cis-Dichloridobis(methoxy­diphenyl­phosphino)platinum(II)

The title compound, [PtCl₂(C₁₃H₁₃OP)₂], adopts a cis-square-planar geometry. Mol­ecules are linked by C—H...Cl and C—H...π(arene) inter­actions.

Key indicators

• Single-crystal X-ray study
• T = 125 K
• Mean [sigma](C-C)= 0.006 Å
• R factor = 0.041
• wR factor = 0.062
• Data-to-parameter ratio = 19.5

checkCIF/PLATON results

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S1. Comment

The title complex (I) can be compared to similar platinum dichloride complexes containing trimethoxy phosphite; [PtCl₂(P(OMe)₃)₂] (Bao et al., 1987) and triphenyl phosphine [PtCl₂(PPh₃)₂] (Fun et al., 2006). The geometry at the platinum atom in the title compound (I) bears a closer resemblance to the triphenyl phosphine complex and can be compared with [PtCl₂(P(OMe)₂Ph)₂] (Slawin et al., 2007).

Related literature

For related literature on PtCl₂L₂ complexes, see: Bao et al. (1987); Fun et al. (2006); Slawin et al. (2007).

Cg1 and Cg2 are the centroids of the C7–c12 and C20–C25 rings.

S2. Experimental

0.8 g (2.14 mmol) of PtCl₂(COD) was dissolved in the minimum volume of dichloromethane in a round-bottomed flask. To this, 0.921 ml (4.28 mmol) of methyldiphenylphosphinite was added. The solution was then stirred for 0.5 h at room temperature. The product was precipitated via slow diffusion of hexane and was then filtered off and dried under vacuum, [PtCl₂(P(OMe)Ph₂)₂] (1.93 mmol,ca 90%. ³¹P-{¹H} NMR: δ 85.2 p.p.m. J{Pt—P} 4183 Hz.

S3. Refinement

All H atoms were included in calculated positions (C—H distances are 0.96 Å for methyl H atoms, 0.97 Å for methylene H atoms and 0.98 Å for methine H atoms) and were refined as riding atoms with U_iso(H) = 1.2 U_eq(parent atom, methylene and methine H atoms) or U_iso(H) = 1.5 U_eq(parent atom, methyl H atoms).

Computing details

Data collection: SCXmini Software (Rigaku/MSC, 2006); cell refinement: PROCESS-AUTO (Rigaku, 1998); data reduction: PROCESS-AUTO; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: CrystalStructure (Rigaku/MSC, 2006); software used to prepare material for publication: CrystalStructure.

Figures

Fig. 1. The structure of (1) with displacement ellipsoids drawn at the 50% probability level, H atoms omitted for clarity.

cis-Dichloridobis(methoxydiphenylphosphino)platinum(II)

Crystal data

[PtCl2(C13H13OP)2]	F(000) = 1360.00
Mr = 698.43	Dx = 1.824 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71075 Å
Hall symbol: -P 2yn	Cell parameters from 23439 reflections
a = 12.4262 (6) Å	θ = 3.1–27.6°
b = 13.6280 (7) Å	µ = 5.85 mm^−1
c = 15.0494 (8) Å	T = 125 K
β = 93.5316 (11)°	Prism, colorless
V = 2543.7 (2) Å^3	0.25 × 0.15 × 0.12 mm
Z = 4

Data collection

Rigaku SCXmini diffractometer	4910 reflections with F^2 > 2σ(F^2)
Detector resolution: 6.85 pixels mm^-1	Rint = 0.057
ω scans	θmax = 27.5°
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)	h = −16→16
Tmin = 0.377, Tmax = 0.495	k = −17→17
26133 measured reflections	l = −19→19
5827 independent reflections

Refinement

Refinement on F^2	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.041	w = 1/[σ^2(Fo^2) + (0.0124P)^2 + 7.7753P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.062	(Δ/σ)max = 0.002
S = 1.13	Δρmax = 0.99 e Å^−3
5827 reflections	Δρmin = −1.02 e Å^−3
299 parameters

Special details

Refinement. Refinement was performed using all reflections. The weighted R-factor (wR) and goodness of fit (S) are based on F². R-factor (gt) are based on F. The threshold expression of F² > 2.0 σ(F²) is used only for calculating R-factor (gt).

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Pt(1)	0.075336 (15)	0.162861 (13)	0.837844 (12)	0.01364 (4)
Cl(1)	0.10233 (10)	0.03053 (9)	0.73956 (8)	0.0204 (2)
Cl(2)	−0.11089 (10)	0.12977 (9)	0.82742 (9)	0.0229 (2)
P(1)	0.25475 (9)	0.16303 (10)	0.85328 (8)	0.0146 (2)
P(2)	0.04528 (10)	0.29335 (9)	0.92198 (8)	0.0135 (2)
O(1)	0.3161 (2)	0.1781 (2)	0.7644 (2)	0.0205 (7)
O(2)	0.1320 (2)	0.3806 (2)	0.9213 (2)	0.0162 (7)
C(1)	0.3066 (3)	0.0446 (3)	0.8932 (3)	0.0165 (10)
C(2)	0.4104 (4)	0.0170 (3)	0.8755 (3)	0.0229 (11)
C(3)	0.4538 (4)	−0.0690 (3)	0.9111 (3)	0.0261 (12)
C(4)	0.3943 (4)	−0.1272 (3)	0.9644 (3)	0.0277 (12)
C(5)	0.2914 (4)	−0.0996 (3)	0.9842 (3)	0.0285 (12)
C(6)	0.2473 (4)	−0.0138 (3)	0.9477 (3)	0.0238 (11)
C(7)	0.3255 (3)	0.2451 (3)	0.9318 (3)	0.0161 (10)
C(8)	0.3143 (3)	0.2328 (3)	1.0229 (3)	0.0182 (10)
C(9)	0.3715 (4)	0.2924 (3)	1.0838 (3)	0.0267 (12)
C(10)	0.4417 (4)	0.3621 (3)	1.0537 (4)	0.0279 (13)
C(11)	0.4526 (4)	0.3749 (3)	0.9635 (3)	0.0273 (12)
C(12)	0.3945 (3)	0.3163 (3)	0.9024 (3)	0.0219 (11)
C(13)	0.2720 (4)	0.2348 (4)	0.6905 (3)	0.0297 (13)
C(14)	0.0499 (3)	0.2684 (3)	1.0394 (3)	0.0156 (10)
C(15)	0.0338 (3)	0.1735 (3)	1.0697 (3)	0.0221 (11)
C(16)	0.0487 (4)	0.1518 (4)	1.1591 (3)	0.0287 (12)
C(17)	0.0785 (4)	0.2256 (4)	1.2200 (3)	0.0271 (12)
C(18)	0.0940 (4)	0.3196 (4)	1.1909 (3)	0.0267 (12)
C(19)	0.0800 (3)	0.3427 (3)	1.1010 (3)	0.0193 (10)
C(20)	−0.0821 (3)	0.3548 (3)	0.8926 (3)	0.0167 (10)
C(21)	−0.1502 (4)	0.3860 (3)	0.9576 (3)	0.0201 (11)
C(22)	−0.2438 (4)	0.4369 (3)	0.9331 (3)	0.0264 (12)
C(23)	−0.2699 (4)	0.4580 (3)	0.8444 (3)	0.0251 (12)
C(24)	−0.2024 (4)	0.4278 (3)	0.7794 (3)	0.0246 (12)
C(25)	−0.1105 (4)	0.3757 (3)	0.8035 (3)	0.0206 (11)
C(26)	0.1466 (4)	0.4373 (3)	0.8418 (3)	0.0242 (11)
H(30)	0.2260	0.2868	0.7123	0.036*
H(2)	0.4519	0.0571	0.8389	0.028*
H(3)	0.5249	−0.0879	0.8987	0.031*
H(4)	0.4242	−0.1867	0.9877	0.033*
H(5)	0.2513	−0.1389	1.0225	0.034*
H(6)	0.1762	0.0049	0.9602	0.029*
H(31)	0.2291	0.1921	0.6497	0.036*
H(8)	0.2675	0.1836	1.0432	0.022*
H(9)	0.3625	0.2855	1.1458	0.032*
H(10)	0.4828	0.4014	1.0954	0.033*
H(11)	0.4998	0.4239	0.9435	0.033*
H(12)	0.4021	0.3249	0.8405	0.026*
H(33)	0.3308	0.2642	0.6591	0.036*
H(28)	0.2017	0.4061	0.8075	0.029*
H(15)	0.0125	0.1232	1.0285	0.026*
H(16)	0.0387	0.0866	1.1792	0.034*
H(17)	0.0881	0.2107	1.2816	0.033*
H(18)	0.1144	0.3695	1.2326	0.032*
H(19)	0.0906	0.4079	1.0813	0.023*
H(21)	−0.1321	0.3723	1.0186	0.024*
H(22)	−0.2902	0.4575	0.9774	0.032*
H(23)	−0.3341	0.4932	0.8279	0.030*
H(24)	−0.2197	0.4431	0.7187	0.029*
H(25)	−0.0656	0.3535	0.7587	0.025*
H(26)	0.1697	0.5039	0.8585	0.029*
H(27)	0.0784	0.4402	0.8057	0.029*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pt(1)	0.01313 (9)	0.01225 (9)	0.01551 (9)	0.00037 (9)	0.00053 (6)	−0.00182 (9)
Cl(1)	0.0223 (6)	0.0175 (6)	0.0212 (6)	0.0008 (5)	0.0010 (5)	−0.0066 (4)
Cl(2)	0.0150 (6)	0.0211 (6)	0.0326 (7)	−0.0030 (4)	0.0014 (5)	−0.0064 (5)
P(1)	0.0142 (5)	0.0143 (5)	0.0155 (5)	0.0010 (5)	0.0013 (4)	−0.0010 (5)
P(2)	0.0130 (6)	0.0122 (6)	0.0155 (6)	0.0007 (4)	0.0014 (5)	0.0005 (4)
O(1)	0.0209 (18)	0.024 (2)	0.0172 (17)	0.0041 (15)	0.0050 (14)	0.0029 (14)
O(2)	0.0180 (17)	0.0141 (16)	0.0167 (17)	−0.0023 (14)	0.0024 (14)	0.0011 (13)
C(1)	0.018 (2)	0.015 (2)	0.016 (2)	0.005 (2)	−0.001 (2)	−0.0011 (19)
C(2)	0.023 (2)	0.026 (2)	0.020 (2)	0.005 (2)	−0.001 (2)	−0.006 (2)
C(3)	0.024 (2)	0.028 (3)	0.026 (3)	0.014 (2)	−0.003 (2)	−0.008 (2)
C(4)	0.036 (3)	0.019 (2)	0.027 (3)	0.010 (2)	−0.005 (2)	−0.004 (2)
C(5)	0.041 (3)	0.019 (2)	0.026 (3)	−0.001 (2)	0.002 (2)	0.003 (2)
C(6)	0.021 (2)	0.018 (2)	0.032 (3)	0.006 (2)	0.006 (2)	−0.001 (2)
C(7)	0.012 (2)	0.017 (2)	0.020 (2)	0.0057 (19)	−0.001 (2)	−0.002 (2)
C(8)	0.014 (2)	0.015 (2)	0.025 (2)	0.003 (2)	−0.002 (2)	0.001 (2)
C(9)	0.032 (3)	0.029 (3)	0.018 (2)	0.012 (2)	−0.007 (2)	−0.003 (2)
C(10)	0.021 (2)	0.019 (2)	0.042 (3)	0.004 (2)	−0.012 (2)	−0.015 (2)
C(11)	0.022 (2)	0.017 (2)	0.043 (3)	−0.002 (2)	0.001 (2)	−0.004 (2)
C(12)	0.020 (2)	0.017 (2)	0.029 (2)	0.003 (2)	0.003 (2)	0.001 (2)
C(13)	0.031 (3)	0.040 (3)	0.019 (2)	0.005 (2)	0.005 (2)	0.009 (2)
C(14)	0.013 (2)	0.016 (2)	0.019 (2)	0.0050 (19)	0.0029 (19)	0.0043 (19)
C(15)	0.020 (2)	0.020 (2)	0.027 (2)	−0.002 (2)	0.007 (2)	−0.000 (2)
C(16)	0.032 (3)	0.020 (2)	0.035 (3)	−0.004 (2)	0.009 (2)	0.014 (2)
C(17)	0.028 (3)	0.037 (3)	0.017 (2)	0.004 (2)	0.003 (2)	0.010 (2)
C(18)	0.029 (2)	0.033 (3)	0.019 (2)	−0.002 (2)	0.002 (2)	−0.003 (2)
C(19)	0.025 (2)	0.016 (2)	0.017 (2)	0.002 (2)	0.003 (2)	0.001 (2)
C(20)	0.016 (2)	0.010 (2)	0.023 (2)	−0.0010 (19)	−0.001 (2)	−0.0001 (19)
C(21)	0.021 (2)	0.018 (2)	0.021 (2)	−0.000 (2)	0.002 (2)	−0.001 (2)
C(22)	0.020 (2)	0.028 (3)	0.032 (3)	0.004 (2)	0.003 (2)	−0.007 (2)
C(23)	0.016 (2)	0.016 (2)	0.042 (3)	0.009 (2)	−0.008 (2)	−0.004 (2)
C(24)	0.025 (2)	0.023 (2)	0.024 (2)	−0.002 (2)	−0.011 (2)	0.000 (2)
C(25)	0.019 (2)	0.021 (2)	0.021 (2)	0.001 (2)	−0.001 (2)	0.000 (2)
C(26)	0.026 (2)	0.022 (2)	0.025 (2)	−0.006 (2)	0.004 (2)	0.004 (2)

Geometric parameters (Å, º)

Pt1—Cl1	2.3693 (12)	C(20)—C(25)	1.395 (6)
Pt1—Cl2	2.3533 (12)	C(21)—C(22)	1.385 (7)
Pt1—P1	2.2272 (11)	C(22)—C(23)	1.385 (7)
Pt1—P2	2.2279 (12)	C(23)—C(24)	1.389 (7)
P(1)—O(1)	1.593 (3)	C(24)—C(25)	1.375 (7)
P(1)—C(1)	1.826 (4)	C(2)—H(2)	0.950
P(1)—C(7)	1.815 (4)	C(3)—H(3)	0.950
P(2)—O(2)	1.605 (3)	C(4)—H(4)	0.950
P(2)—C(14)	1.797 (4)	C(5)—H(5)	0.950
P(2)—C(20)	1.821 (4)	C(6)—H(6)	0.950
O(1)—C(13)	1.434 (6)	C(8)—H(8)	0.950
O(2)—C(26)	1.444 (6)	C(9)—H(9)	0.950
C(1)—C(2)	1.385 (7)	C(10)—H(10)	0.950
C(1)—C(6)	1.388 (7)	C(11)—H(11)	0.950
C(2)—C(3)	1.384 (7)	C(12)—H(12)	0.950
C(3)—C(4)	1.375 (7)	C(13)—H(30)	0.980
C(4)—C(5)	1.383 (8)	C(13)—H(31)	0.980
C(5)—C(6)	1.390 (7)	C(13)—H(33)	0.980
C(7)—C(8)	1.396 (6)	C(15)—H(15)	0.950
C(7)—C(12)	1.386 (6)	C(16)—H(16)	0.950
C(8)—C(9)	1.387 (7)	C(17)—H(17)	0.950
C(9)—C(10)	1.385 (7)	C(18)—H(18)	0.950
C(10)—C(11)	1.383 (8)	C(19)—H(19)	0.950
C(11)—C(12)	1.387 (7)	C(21)—H(21)	0.950
C(14)—C(15)	1.390 (6)	C(22)—H(22)	0.950
C(14)—C(19)	1.407 (6)	C(23)—H(23)	0.950
C(15)—C(16)	1.379 (7)	C(24)—H(24)	0.950
C(16)—C(17)	1.395 (7)	C(25)—H(25)	0.950
C(17)—C(18)	1.372 (7)	C(26)—H(28)	0.980
C(18)—C(19)	1.389 (6)	C(26)—H(26)	0.980
C(20)—C(21)	1.398 (7)	C(26)—H(27)	0.980
Cl(1)···C(16)^i	3.518 (5)	H(31)···H(22)^x	3.295
O(2)···C(22)^ii	3.542 (6)	H(31)···H(26)^iii	2.863
C(2)···C(26)^iii	3.478 (7)	H(8)···H(3)^iv	2.974
C(3)···C(3)^iv	3.412 (7)	H(8)···H(24)^vi	3.152
C(4)···C(13)^iii	3.557 (7)	H(9)···Cl(2)^vi	2.968
C(5)···C(13)^iii	3.518 (7)	H(9)···C(25)^vi	3.236
C(13)···C(4)^v	3.557 (7)	H(9)···H(3)^iv	3.125
C(13)···C(5)^v	3.518 (7)	H(9)···H(23)^ii	3.066
C(16)···Cl(1)^i	3.518 (5)	H(9)···H(24)^vi	3.477
C(17)···C(23)^vi	3.589 (7)	H(9)···H(25)^vi	2.663
C(17)···C(24)^vi	3.504 (7)	H(10)···Cl(1)^vi	2.716
C(22)···O(2)^ii	3.542 (6)	H(10)···C(11)^ix	3.287
C(23)···C(17)^vii	3.589 (7)	H(10)···C(23)^ii	3.433
C(24)···C(17)^vii	3.504 (7)	H(10)···H(4)^iv	3.412
C(26)···C(2)^v	3.478 (7)	H(10)···H(31)^vi	3.369
Cl(1)···H(10)^vii	2.716	H(10)···H(11)^ix	2.463
Cl(1)···H(11)^iii	3.298	H(10)···H(22)^xi	3.508
Cl(1)···H(12)^iii	3.049	H(10)···H(22)^ii	3.210
Cl(1)···H(28)^iii	3.085	H(10)···H(23)^ii	2.660
Cl(1)···H(16)^i	2.716	H(11)···Cl(1)^v	3.298
Cl(1)···H(23)^viii	3.462	H(11)···C(10)^ix	3.005
Cl(1)···H(26)^iii	3.294	H(11)···C(11)^ix	3.118
Cl(2)···H(5)^i	2.941	H(11)···C(22)^xi	3.205
Cl(2)···H(9)^vii	2.968	H(11)···C(23)^xi	3.340
Cl(2)···H(16)^i	3.085	H(11)···H(4)^iv	3.506
Cl(2)···H(23)^viii	3.034	H(11)···H(10)^ix	2.463
Cl(2)···H(24)^viii	3.347	H(11)···H(11)^ix	2.682
O(1)···H(26)^iii	3.021	H(11)···H(17)^x	3.291
O(2)···H(21)^ii	3.488	H(11)···H(22)^xi	2.667
O(2)···H(22)^ii	3.270	H(11)···H(22)^ii	3.346
C(1)···H(28)^iii	3.556	H(11)···H(23)^xi	2.935
C(2)···H(3)^iv	3.577	H(12)···Cl(1)^v	3.049
C(2)···H(28)^iii	3.366	H(12)···C(16)^x	3.389
C(2)···H(27)^iii	2.931	H(12)···C(17)^x	3.010
C(3)···H(30)^iii	3.434	H(12)···H(16)^x	3.276
C(3)···H(3)^iv	3.570	H(12)···H(17)^x	2.572
C(3)···H(25)^iii	3.165	H(33)···C(4)^v	3.583
C(3)···H(27)^iii	3.265	H(33)···C(5)^v	3.163
C(4)···H(30)^iii	3.192	H(33)···C(6)^v	3.534
C(4)···H(2)^iv	3.554	H(33)···C(14)^x	3.385
C(4)···H(31)^iii	3.323	H(33)···C(15)^x	3.052
C(4)···H(33)^iii	3.583	H(33)···C(16)^x	2.940
C(5)···H(30)^iii	3.334	H(33)···C(17)^x	3.160
C(5)···H(31)^iii	3.482	H(33)···C(18)^x	3.468
C(5)···H(33)^iii	3.163	H(33)···C(19)^x	3.578
C(6)···H(33)^iii	3.534	H(33)···H(5)^v	3.148
C(6)···H(15)^i	3.594	H(33)···H(15)^x	3.444
C(7)···H(4)^iv	3.363	H(33)···H(16)^x	3.287
C(8)···H(3)^iv	2.999	H(33)···H(21)^x	2.874
C(8)···H(4)^iv	3.324	H(33)···H(26)^iii	3.557
C(9)···H(3)^iv	3.074	H(28)···Cl(1)^v	3.085
C(9)···H(4)^iv	3.166	H(28)···C(1)^v	3.556
C(9)···H(23)^ii	3.255	H(28)···C(2)^v	3.366
C(9)···H(25)^vi	3.353	H(28)···H(2)^v	3.494
C(10)···H(4)^iv	3.001	H(15)···C(6)^i	3.594
C(10)···H(11)^ix	3.005	H(15)···H(5)^i	3.327
C(10)···H(22)^ii	3.115	H(15)···H(6)^i	2.937
C(10)···H(23)^ii	3.024	H(15)···H(33)^xii	3.444
C(11)···H(4)^iv	3.054	H(15)···H(15)^i	3.476
C(11)···H(10)^ix	3.287	H(16)···Cl(1)^i	2.716
C(11)···H(11)^ix	3.118	H(16)···Cl(2)^i	3.085
C(11)···H(17)^x	3.502	H(16)···C(23)^vi	3.387
C(11)···H(22)^xi	3.382	H(16)···C(24)^vi	3.473
C(11)···H(22)^ii	3.209	H(16)···H(6)^i	3.521
C(12)···H(4)^iv	3.235	H(16)···H(12)^xii	3.276
C(12)···H(17)^x	3.125	H(16)···H(33)^xii	3.287
C(13)···H(21)^x	3.259	H(16)···H(23)^vi	2.873
C(13)···H(26)^iii	3.322	H(16)···H(24)^vi	3.051
C(14)···H(33)^xii	3.385	H(17)···C(11)^xii	3.502
C(15)···H(6)^i	3.575	H(17)···C(12)^xii	3.125
C(15)···H(33)^xii	3.052	H(17)···C(23)^vi	3.014
C(16)···H(12)^xii	3.389	H(17)···C(24)^vi	3.217
C(16)···H(33)^xii	2.940	H(17)···H(11)^xii	3.291
C(16)···H(23)^vi	3.468	H(17)···H(12)^xii	2.572
C(16)···H(24)^vi	3.231	H(17)···H(23)^vi	3.009
C(17)···H(12)^xii	3.010	H(17)···H(24)^vi	3.358
C(17)···H(33)^xii	3.160	H(18)···C(23)^ii	3.298
C(17)···H(23)^vi	3.534	H(18)···C(24)^ii	2.980
C(17)···H(24)^vi	3.403	H(18)···C(25)^ii	3.514
C(18)···H(2)^xii	3.374	H(18)···H(2)^xii	2.835
C(18)···H(33)^xii	3.468	H(18)···H(23)^ii	3.477
C(19)···H(33)^xii	3.578	H(18)···H(24)^ii	2.941
C(20)···H(19)^ii	3.259	H(18)···H(27)^ii	3.553
C(21)···H(31)^xii	3.503	H(19)···C(20)^ii	3.259
C(21)···H(19)^ii	2.971	H(19)···C(21)^ii	2.971
C(21)···H(26)^ii	3.170	H(19)···C(22)^ii	2.861
C(22)···H(11)^xiii	3.205	H(19)···C(23)^ii	3.040
C(22)···H(19)^ii	2.861	H(19)···C(24)^ii	3.313
C(22)···H(26)^ii	3.313	H(19)···C(25)^ii	3.422
C(23)···H(10)^ii	3.433	H(19)···H(21)^ii	3.405
C(23)···H(11)^xiii	3.340	H(19)···H(22)^ii	3.250
C(23)···H(16)^vii	3.387	H(19)···H(23)^ii	3.511
C(23)···H(17)^vii	3.014	H(19)···H(27)^ii	3.468
C(23)···H(18)^ii	3.298	H(21)···O(2)^ii	3.488
C(23)···H(19)^ii	3.040	H(21)···C(13)^xii	3.259
C(24)···H(3)^v	3.582	H(21)···C(26)^ii	3.351
C(24)···H(16)^vii	3.473	H(21)···H(5)^i	3.546
C(24)···H(17)^vii	3.217	H(21)···H(31)^xii	2.837
C(24)···H(18)^ii	2.980	H(21)···H(33)^xii	2.874
C(24)···H(19)^ii	3.313	H(21)···H(19)^ii	3.405
C(25)···H(3)^v	3.322	H(21)···H(26)^ii	2.568
C(25)···H(9)^vii	3.236	H(22)···O(2)^ii	3.270
C(25)···H(18)^ii	3.514	H(22)···C(10)^ii	3.115
C(25)···H(19)^ii	3.422	H(22)···C(11)^xiii	3.382
C(26)···H(2)^v	3.340	H(22)···C(11)^ii	3.209
C(26)···H(21)^ii	3.351	H(22)···C(26)^ii	3.471
C(26)···H(22)^ii	3.471	H(22)···H(31)^xii	3.295
H(30)···C(3)^v	3.434	H(22)···H(10)^xiii	3.508
H(30)···C(4)^v	3.192	H(22)···H(10)^ii	3.210
H(30)···C(5)^v	3.334	H(22)···H(11)^xiii	2.667
H(30)···H(4)^v	3.461	H(22)···H(11)^ii	3.346
H(2)···C(4)^iv	3.554	H(22)···H(19)^ii	3.250
H(2)···C(18)^x	3.374	H(22)···H(26)^ii	2.858
H(2)···C(26)^iii	3.340	H(23)···Cl(1)^xiv	3.462
H(2)···H(4)^iv	3.436	H(23)···Cl(2)^xiv	3.034
H(2)···H(28)^iii	3.494	H(23)···C(9)^ii	3.255
H(2)···H(18)^x	2.835	H(23)···C(10)^ii	3.024
H(2)···H(25)^iii	3.480	H(23)···C(16)^vii	3.468
H(2)···H(26)^iii	3.329	H(23)···C(17)^vii	3.534
H(2)···H(27)^iii	2.704	H(23)···H(9)^ii	3.066
H(3)···C(2)^iv	3.577	H(23)···H(10)^ii	2.660
H(3)···C(3)^iv	3.570	H(23)···H(11)^xiii	2.935
H(3)···C(8)^iv	2.999	H(23)···H(16)^vii	2.873
H(3)···C(9)^iv	3.074	H(23)···H(17)^vii	3.009
H(3)···C(24)^iii	3.582	H(23)···H(18)^ii	3.477
H(3)···C(25)^iii	3.322	H(23)···H(19)^ii	3.511
H(3)···H(8)^iv	2.974	H(24)···Cl(2)^xiv	3.347
H(3)···H(9)^iv	3.125	H(24)···C(16)^vii	3.231
H(3)···H(24)^iii	3.112	H(24)···C(17)^vii	3.403
H(3)···H(25)^iii	2.579	H(24)···H(3)^v	3.112
H(3)···H(27)^iii	3.281	H(24)···H(8)^vii	3.152
H(4)···C(7)^iv	3.363	H(24)···H(9)^vii	3.477
H(4)···C(8)^iv	3.324	H(24)···H(16)^vii	3.051
H(4)···C(9)^iv	3.166	H(24)···H(17)^vii	3.358
H(4)···C(10)^iv	3.001	H(24)···H(18)^ii	2.941
H(4)···C(11)^iv	3.054	H(25)···C(3)^v	3.165
H(4)···C(12)^iv	3.235	H(25)···C(9)^vii	3.353
H(4)···H(30)^iii	3.461	H(25)···H(2)^v	3.480
H(4)···H(2)^iv	3.436	H(25)···H(3)^v	2.579
H(4)···H(31)^iii	3.185	H(25)···H(9)^vii	2.663
H(4)···H(10)^iv	3.412	H(26)···Cl(1)^v	3.294
H(4)···H(11)^iv	3.506	H(26)···O(1)^v	3.021
H(5)···Cl(2)^i	2.941	H(26)···C(13)^v	3.322
H(5)···H(31)^iii	3.486	H(26)···C(21)^ii	3.170
H(5)···H(33)^iii	3.148	H(26)···C(22)^ii	3.313
H(5)···H(15)^i	3.327	H(26)···H(2)^v	3.329
H(5)···H(21)^i	3.546	H(26)···H(31)^v	2.863
H(6)···C(15)^i	3.575	H(26)···H(33)^v	3.557
H(6)···H(15)^i	2.937	H(26)···H(21)^ii	2.568
H(6)···H(16)^i	3.521	H(26)···H(22)^ii	2.858
H(31)···C(4)^v	3.323	H(27)···C(2)^v	2.931
H(31)···C(5)^v	3.482	H(27)···C(3)^v	3.265
H(31)···C(21)^x	3.503	H(27)···H(2)^v	2.704
H(31)···H(4)^v	3.185	H(27)···H(3)^v	3.281
H(31)···H(5)^v	3.486	H(27)···H(18)^ii	3.553
H(31)···H(10)^vii	3.369	H(27)···H(19)^ii	3.468
H(31)···H(21)^x	2.837
Cl1—Pt1—Cl2	89.37 (4)	C(1)—C(2)—H(2)	120.0
P1—Pt1—P2	98.14 (4)	C(3)—C(2)—H(2)	120.0
Cl1—Pt1—P1	83.49 (4)	C(2)—C(3)—H(3)	119.9
Cl1—Pt1—P2	175.95 (4)	C(4)—C(3)—H(3)	119.9
Cl2—Pt1—P1	168.82 (4)	C(3)—C(4)—H(4)	119.8
Cl2—Pt1—P2	89.56 (4)	C(5)—C(4)—H(4)	119.8
Pt(1)—P(1)—O(1)	116.11 (12)	C(4)—C(5)—H(5)	120.3
Pt(1)—P(1)—C(1)	111.37 (16)	C(6)—C(5)—H(5)	120.3
Pt(1)—P(1)—C(7)	120.68 (16)	C(1)—C(6)—H(6)	119.8
O(1)—P(1)—C(1)	102.3 (2)	C(5)—C(6)—H(6)	119.8
O(1)—P(1)—C(7)	103.3 (2)	C(7)—C(8)—H(8)	120.0
C(1)—P(1)—C(7)	100.6 (2)	C(9)—C(8)—H(8)	120.0
Pt(1)—P(2)—O(2)	116.82 (13)	C(8)—C(9)—H(9)	120.3
Pt(1)—P(2)—C(14)	114.29 (15)	C(10)—C(9)—H(9)	120.3
Pt(1)—P(2)—C(20)	113.76 (15)	C(9)—C(10)—H(10)	119.7
O(2)—P(2)—C(14)	99.56 (19)	C(11)—C(10)—H(10)	119.7
O(2)—P(2)—C(20)	103.39 (19)	C(10)—C(11)—H(11)	120.0
C(14)—P(2)—C(20)	107.5 (2)	C(12)—C(11)—H(11)	120.0
P(1)—O(1)—C(13)	122.7 (3)	C(7)—C(12)—H(12)	120.0
P(2)—O(2)—C(26)	121.4 (2)	C(11)—C(12)—H(12)	120.0
P(1)—C(1)—C(2)	119.4 (3)	O(1)—C(13)—H(30)	109.5
P(1)—C(1)—C(6)	120.8 (3)	O(1)—C(13)—H(31)	109.5
C(2)—C(1)—C(6)	119.5 (4)	O(1)—C(13)—H(33)	109.5
C(1)—C(2)—C(3)	120.0 (4)	H(30)—C(13)—H(31)	109.5
C(2)—C(3)—C(4)	120.3 (5)	H(30)—C(13)—H(33)	109.5
C(3)—C(4)—C(5)	120.4 (4)	H(31)—C(13)—H(33)	109.5
C(4)—C(5)—C(6)	119.4 (5)	C(14)—C(15)—H(15)	119.8
C(1)—C(6)—C(5)	120.4 (4)	C(16)—C(15)—H(15)	119.8
P(1)—C(7)—C(8)	119.5 (3)	C(15)—C(16)—H(16)	120.0
P(1)—C(7)—C(12)	120.5 (3)	C(17)—C(16)—H(16)	120.0
C(8)—C(7)—C(12)	119.9 (4)	C(16)—C(17)—H(17)	120.0
C(7)—C(8)—C(9)	120.1 (4)	C(18)—C(17)—H(17)	120.0
C(8)—C(9)—C(10)	119.5 (4)	C(17)—C(18)—H(18)	119.7
C(9)—C(10)—C(11)	120.7 (4)	C(19)—C(18)—H(18)	119.6
C(10)—C(11)—C(12)	120.0 (4)	C(14)—C(19)—H(19)	120.3
C(7)—C(12)—C(11)	119.9 (4)	C(18)—C(19)—H(19)	120.3
P(2)—C(14)—C(15)	120.1 (3)	C(20)—C(21)—H(21)	120.0
P(2)—C(14)—C(19)	120.2 (3)	C(22)—C(21)—H(21)	120.0
C(15)—C(14)—C(19)	119.4 (4)	C(21)—C(22)—H(22)	119.9
C(14)—C(15)—C(16)	120.4 (4)	C(23)—C(22)—H(22)	119.9
C(15)—C(16)—C(17)	120.1 (4)	C(22)—C(23)—H(23)	120.0
C(16)—C(17)—C(18)	120.0 (4)	C(24)—C(23)—H(23)	120.0
C(17)—C(18)—C(19)	120.7 (4)	C(23)—C(24)—H(24)	120.1
C(14)—C(19)—C(18)	119.4 (4)	C(25)—C(24)—H(24)	120.1
P(2)—C(20)—C(21)	121.6 (3)	C(20)—C(25)—H(25)	119.5
P(2)—C(20)—C(25)	119.5 (3)	C(24)—C(25)—H(25)	119.5
C(21)—C(20)—C(25)	118.8 (4)	O(2)—C(26)—H(28)	109.5
C(20)—C(21)—C(22)	120.1 (4)	O(2)—C(26)—H(26)	109.5
C(21)—C(22)—C(23)	120.2 (5)	O(2)—C(26)—H(27)	109.5
C(22)—C(23)—C(24)	120.1 (4)	H(28)—C(26)—H(26)	109.5
C(23)—C(24)—C(25)	119.7 (4)	H(28)—C(26)—H(27)	109.5
C(20)—C(25)—C(24)	121.0 (4)	H(26)—C(26)—H(27)	109.5
Cl(1)—Pt(1)—P(1)—O(1)	58.22 (15)	O(2)—P(2)—C(20)—C(25)	80.4 (3)
Cl(1)—Pt(1)—P(1)—C(1)	−58.24 (16)	C(20)—P(2)—O(2)—C(26)	−60.0 (3)
Cl(1)—Pt(1)—P(1)—C(7)	−175.70 (19)	C(14)—P(2)—C(20)—C(21)	8.2 (4)
Cl(2)—Pt(1)—P(1)—O(1)	108.8 (2)	C(14)—P(2)—C(20)—C(25)	−174.9 (3)
Cl(2)—Pt(1)—P(1)—C(1)	−7.6 (3)	C(20)—P(2)—C(14)—C(15)	105.2 (4)
Cl(2)—Pt(1)—P(1)—C(7)	−125.1 (2)	C(20)—P(2)—C(14)—C(19)	−80.9 (4)
Cl(2)—Pt(1)—P(2)—O(2)	−154.11 (14)	P(1)—C(1)—C(2)—C(3)	175.0 (3)
Cl(2)—Pt(1)—P(2)—C(14)	90.27 (17)	P(1)—C(1)—C(6)—C(5)	−174.2 (3)
Cl(2)—Pt(1)—P(2)—C(20)	−33.70 (17)	C(2)—C(1)—C(6)—C(5)	−0.2 (6)
P(1)—Pt(1)—P(2)—O(2)	34.03 (14)	C(6)—C(1)—C(2)—C(3)	0.9 (7)
P(1)—Pt(1)—P(2)—C(14)	−81.59 (17)	C(1)—C(2)—C(3)—C(4)	−0.3 (6)
P(1)—Pt(1)—P(2)—C(20)	154.44 (17)	C(2)—C(3)—C(4)—C(5)	−1.2 (8)
P(2)—Pt(1)—P(1)—O(1)	−118.04 (15)	C(3)—C(4)—C(5)—C(6)	1.9 (7)
P(2)—Pt(1)—P(1)—C(1)	125.50 (16)	C(4)—C(5)—C(6)—C(1)	−1.2 (7)
P(2)—Pt(1)—P(1)—C(7)	8.04 (19)	P(1)—C(7)—C(8)—C(9)	177.3 (3)
Pt(1)—P(1)—O(1)—C(13)	30.6 (3)	P(1)—C(7)—C(12)—C(11)	−176.5 (3)
Pt(1)—P(1)—C(1)—C(2)	155.6 (3)	C(8)—C(7)—C(12)—C(11)	0.2 (5)
Pt(1)—P(1)—C(1)—C(6)	−30.4 (4)	C(12)—C(7)—C(8)—C(9)	0.6 (7)
Pt(1)—P(1)—C(7)—C(8)	65.7 (4)	C(7)—C(8)—C(9)—C(10)	−1.8 (7)
Pt(1)—P(1)—C(7)—C(12)	−117.6 (3)	C(8)—C(9)—C(10)—C(11)	2.2 (7)
O(1)—P(1)—C(1)—C(2)	31.0 (4)	C(9)—C(10)—C(11)—C(12)	−1.4 (7)
O(1)—P(1)—C(1)—C(6)	−155.0 (3)	C(10)—C(11)—C(12)—C(7)	0.2 (5)
C(1)—P(1)—O(1)—C(13)	152.1 (3)	P(2)—C(14)—C(15)—C(16)	173.0 (3)
O(1)—P(1)—C(7)—C(8)	−162.6 (3)	P(2)—C(14)—C(19)—C(18)	−173.4 (3)
O(1)—P(1)—C(7)—C(12)	14.1 (4)	C(15)—C(14)—C(19)—C(18)	0.6 (7)
C(7)—P(1)—O(1)—C(13)	−103.8 (3)	C(19)—C(14)—C(15)—C(16)	−1.0 (7)
C(1)—P(1)—C(7)—C(8)	−57.1 (4)	C(14)—C(15)—C(16)—C(17)	1.0 (7)
C(1)—P(1)—C(7)—C(12)	119.6 (4)	C(15)—C(16)—C(17)—C(18)	−0.6 (7)
C(7)—P(1)—C(1)—C(2)	−75.3 (4)	C(16)—C(17)—C(18)—C(19)	0.2 (6)
C(7)—P(1)—C(1)—C(6)	98.7 (4)	C(17)—C(18)—C(19)—C(14)	−0.2 (5)
Pt(1)—P(2)—O(2)—C(26)	65.8 (3)	P(2)—C(20)—C(21)—C(22)	176.7 (3)
Pt(1)—P(2)—C(14)—C(15)	−22.1 (4)	P(2)—C(20)—C(25)—C(24)	−175.6 (3)
Pt(1)—P(2)—C(14)—C(19)	151.8 (3)	C(21)—C(20)—C(25)—C(24)	1.4 (7)
Pt(1)—P(2)—C(20)—C(21)	135.8 (3)	C(25)—C(20)—C(21)—C(22)	−0.2 (5)
Pt(1)—P(2)—C(20)—C(25)	−47.3 (4)	C(20)—C(21)—C(22)—C(23)	−0.6 (7)
O(2)—P(2)—C(14)—C(15)	−147.4 (3)	C(21)—C(22)—C(23)—C(24)	0.2 (6)
O(2)—P(2)—C(14)—C(19)	26.5 (4)	C(22)—C(23)—C(24)—C(25)	1.0 (7)
C(14)—P(2)—O(2)—C(26)	−170.7 (3)	C(23)—C(24)—C(25)—C(20)	−1.8 (7)
O(2)—P(2)—C(20)—C(21)	−96.5 (4)

Symmetry codes: (i) −x, −y, −z+2; (ii) −x, −y+1, −z+2; (iii) −x+1/2, y−1/2, −z+3/2; (iv) −x+1, −y, −z+2; (v) −x+1/2, y+1/2, −z+3/2; (vi) x+1/2, −y+1/2, z+1/2; (vii) x−1/2, −y+1/2, z−1/2; (viii) −x−1/2, y−1/2, −z+3/2; (ix) −x+1, −y+1, −z+2; (x) x+1/2, −y+1/2, z−1/2; (xi) x+1, y, z; (xii) x−1/2, −y+1/2, z+1/2; (xiii) x−1, y, z; (xiv) −x−1/2, y+1/2, −z+3/2.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C10—H10···Cl1^vi	0.95	2.72	3.642 (6)	165
C16—H16···Cl1^i	0.95	2.72	3.518 (5)	143
C4—H4···Cg1^iv	0.95	2.88	3.692 (5)	145
C19—H19···Cg2^ii	0.95	2.83	3.641 (4)	144

Symmetry codes: (i) −x, −y, −z+2; (ii) −x, −y+1, −z+2; (iv) −x+1, −y, −z+2; (vi) x+1/2, −y+1/2, z+1/2.