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The title compound, [Ru(N3)2(C25H22P2)2] or cis-[Ru(N3)2(dppm)2] [dppm is bis­(diphenyl­phosphino)methane], was obtained unexpectedly from our attempts to prepare new ruthenium mol­ecular wires using organic bridging ligands. Both the azido ligands show a triple bond adjacent to the metal.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S160053680602900X/gk2019sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S160053680602900X/gk2019Isup2.hkl
Contains datablock I

CCDC reference: 621318

Key indicators

  • Single-crystal X-ray study
  • T = 173 K
  • Mean [sigma](C-C) = 0.009 Å
  • Disorder in solvent or counterion
  • R factor = 0.062
  • wR factor = 0.162
  • Data-to-parameter ratio = 14.0

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT027_ALERT_3_B _diffrn_reflns_theta_full (too) Low ............ 24.97 Deg.
Alert level C PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT068_ALERT_1_C Reported F000 Differs from Calcd (or Missing)... ? PLAT077_ALERT_4_C Unitcell contains non-integer number of atoms .. ? PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ? PLAT220_ALERT_2_C Large Non-Solvent N Ueq(max)/Ueq(min) ... 2.94 Ratio PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for N6 PLAT243_ALERT_4_C High 'Solvent' Ueq as Compared to Neighbors for C62 PLAT302_ALERT_4_C Anion/Solvent Disorder ......................... 42.00 Perc. PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 10
Alert level G FORMU01_ALERT_1_G There is a discrepancy between the atom counts in the _chemical_formula_sum and _chemical_formula_moiety. This is usually due to the moiety formula being in the wrong format. Atom count from _chemical_formula_sum: C50.42 H44.83 Cl0.83 N6 P4 Atom count from _chemical_formula_moiety:C50.42 H44.84 Cl0.84 N6 P4 CELLZ01_ALERT_1_G Difference between formula and atom_site contents detected. CELLZ01_ALERT_1_G ALERT: check formula stoichiometry or atom site occupancies. From the CIF: _cell_formula_units_Z 8 From the CIF: _chemical_formula_sum C50.42 H44.83 Cl0.83 N6 P4 Ru TEST: Compare cell contents of formula and atom_site data atom Z*formula cif sites diff C 403.36 403.34 0.02 H 358.64 358.67 -0.03 Cl 6.64 6.67 -0.03 N 48.00 48.00 0.00 P 32.00 32.00 0.00 Ru 8.00 8.00 0.00
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 9 ALERT level C = Check and explain 3 ALERT level G = General alerts; check 5 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 2 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 4 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: COLLECT (Hooft, 1998); cell refinement: DENZO (Otwinowski & Minor, 1997); data reduction: DENZO and SCALEPACK (Otwinowski & Minor, 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 2001); software used to prepare material for publication: SHELXTL (Sheldrick, 2001) and CIFTAB (Sheldrick, 1993).

cis-Diazido[bis(diphenylphosphino)methane-κ2P,P']ruthenium(II) dichloromethane 0.42-solvate top
Crystal data top
[Ru(N3)2(C25H22P2)2]·0.42CH2Cl2F(000) = 4060
Mr = 989.17Dx = 1.436 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.71073 Å
a = 36.8818 (7) ÅCell parameters from 8316 reflections
b = 11.2016 (2) Åθ = 1–25°
c = 22.3275 (4) ŵ = 0.57 mm1
β = 97.235 (2)°T = 173 K
V = 9150.8 (3) Å3Block, yellow
Z = 80.45 × 0.40 × 0.40 mm
Data collection top
Nonius KappaCCD
diffractometer
6115 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tubeRint = 0.067
Graphite monochromatorθmax = 25.0°, θmin = 5.7°
φ and ω scansh = 3443
42989 measured reflectionsk = 1313
7920 independent reflectionsl = 2625
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.062Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.162H-atom parameters constrained
S = 1.06 w = 1/[σ2(Fo2) + (0.0635P)2 + 73.832P]
where P = (Fo2 + 2Fc2)/3
7920 reflections(Δ/σ)max = 0.001
566 parametersΔρmax = 1.45 e Å3
91 restraintsΔρmin = 0.91 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ru10.868972 (12)0.03797 (4)0.564765 (18)0.03287 (16)
N20.83196 (15)0.1139 (5)0.5837 (2)0.0444 (9)
N30.83097 (18)0.1544 (6)0.6155 (4)0.0658 (12)
N40.8268 (3)0.2228 (8)0.6628 (4)0.103 (2)
N50.90359 (15)0.0252 (5)0.6472 (2)0.0444 (9)
N60.90693 (18)0.0087 (6)0.6834 (4)0.0658 (12)
N70.9143 (3)0.0173 (10)0.7421 (5)0.131 (3)
P80.91616 (4)0.14491 (12)0.53215 (6)0.0335 (3)
C90.91267 (15)0.2889 (5)0.4922 (3)0.0369 (13)
C100.92532 (16)0.3037 (5)0.4367 (3)0.0404 (14)
H100.93640.23880.41840.048*
C110.92172 (18)0.4150 (6)0.4079 (3)0.0488 (16)
H110.93000.42490.36960.059*
C120.90634 (19)0.5093 (6)0.4343 (3)0.0534 (18)
H120.90450.58470.41470.064*
C130.89360 (18)0.4953 (6)0.4890 (3)0.0501 (16)
H130.88240.56050.50680.060*
C140.89707 (16)0.3861 (5)0.5181 (3)0.0405 (14)
H140.88870.37740.55640.049*
C150.95843 (16)0.1602 (5)0.5841 (2)0.0387 (13)
C160.97004 (17)0.2707 (6)0.6080 (3)0.0436 (14)
H160.95710.34100.59450.052*
C171.00055 (18)0.2787 (6)0.6515 (3)0.0531 (17)
H171.00830.35460.66700.064*
C181.01938 (18)0.1789 (7)0.6720 (3)0.0532 (17)
H181.03980.18510.70240.064*
C191.00849 (18)0.0678 (6)0.6481 (3)0.0514 (16)
H191.02180.00170.66170.062*
C200.97841 (17)0.0581 (6)0.6045 (3)0.0439 (14)
H200.97130.01790.58820.053*
C210.92712 (16)0.0344 (5)0.4761 (2)0.0365 (13)
H21A0.95340.01370.48050.044*
H21B0.91880.05950.43410.044*
P220.89870 (4)0.08648 (13)0.50193 (6)0.0334 (3)
C230.93031 (16)0.2035 (5)0.5315 (2)0.0375 (13)
C240.92452 (18)0.2648 (5)0.5836 (3)0.0428 (14)
H240.90450.24440.60460.051*
C250.94823 (19)0.3564 (6)0.6047 (3)0.0515 (17)
H250.94450.39740.64060.062*
C260.97691 (18)0.3885 (6)0.5746 (3)0.0493 (16)
H260.99290.45100.58980.059*
C270.98260 (17)0.3301 (6)0.5221 (3)0.0471 (15)
H271.00210.35350.50070.056*
C280.95960 (16)0.2371 (5)0.5008 (3)0.0418 (14)
H280.96380.19590.46510.050*
C290.87537 (16)0.1589 (5)0.4343 (2)0.0362 (13)
C300.89093 (18)0.1638 (6)0.3810 (3)0.0460 (15)
H300.91480.13310.37980.055*
C310.8718 (2)0.2133 (6)0.3292 (3)0.0534 (17)
H310.88250.21530.29260.064*
C320.8373 (2)0.2597 (6)0.3313 (3)0.0565 (18)
H320.82420.29370.29610.068*
C330.8219 (2)0.2568 (6)0.3841 (3)0.0543 (17)
H330.79820.28950.38530.065*
C340.84067 (18)0.2061 (5)0.4363 (3)0.0442 (15)
H340.82980.20390.47270.053*
P350.83974 (4)0.18708 (14)0.61468 (6)0.0387 (4)
C360.86325 (18)0.3138 (6)0.6535 (3)0.0456 (15)
C370.89788 (18)0.2976 (6)0.6848 (3)0.0491 (16)
H370.90960.22210.68480.059*
C380.9152 (2)0.3936 (8)0.7161 (3)0.064 (2)
H380.93880.38320.73810.076*
C390.8983 (3)0.5040 (8)0.7154 (4)0.074 (2)
H390.91020.56880.73720.089*
C400.8646 (3)0.5201 (8)0.6834 (4)0.078 (2)
H400.85330.59640.68220.093*
C410.8471 (2)0.4256 (7)0.6531 (3)0.064 (2)
H410.82350.43700.63150.077*
C420.80634 (16)0.1529 (6)0.6657 (2)0.0420 (14)
C430.81110 (18)0.0537 (6)0.7023 (3)0.0465 (15)
H430.83150.00290.70030.056*
C440.7861 (2)0.0276 (7)0.7422 (3)0.0625 (19)
H440.78960.04090.76730.075*
C450.7563 (2)0.1002 (9)0.7454 (3)0.070 (2)
H450.73890.08070.77170.084*
C460.75198 (19)0.2020 (8)0.7100 (3)0.067 (2)
H460.73200.25390.71320.080*
C470.77629 (18)0.2284 (7)0.6704 (3)0.0564 (18)
H470.77290.29790.64600.068*
C480.81337 (17)0.2476 (5)0.5451 (2)0.0405 (14)
H48A0.82310.32490.53260.049*
H48B0.78690.25460.54830.049*
P490.82406 (4)0.12182 (13)0.49612 (6)0.0343 (3)
C500.78078 (16)0.0405 (5)0.4795 (2)0.0372 (13)
C510.75941 (18)0.0201 (6)0.5262 (3)0.0462 (15)
H510.76650.05370.56490.055*
C520.72825 (19)0.0483 (6)0.5161 (3)0.0521 (16)
H520.71380.06000.54790.063*
C530.71782 (18)0.0999 (6)0.4610 (3)0.0534 (17)
H530.69660.14860.45470.064*
C540.73845 (18)0.0802 (6)0.4148 (3)0.0538 (17)
H540.73130.11570.37650.065*
C550.76943 (17)0.0096 (6)0.4232 (3)0.0448 (15)
H550.78300.00480.39050.054*
C560.83151 (15)0.1878 (5)0.4235 (2)0.0360 (13)
C570.82442 (17)0.3078 (5)0.4101 (3)0.0430 (14)
H570.81400.35680.43810.052*
C580.83232 (19)0.3554 (6)0.3569 (3)0.0544 (17)
H580.82770.43750.34850.065*
C590.84702 (19)0.2851 (7)0.3154 (3)0.0552 (18)
H590.85270.31920.27880.066*
C600.85357 (17)0.1646 (7)0.3269 (3)0.0497 (16)
H600.86330.11550.29800.060*
C610.84570 (16)0.1171 (6)0.3813 (2)0.0391 (13)
H610.85010.03480.38970.047*
C620.9988 (17)0.7316 (14)0.755 (4)0.126 (4)0.417 (7)
H62A1.00450.76550.79600.151*0.417 (7)
H62B0.97610.76900.73500.151*0.417 (7)
Cl630.9939 (3)0.5799 (6)0.7582 (5)0.126 (3)0.417 (7)
Cl641.03435 (16)0.7548 (5)0.7137 (2)0.087 (2)0.417 (7)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru10.0435 (3)0.0312 (3)0.0231 (2)0.0034 (2)0.00088 (18)0.00104 (18)
N20.045 (2)0.052 (2)0.036 (2)0.0156 (17)0.0027 (17)0.0104 (17)
N30.062 (2)0.046 (2)0.084 (3)0.0059 (19)0.011 (2)0.008 (2)
N40.137 (6)0.084 (5)0.085 (5)0.011 (5)0.005 (4)0.015 (4)
N50.045 (2)0.052 (2)0.036 (2)0.0156 (17)0.0027 (17)0.0104 (17)
N60.062 (2)0.046 (2)0.084 (3)0.0059 (19)0.011 (2)0.008 (2)
N70.155 (7)0.130 (6)0.101 (5)0.011 (6)0.016 (5)0.013 (5)
P80.0415 (8)0.0264 (7)0.0313 (7)0.0016 (6)0.0001 (6)0.0002 (6)
C90.036 (3)0.032 (3)0.040 (3)0.003 (2)0.006 (2)0.001 (2)
C100.042 (3)0.037 (3)0.041 (3)0.005 (3)0.002 (3)0.005 (3)
C110.057 (4)0.046 (4)0.040 (3)0.006 (3)0.004 (3)0.012 (3)
C120.068 (4)0.035 (4)0.050 (4)0.009 (3)0.018 (3)0.012 (3)
C130.063 (4)0.032 (3)0.049 (4)0.002 (3)0.015 (3)0.005 (3)
C140.048 (3)0.029 (3)0.041 (3)0.002 (3)0.006 (3)0.002 (2)
C150.046 (3)0.038 (3)0.032 (3)0.002 (3)0.002 (3)0.002 (2)
C160.052 (4)0.038 (3)0.040 (3)0.000 (3)0.000 (3)0.001 (3)
C170.058 (4)0.052 (4)0.045 (4)0.003 (3)0.008 (3)0.009 (3)
C180.047 (4)0.073 (5)0.037 (3)0.002 (3)0.005 (3)0.002 (3)
C190.049 (4)0.052 (4)0.050 (4)0.009 (3)0.004 (3)0.008 (3)
C200.047 (4)0.040 (4)0.043 (3)0.003 (3)0.002 (3)0.000 (3)
C210.045 (3)0.031 (3)0.033 (3)0.001 (3)0.002 (2)0.001 (2)
P220.0455 (8)0.0270 (7)0.0272 (7)0.0011 (6)0.0023 (6)0.0000 (6)
C230.051 (3)0.027 (3)0.033 (3)0.002 (3)0.001 (3)0.002 (2)
C240.057 (4)0.037 (3)0.034 (3)0.004 (3)0.002 (3)0.000 (3)
C250.065 (4)0.042 (4)0.045 (4)0.001 (3)0.004 (3)0.016 (3)
C260.053 (4)0.037 (4)0.053 (4)0.002 (3)0.010 (3)0.011 (3)
C270.049 (4)0.040 (3)0.051 (4)0.001 (3)0.000 (3)0.001 (3)
C280.050 (4)0.036 (3)0.039 (3)0.001 (3)0.005 (3)0.001 (3)
C290.053 (4)0.026 (3)0.029 (3)0.002 (3)0.003 (3)0.002 (2)
C300.056 (4)0.043 (4)0.038 (3)0.010 (3)0.004 (3)0.001 (3)
C310.079 (5)0.050 (4)0.031 (3)0.015 (4)0.004 (3)0.008 (3)
C320.086 (5)0.037 (4)0.042 (4)0.004 (3)0.013 (4)0.007 (3)
C330.066 (4)0.048 (4)0.045 (4)0.013 (3)0.009 (3)0.003 (3)
C340.061 (4)0.037 (3)0.033 (3)0.004 (3)0.002 (3)0.006 (3)
P350.0461 (9)0.0420 (9)0.0269 (7)0.0008 (7)0.0003 (6)0.0070 (6)
C360.055 (4)0.050 (4)0.033 (3)0.005 (3)0.010 (3)0.012 (3)
C370.059 (4)0.054 (4)0.034 (3)0.017 (3)0.004 (3)0.000 (3)
C380.068 (5)0.088 (6)0.034 (4)0.028 (4)0.003 (3)0.008 (4)
C390.095 (6)0.076 (6)0.056 (5)0.032 (5)0.027 (5)0.038 (4)
C400.088 (6)0.069 (5)0.077 (6)0.001 (5)0.015 (5)0.042 (5)
C410.070 (5)0.057 (5)0.065 (5)0.002 (4)0.010 (4)0.032 (4)
C420.043 (3)0.055 (4)0.027 (3)0.000 (3)0.001 (2)0.012 (3)
C430.050 (4)0.060 (4)0.029 (3)0.002 (3)0.004 (3)0.004 (3)
C440.066 (5)0.076 (5)0.046 (4)0.011 (4)0.010 (3)0.005 (4)
C450.054 (5)0.109 (7)0.051 (4)0.013 (5)0.017 (4)0.014 (5)
C460.045 (4)0.097 (6)0.060 (5)0.006 (4)0.011 (4)0.023 (5)
C470.051 (4)0.069 (5)0.047 (4)0.004 (4)0.001 (3)0.007 (3)
C480.051 (4)0.042 (3)0.028 (3)0.003 (3)0.000 (3)0.008 (2)
P490.0412 (8)0.0354 (8)0.0255 (7)0.0025 (6)0.0009 (6)0.0022 (6)
C500.044 (3)0.039 (3)0.028 (3)0.002 (3)0.001 (2)0.002 (2)
C510.056 (4)0.047 (4)0.036 (3)0.003 (3)0.007 (3)0.001 (3)
C520.061 (4)0.052 (4)0.045 (4)0.011 (3)0.016 (3)0.004 (3)
C530.052 (4)0.057 (4)0.051 (4)0.021 (3)0.005 (3)0.001 (3)
C540.058 (4)0.062 (4)0.040 (3)0.020 (3)0.000 (3)0.013 (3)
C550.050 (4)0.051 (4)0.033 (3)0.007 (3)0.004 (3)0.006 (3)
C560.037 (3)0.042 (3)0.027 (3)0.007 (3)0.005 (2)0.001 (2)
C570.051 (4)0.040 (3)0.034 (3)0.001 (3)0.006 (3)0.000 (3)
C580.073 (5)0.042 (4)0.043 (4)0.012 (3)0.012 (3)0.008 (3)
C590.063 (4)0.066 (5)0.035 (3)0.024 (4)0.003 (3)0.014 (3)
C600.050 (4)0.067 (5)0.032 (3)0.008 (3)0.003 (3)0.004 (3)
C610.045 (3)0.044 (3)0.028 (3)0.000 (3)0.003 (2)0.000 (3)
C620.125 (5)0.126 (4)0.125 (5)0.002 (3)0.017 (3)0.001 (3)
Cl630.125 (4)0.126 (3)0.123 (4)0.007 (3)0.007 (3)0.006 (3)
Cl640.108 (3)0.071 (3)0.080 (3)0.038 (2)0.004 (2)0.006 (2)
Geometric parameters (Å, º) top
Ru1—N22.254 (5)C33—H330.9500
Ru1—N52.220 (6)C33—C341.398 (8)
Ru1—P82.3050 (15)C34—H340.9500
Ru1—P222.3455 (15)P35—C361.825 (6)
Ru1—P352.3446 (16)P35—C421.821 (6)
Ru1—P492.3099 (15)P35—C481.855 (6)
N2—N30.847 (7)C36—C371.388 (9)
N3—N41.330 (10)C36—C411.386 (10)
N5—N60.823 (7)C37—H370.9500
N6—N71.336 (11)C37—C381.394 (9)
P8—C91.840 (6)C38—H380.9500
P8—C151.830 (6)C38—C391.384 (12)
P8—C211.842 (6)C39—H390.9500
C9—C101.387 (8)C39—C401.366 (12)
C9—C141.392 (8)C40—H400.9500
C10—H100.9500C40—C411.373 (10)
C10—C111.402 (8)C41—H410.9500
C11—H110.9500C42—C431.377 (9)
C11—C121.368 (10)C42—C471.409 (9)
C12—H120.9500C43—H430.9500
C12—C131.372 (10)C43—C441.390 (9)
C13—H130.9500C44—H440.9500
C13—C141.384 (8)C44—C451.377 (11)
C14—H140.9500C45—H450.9500
C15—C161.394 (8)C45—C461.385 (12)
C15—C201.404 (8)C46—H460.9500
C16—H160.9500C46—C471.368 (10)
C16—C171.393 (8)C47—H470.9500
C17—H170.9500C48—H48A0.9900
C17—C181.364 (9)C48—H48B0.9900
C18—H180.9500C48—P491.856 (6)
C18—C191.394 (10)P49—C501.835 (6)
C19—H190.9500P49—C561.834 (5)
C19—C201.385 (8)C50—C511.402 (8)
C20—H200.9500C50—C551.392 (8)
C21—H21A0.9900C51—H510.9500
C21—H21B0.9900C51—C521.376 (9)
C21—P221.848 (6)C52—H520.9500
P22—C231.821 (6)C52—C531.371 (9)
P22—C291.831 (6)C53—H530.9500
C23—C241.391 (8)C53—C541.374 (9)
C23—C281.401 (8)C54—H540.9500
C24—H240.9500C54—C551.383 (9)
C24—C251.391 (9)C55—H550.9500
C25—H250.9500C56—C571.395 (8)
C25—C261.371 (9)C56—C611.383 (8)
C26—H260.9500C57—H570.9500
C26—C271.380 (9)C57—C581.366 (9)
C27—H270.9500C58—H580.9500
C27—C281.390 (8)C58—C591.378 (10)
C28—H280.9500C59—H590.9500
C29—C301.386 (8)C59—C601.390 (10)
C29—C341.391 (8)C60—H600.9500
C30—H300.9500C60—C611.391 (8)
C30—C311.391 (9)C61—H610.9500
C31—H310.9500C62—H62A0.9900
C31—C321.382 (10)C62—H62B0.9900
C32—H320.9500C62—Cl631.711 (13)
C32—C331.372 (10)C62—Cl641.715 (16)
N2—Ru1—N584.41 (19)C32—C33—H33119.6
N2—Ru1—P8161.90 (15)C32—C33—C34120.7 (7)
N2—Ru1—P2290.18 (14)H33—C33—C34119.6
N2—Ru1—P3597.07 (15)C29—C34—C33119.2 (6)
N2—Ru1—P4991.76 (16)C29—C34—H34120.4
N5—Ru1—P892.83 (14)C33—C34—H34120.4
N5—Ru1—P2292.48 (15)Ru1—P35—C36124.1 (2)
N5—Ru1—P3594.81 (15)Ru1—P35—C42122.4 (2)
N5—Ru1—P49165.79 (15)Ru1—P35—C4894.94 (18)
P8—Ru1—P2272.03 (5)C36—P35—C42100.6 (3)
P8—Ru1—P35100.99 (6)C36—P35—C48106.4 (3)
P8—Ru1—P4994.93 (5)C42—P35—C48106.1 (3)
P22—Ru1—P35170.18 (5)P35—C36—C37119.3 (5)
P22—Ru1—P49101.24 (5)P35—C36—C41121.4 (5)
P35—Ru1—P4972.03 (5)C37—C36—C41119.3 (6)
Ru1—N2—N3130.7 (7)C36—C37—H37120.5
N2—N3—N4174.9 (10)C36—C37—C38119.1 (7)
Ru1—N5—N6137.9 (8)H37—C37—C38120.5
N5—N6—N7176.9 (11)C37—C38—H38119.8
Ru1—P8—C9126.82 (19)C37—C38—C39120.4 (7)
Ru1—P8—C15117.71 (19)H38—C38—C39119.8
Ru1—P8—C2195.99 (18)C38—C39—H39119.9
C9—P8—C15103.1 (3)C38—C39—C40120.2 (7)
C9—P8—C21105.5 (3)H39—C39—C40119.9
C15—P8—C21104.6 (3)C39—C40—H40120.1
P8—C9—C10121.8 (4)C39—C40—C41119.8 (8)
P8—C9—C14119.4 (4)H40—C40—C41120.1
C10—C9—C14118.8 (5)C36—C41—C40121.2 (8)
C9—C10—H10120.2C36—C41—H41119.4
C9—C10—C11119.6 (6)C40—C41—H41119.4
H10—C10—C11120.2P35—C42—C43119.7 (5)
C10—C11—H11119.7P35—C42—C47121.4 (5)
C10—C11—C12120.6 (6)C43—C42—C47118.9 (6)
H11—C11—C12119.7C42—C43—H43119.9
C11—C12—H12119.9C42—C43—C44120.3 (6)
C11—C12—C13120.2 (6)H43—C43—C44119.9
H12—C12—C13119.9C43—C44—H44119.8
C12—C13—H13120.1C43—C44—C45120.4 (7)
C12—C13—C14119.9 (6)H44—C44—C45119.8
H13—C13—C14120.1C44—C45—H45120.2
C9—C14—C13121.0 (6)C44—C45—C46119.5 (7)
C9—C14—H14119.5H45—C45—C46120.2
C13—C14—H14119.5C45—C46—H46119.7
P8—C15—C16121.4 (4)C45—C46—C47120.6 (7)
P8—C15—C20120.0 (4)H46—C46—C47119.7
C16—C15—C20118.4 (5)C42—C47—C46120.2 (7)
C15—C16—H16119.8C42—C47—H47119.9
C15—C16—C17120.4 (6)C46—C47—H47119.9
H16—C16—C17119.8P35—C48—H48A112.7
C16—C17—H17119.5P35—C48—H48B112.7
C16—C17—C18120.9 (6)P35—C48—P4995.1 (3)
H17—C17—C18119.5H48A—C48—H48B110.2
C17—C18—H18120.3H48A—C48—P49112.7
C17—C18—C19119.5 (6)H48B—C48—P49112.7
H18—C18—C19120.3Ru1—P49—C4896.06 (18)
C18—C19—H19119.8Ru1—P49—C50117.71 (19)
C18—C19—C20120.4 (6)Ru1—P49—C56125.16 (19)
H19—C19—C20119.8C48—P49—C50104.6 (3)
C15—C20—C19120.3 (6)C48—P49—C56106.4 (3)
C15—C20—H20119.8C50—P49—C56104.2 (2)
C19—C20—H20119.8P49—C50—C51119.1 (4)
P8—C21—H21A112.6P49—C50—C55122.5 (4)
P8—C21—H21B112.6C51—C50—C55118.2 (5)
P8—C21—P2295.7 (3)C50—C51—H51119.8
H21A—C21—H21B110.1C50—C51—C52120.4 (6)
H21A—C21—P22112.6H51—C51—C52119.8
H21B—C21—P22112.6C51—C52—H52119.5
Ru1—P22—C2194.46 (18)C51—C52—C53121.0 (6)
Ru1—P22—C23122.48 (19)H52—C52—C53119.5
Ru1—P22—C29123.4 (2)C52—C53—H53120.4
C21—P22—C23106.1 (3)C52—C53—C54119.1 (6)
C21—P22—C29107.0 (3)H53—C53—C54120.4
C23—P22—C29101.1 (3)C53—C54—H54119.4
P22—C23—C24120.0 (5)C53—C54—C55121.1 (6)
P22—C23—C28120.9 (4)H54—C54—C55119.4
C24—C23—C28119.0 (5)C50—C55—C54120.1 (6)
C23—C24—H24120.3C50—C55—H55120.0
C23—C24—C25119.5 (6)C54—C55—H55120.0
H24—C24—C25120.3P49—C56—C57122.2 (4)
C24—C25—H25119.4P49—C56—C61118.9 (4)
C24—C25—C26121.2 (6)C57—C56—C61118.8 (5)
H25—C25—C26119.4C56—C57—H57119.7
C25—C26—H26120.0C56—C57—C58120.5 (6)
C25—C26—C27120.0 (6)H57—C57—C58119.7
H26—C26—C27120.0C57—C58—H58119.8
C26—C27—H27120.2C57—C58—C59120.4 (6)
C26—C27—C28119.7 (6)H58—C58—C59119.8
H27—C27—C28120.2C58—C59—H59119.8
C23—C28—C27120.6 (6)C58—C59—C60120.4 (6)
C23—C28—H28119.7H59—C59—C60119.8
C27—C28—H28119.7C59—C60—H60120.6
P22—C29—C30121.6 (5)C59—C60—C61118.8 (6)
P22—C29—C34118.7 (4)H60—C60—C61120.6
C30—C29—C34119.7 (5)C56—C61—C60121.0 (6)
C29—C30—H30119.7C56—C61—H61119.5
C29—C30—C31120.5 (6)C60—C61—H61119.5
H30—C30—C31119.7H62A—C62—H62B108.8
C30—C31—H31120.2H62A—C62—Cl63110.7
C30—C31—C32119.6 (6)H62A—C62—Cl64110.7
H31—C31—C32120.2H62B—C62—Cl63110.7
C31—C32—H32119.9H62B—C62—Cl64110.7
C31—C32—C33120.2 (6)Cl63—C62—Cl64105.3 (12)
H32—C32—C33119.9
N5—Ru1—N2—N317.1 (10)C30—C31—C32—C330.1 (10)
P8—Ru1—N2—N399.1 (10)C31—C32—C33—C340.6 (10)
P22—Ru1—N2—N3109.6 (10)P22—C29—C34—C33177.1 (5)
P35—Ru1—N2—N377.1 (10)C30—C29—C34—C330.6 (9)
P49—Ru1—N2—N3149.2 (10)C32—C33—C34—C290.3 (10)
N2—Ru1—N5—N696.6 (11)N2—Ru1—P35—C36147.3 (3)
P8—Ru1—N5—N6101.3 (11)N2—Ru1—P35—C4213.5 (3)
P22—Ru1—N5—N6173.4 (11)N2—Ru1—P35—C4899.1 (3)
P35—Ru1—N5—N60.0 (11)N5—Ru1—P35—C3662.4 (3)
P49—Ru1—N5—N621.7 (15)N5—Ru1—P35—C4271.5 (3)
N2—Ru1—P8—C9135.0 (5)N5—Ru1—P35—C48176.0 (2)
N2—Ru1—P8—C1589.4 (5)P8—Ru1—P35—C3631.4 (3)
N2—Ru1—P8—C2120.5 (5)P8—Ru1—P35—C42165.3 (2)
N5—Ru1—P8—C9144.4 (3)P8—Ru1—P35—C4882.1 (2)
N5—Ru1—P8—C158.8 (3)P49—Ru1—P35—C36123.1 (3)
N5—Ru1—P8—C21101.1 (2)P49—Ru1—P35—C42103.0 (2)
P22—Ru1—P8—C9123.9 (2)P49—Ru1—P35—C489.5 (2)
P22—Ru1—P8—C15100.5 (2)Ru1—P35—C36—C3736.9 (6)
P22—Ru1—P8—C219.44 (18)Ru1—P35—C36—C41144.0 (5)
P35—Ru1—P8—C948.9 (2)C42—P35—C36—C37104.9 (5)
P35—Ru1—P8—C1586.7 (2)C42—P35—C36—C4174.3 (6)
P35—Ru1—P8—C21163.42 (18)C48—P35—C36—C37144.7 (5)
P49—Ru1—P8—C923.7 (2)C48—P35—C36—C4136.1 (6)
P49—Ru1—P8—C15159.3 (2)P35—C36—C37—C38177.8 (5)
P49—Ru1—P8—C2190.79 (19)C41—C36—C37—C381.4 (9)
Ru1—P8—C9—C10124.0 (4)C36—C37—C38—C390.9 (10)
Ru1—P8—C9—C1456.3 (5)C37—C38—C39—C400.6 (11)
C15—P8—C9—C1095.5 (5)C38—C39—C40—C411.6 (13)
C15—P8—C9—C1484.2 (5)C39—C40—C41—C361.0 (13)
C21—P8—C9—C1013.9 (5)P35—C36—C41—C40178.7 (6)
C21—P8—C9—C14166.3 (4)C37—C36—C41—C400.5 (11)
P8—C9—C10—C11179.4 (4)Ru1—P35—C42—C4336.5 (5)
C14—C9—C10—C110.8 (8)Ru1—P35—C42—C47145.9 (4)
C9—C10—C11—C120.9 (9)C36—P35—C42—C43106.1 (5)
C10—C11—C12—C131.3 (10)C36—P35—C42—C4771.4 (5)
C11—C12—C13—C141.5 (9)C48—P35—C42—C43143.3 (5)
C12—C13—C14—C91.4 (9)C48—P35—C42—C4739.2 (6)
P8—C9—C14—C13179.2 (4)P35—C42—C43—C44179.0 (5)
C10—C9—C14—C131.1 (8)C47—C42—C43—C441.4 (9)
Ru1—P8—C15—C16113.9 (5)C42—C43—C44—C450.2 (10)
Ru1—P8—C15—C2061.1 (5)C43—C44—C45—C462.1 (11)
C9—P8—C15—C1631.0 (6)C44—C45—C46—C472.3 (11)
C9—P8—C15—C20154.1 (5)C45—C46—C47—C420.8 (11)
C21—P8—C15—C16141.1 (5)P35—C42—C47—C46178.7 (5)
C21—P8—C15—C2043.9 (5)C43—C42—C47—C461.1 (9)
P8—C15—C16—C17174.4 (5)Ru1—P35—C48—P4911.4 (2)
C20—C15—C16—C170.7 (9)C36—P35—C48—P49139.1 (3)
C15—C16—C17—C180.7 (10)C42—P35—C48—P49114.4 (3)
C16—C17—C18—C191.6 (10)P35—C48—P49—Ru111.5 (2)
C17—C18—C19—C201.1 (10)P35—C48—P49—C50109.2 (3)
C18—C19—C20—C150.3 (10)P35—C48—P49—C56140.9 (3)
P8—C15—C20—C19173.9 (5)N2—Ru1—P49—C48106.4 (2)
C16—C15—C20—C191.2 (9)N2—Ru1—P49—C503.6 (2)
Ru1—P8—C21—P2211.5 (2)N2—Ru1—P49—C56138.7 (3)
C9—P8—C21—P22142.4 (2)N5—Ru1—P49—C4832.4 (6)
C15—P8—C21—P22109.2 (3)N5—Ru1—P49—C5077.6 (6)
P8—C21—P22—Ru111.2 (2)N5—Ru1—P49—C56147.3 (6)
P8—C21—P22—C23114.4 (3)P8—Ru1—P49—C4890.4 (2)
P8—C21—P22—C29138.2 (3)P8—Ru1—P49—C50159.6 (2)
N2—Ru1—P22—C21174.0 (2)P8—Ru1—P49—C5624.5 (2)
N2—Ru1—P22—C2373.6 (3)P22—Ru1—P49—C48163.1 (2)
N2—Ru1—P22—C2960.2 (3)P22—Ru1—P49—C5086.9 (2)
N5—Ru1—P22—C21101.6 (2)P22—Ru1—P49—C5648.1 (2)
N5—Ru1—P22—C2310.8 (3)P35—Ru1—P49—C489.5 (2)
N5—Ru1—P22—C29144.7 (3)P35—Ru1—P49—C50100.5 (2)
P8—Ru1—P22—C219.39 (18)P35—Ru1—P49—C56124.5 (2)
P8—Ru1—P22—C23102.9 (2)Ru1—P49—C50—C5162.1 (5)
P8—Ru1—P22—C29123.2 (2)Ru1—P49—C50—C55113.2 (5)
P49—Ru1—P22—C2182.19 (19)C48—P49—C50—C5143.0 (5)
P49—Ru1—P22—C23165.5 (2)C48—P49—C50—C55141.7 (5)
P49—Ru1—P22—C2931.6 (2)C56—P49—C50—C51154.5 (5)
Ru1—P22—C23—C2433.7 (5)C56—P49—C50—C5530.2 (6)
Ru1—P22—C23—C28149.4 (4)P49—C50—C51—C52175.1 (5)
C21—P22—C23—C24140.0 (5)C55—C50—C51—C520.4 (9)
C21—P22—C23—C2843.2 (5)C50—C51—C52—C531.3 (10)
C29—P22—C23—C24108.4 (5)C51—C52—C53—C541.6 (11)
C29—P22—C23—C2868.4 (5)C52—C53—C54—C550.0 (11)
P22—C23—C24—C25178.1 (5)C53—C54—C55—C501.7 (11)
C28—C23—C24—C251.2 (8)P49—C50—C55—C54173.4 (5)
C23—C24—C25—C261.0 (9)C51—C50—C55—C541.9 (9)
C24—C25—C26—C270.3 (10)Ru1—P49—C56—C57118.2 (4)
C25—C26—C27—C281.4 (10)Ru1—P49—C56—C6159.7 (5)
C26—C27—C28—C231.2 (9)C48—P49—C56—C578.2 (5)
P22—C23—C28—C27177.0 (5)C48—P49—C56—C61169.7 (4)
C24—C23—C28—C270.1 (9)C50—P49—C56—C57102.0 (5)
Ru1—P22—C29—C30137.5 (4)C50—P49—C56—C6180.1 (5)
Ru1—P22—C29—C3440.2 (5)P49—C56—C57—C58176.1 (5)
C21—P22—C29—C3030.1 (5)C61—C56—C57—C581.8 (9)
C21—P22—C29—C34147.6 (5)C56—C57—C58—C590.8 (10)
C23—P22—C29—C3080.8 (5)C57—C58—C59—C600.8 (10)
C23—P22—C29—C34101.5 (5)C58—C59—C60—C611.2 (10)
P22—C29—C30—C31176.4 (5)P49—C56—C61—C60176.7 (4)
C34—C29—C30—C311.3 (9)C57—C56—C61—C601.3 (8)
C29—C30—C31—C321.0 (9)C59—C60—C61—C560.2 (9)
 

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