012 (2)0.022 (2)0.002 (2)0.005 (2)0.001 (2)
C20.022 (2)0.019 (2)0.027 (2)0.003 (2)0.005 (2)0.001 (2)
C30.032 (2)0.025 (2)0.024 (2)0.002 (2)0.008 (2)0.003 (2)
C40.041 (3)0.042 (3)0.025 (2)0.002 (2)0.006 (2)0.001 (2)
C50.039 (3)0.043 (3)0.032 (3)0.003 (2)0.000 (2)0.015 (2)
C60.045 (3)0.023 (2)0.043 (3)0.008 (2)0.004 (2)0.011 (2)
C70.040 (3)0.020 (2)0.032 (3)0.004 (2)0.011 (2)0.002 (2)
Geometric parameters (Å, º) top
Ag1—N12.251 (3)C2—C31.396 (6)
Ag1—N2i2.299 (3)C3—C41.362 (6)
Ag1—N3ii2.256 (3)C4—C51.376 (7)
N1—C11.343 (5)C5—C61.371 (8)
N1—N21.368 (4)C6—C71.380 (7)
N2—N31.292 (5)C3—H30.93
N3—N41.327 (5)C4—H40.93
N4—C11.342 (5)C5—H50.93
C1—C21.464 (6)C6—H60.93
C2—C71.389 (6)C7—H70.93
N1—Ag1—N2i114.4 (1)C7—C2—C1122.5 (4)
N1—Ag1—N3ii134.5 (1)C3—C2—C1118.6 (4)
N2i—Ag1—N3ii110.4 (1)C4—C3—C2120.7 (5)
C1—N1—N2104.9 (3)C3—C4—C5120.1 (5)
C1—N1—Ag1135.7 (3)C6—C5—C4120.0 (4)
N2—N1—Ag1116.6 (2)C5—C6—C7120.6 (4)
N3—N2—N1108.1 (3)C6—C7—C2119.7 (4)
N3—N2—Ag1iii123.8 (3)C4—C3—H3119.7
N1—N2—Ag1iii128.0 (2)C2—C3—H3119.7
N2—N3—N4111.6 (3)C3—C4—H4119.9
N2—N3—Ag1iv124.1 (3)C5—C4—H4119.9
N4—N3—Ag1iv123.5 (3)C6—C5—H5120.0
N3—N4—C1104.8 (3)C4—C5—H5120.0
N4—C1—N1110.5 (3)C5—C6—H6119.7
N4—C1—C2122.2 (4)C7—C6—H6119.7
N1—C1—C2127.2 (4)C6—C7—H7120.2
C7—C2—C3118.9 (4)C2—C7—H7120.2
N3ii—Ag1—N1—C117.2 (5)N2—N1—C1—N40.0 (5)
N2i—Ag1—N1—C1173.8 (4)Ag1—N1—C1—N4159.4 (3)
N3ii—Ag1—N1—N2175.0 (2)N2—N1—C1—C2177.2 (4)
N2i—Ag1—N1—N216.1 (4)Ag1—N1—C1—C223.4 (6)
C1—N1—N2—N30.2 (4)N4—C1—C2—C7165.6 (4)
Ag1—N1—N2—N3164.3 (3)N1—C1—C2—C711.3 (6)
C1—N1—N2—Ag1iii177.3 (3)N4—C1—C2—C314.2 (6)
Ag1—N1—N2—Ag1iii18.6 (4)N1—C1—C2—C3168.9 (4)
N1—N2—N3—N40.4 (5)C7—C2—C3—C40.9 (7)
Ag1iii—N2—N3—N4177.6 (3)C1—C2—C3—C4179.0 (4)
N1—N2—N3—Ag1iv170.0 (2)C2—C3—C4—C50.5 (7)
Ag1iii—N2—N3—Ag1iv7.2 (5)C3—C4—C5—C60.7 (7)
N2—N3—N4—C10.4 (5)C4—C5—C6—C71.2 (8)
Ag1iv—N3—N4—C1170.1 (3)C5—C6—C7—C21.5 (8)
N3—N4—C1—N10.2 (5)C3—C2—C7—C61.4 (6)
N3—N4—C1—C2177.1 (4)C1—C2—C7—C6178.5 (4)
Symmetry codes: (i) x+1, y1/2, z+3/2; (ii) x, y1, z; (iii) x+1, y+1/2, z+3/2; (iv) x, y+1, z.
 

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