Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S010827011002442X/ga3151sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S010827011002442X/ga3151Isup2.hkl |
CCDC reference: 790627
For related literature, see: Allen (2002); Blake et al. (2009); Chai et al. (2005); Christou (1989); Libby et al. (1991); Peters et al. (1999); Shannon & Prewitt (1969, 1970); Sheldrick (2008); Veith et al. (2007); Vincent et al. (1989); Wang et al. (1991); Wiberg et al. (2002).
A solution of 1,8-C10H6(NSiiPr3)2Li(THF)MnCl(THF) (0.075 g, 0.11 mmol; Blake et al., 2009) in toluene (10 ml) was added to a stirred slurry of NaOtBu (0.010 g, 0.11 mmol) in toluene (10 ml) and the mixture stirred at room temperature for 24 h. Removal of volatiles in vacuo gave a brown solid, which was extracted with hexanes (10 ml). The solution was filtered and concentrated to ca 5 ml, which yielded brown crystals of [1,8-C10H6(NSiiPr3)2Mn(µ3-O)Na(THF)]2, (I), after storage at 238 K.
The intensity of the diffraction falls off very steeply above ca 2θ = 50°, and accordingly a cut-off was applied at 2θ = 50.2°. This feature appeared consistent throughout the frame set, suggesting that no changes occurred to the crystal during data collection.
Methyl H atoms were located in circular difference Fourier syntheses and thereafter refined as part of a rigid rotating group, with C—H = 0.98 Å and Uiso(H) = 1.5Ueq(C). The remaining H atoms were placed geometrically and refined with C—H(aromatic) = 0.95 Å, C—H(methylene) = 0.99 Å and C—H(methine) = 1.00 Å, and with Uiso(H) = 1.2Ueq(C). Rigid-bond restraints (Sheldrick, 2008), with effective standard deviations of 0.01 Å2 for 1,2-atom pairs and 0.001 Å2 for 1,3-atom pairs, were applied to the anisotropic displacement parameters of the THF atoms (O2/C29–C32).
Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT (Bruker, 2002) and SHELXTL (Sheldrick, 2008); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: publCIF (Westrip, 2010) and PLATON (Spek, 2009).
[Na2Mn2(C32H56N2OSi2)2O2] | F(000) = 2736 |
Mr = 1269.80 | Dx = 1.216 Mg m−3 |
Orthorhombic, Pbcn | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2n 2ab | Cell parameters from 7869 reflections |
a = 25.209 (2) Å | θ = 2.3–27.1° |
b = 17.6946 (15) Å | µ = 0.49 mm−1 |
c = 15.5541 (13) Å | T = 150 K |
V = 6938.0 (10) Å3 | Plate, brown |
Z = 4 | 0.27 × 0.27 × 0.07 mm |
Bruker SMART APEX CCD area-detector diffractometer | 6173 independent reflections |
Radiation source: sealed tube | 5327 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.047 |
Detector resolution: 8.366 pixels mm-1 | θmax = 25.1°, θmin = 2.3° |
ω rotation with narrow frames scans | h = −24→30 |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | k = −21→20 |
Tmin = 0.652, Tmax = 0.746 | l = −17→18 |
34383 measured reflections |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.067 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.155 | H-atom parameters constrained |
S = 1.21 | w = 1/[σ2(Fo2) + (0.061P)2 + 9.211P] where P = (Fo2 + 2Fc2)/3 |
6173 reflections | (Δ/σ)max = 0.001 |
373 parameters | Δρmax = 0.59 e Å−3 |
10 restraints | Δρmin = −0.35 e Å−3 |
[Na2Mn2(C32H56N2OSi2)2O2] | V = 6938.0 (10) Å3 |
Mr = 1269.80 | Z = 4 |
Orthorhombic, Pbcn | Mo Kα radiation |
a = 25.209 (2) Å | µ = 0.49 mm−1 |
b = 17.6946 (15) Å | T = 150 K |
c = 15.5541 (13) Å | 0.27 × 0.27 × 0.07 mm |
Bruker SMART APEX CCD area-detector diffractometer | 6173 independent reflections |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | 5327 reflections with I > 2σ(I) |
Tmin = 0.652, Tmax = 0.746 | Rint = 0.047 |
34383 measured reflections |
R[F2 > 2σ(F2)] = 0.067 | 10 restraints |
wR(F2) = 0.155 | H-atom parameters constrained |
S = 1.21 | Δρmax = 0.59 e Å−3 |
6173 reflections | Δρmin = −0.35 e Å−3 |
373 parameters |
x | y | z | Uiso*/Ueq | ||
Mn1 | 0.45141 (2) | 0.72512 (3) | 0.78677 (3) | 0.02163 (16) | |
Si1 | 0.42062 (4) | 0.82489 (6) | 0.97030 (7) | 0.0284 (2) | |
Na1 | 0.40911 (6) | 0.74511 (10) | 0.59699 (10) | 0.0433 (4) | |
O1 | 0.47915 (9) | 0.71703 (13) | 0.67526 (15) | 0.0241 (5) | |
N1 | 0.42181 (11) | 0.80197 (15) | 0.86268 (18) | 0.0244 (6) | |
C1 | 0.40060 (14) | 0.8528 (2) | 0.8021 (2) | 0.0277 (8) | |
Si2 | 0.36400 (4) | 0.59814 (6) | 0.74039 (7) | 0.0293 (3) | |
O2 | 0.36783 (14) | 0.75504 (19) | 0.4689 (2) | 0.0599 (9) | |
N2 | 0.37806 (11) | 0.69412 (16) | 0.7531 (2) | 0.0269 (7) | |
C2 | 0.41805 (17) | 0.9275 (2) | 0.7992 (3) | 0.0372 (9) | |
H2 | 0.4489 | 0.9414 | 0.8306 | 0.045* | |
C3 | 0.3915 (2) | 0.9825 (2) | 0.7512 (3) | 0.0475 (11) | |
H3 | 0.4039 | 1.0332 | 0.7520 | 0.057* | |
C4 | 0.3486 (2) | 0.9647 (2) | 0.7041 (3) | 0.0466 (11) | |
H4 | 0.3303 | 1.0033 | 0.6737 | 0.056* | |
C5 | 0.33033 (17) | 0.8886 (2) | 0.6991 (2) | 0.0374 (9) | |
C6 | 0.28456 (19) | 0.8699 (3) | 0.6520 (3) | 0.0488 (12) | |
H6 | 0.2662 | 0.9082 | 0.6212 | 0.059* | |
C7 | 0.26663 (17) | 0.7984 (3) | 0.6501 (3) | 0.0478 (11) | |
H7 | 0.2338 | 0.7876 | 0.6226 | 0.057* | |
C8 | 0.29556 (15) | 0.7392 (2) | 0.6882 (3) | 0.0372 (9) | |
H8 | 0.2822 | 0.6891 | 0.6846 | 0.045* | |
C9 | 0.34357 (14) | 0.7523 (2) | 0.7311 (2) | 0.0265 (8) | |
C10 | 0.35890 (14) | 0.8301 (2) | 0.7436 (2) | 0.0285 (8) | |
C11 | 0.30765 (17) | 0.8202 (3) | 0.9726 (3) | 0.0511 (12) | |
H11A | 0.2749 | 0.8380 | 0.9997 | 0.077* | |
H11B | 0.3140 | 0.7675 | 0.9887 | 0.077* | |
H11C | 0.3043 | 0.8240 | 0.9099 | 0.077* | |
C12 | 0.35418 (16) | 0.8689 (2) | 1.0027 (3) | 0.0375 (9) | |
H12 | 0.3532 | 0.8673 | 1.0669 | 0.045* | |
C13 | 0.34472 (17) | 0.9513 (2) | 0.9783 (3) | 0.0457 (11) | |
H13A | 0.3430 | 0.9559 | 0.9156 | 0.069* | |
H13B | 0.3739 | 0.9825 | 1.0003 | 0.069* | |
H13C | 0.3112 | 0.9686 | 1.0034 | 0.069* | |
C14 | 0.52835 (16) | 0.8800 (2) | 0.9599 (3) | 0.0439 (11) | |
H14A | 0.5504 | 0.9255 | 0.9635 | 0.066* | |
H14B | 0.5231 | 0.8665 | 0.8994 | 0.066* | |
H14C | 0.5461 | 0.8383 | 0.9897 | 0.066* | |
C15 | 0.47425 (16) | 0.8952 (2) | 1.0022 (3) | 0.0366 (9) | |
H15 | 0.4623 | 0.9453 | 0.9798 | 0.044* | |
C16 | 0.4806 (2) | 0.9052 (3) | 1.0998 (3) | 0.0531 (12) | |
H16A | 0.4936 | 0.8579 | 1.1251 | 0.080* | |
H16B | 0.4462 | 0.9181 | 1.1252 | 0.080* | |
H16C | 0.5061 | 0.9458 | 1.1113 | 0.080* | |
C17 | 0.48236 (17) | 0.6986 (2) | 1.0332 (3) | 0.0416 (10) | |
H17A | 0.5057 | 0.7308 | 1.0678 | 0.062* | |
H17B | 0.4961 | 0.6954 | 0.9744 | 0.062* | |
H17C | 0.4810 | 0.6479 | 1.0585 | 0.062* | |
C18 | 0.42650 (16) | 0.7324 (2) | 1.0317 (3) | 0.0366 (9) | |
H18 | 0.4042 | 0.6953 | 0.9993 | 0.044* | |
C19 | 0.4038 (2) | 0.7337 (3) | 1.1241 (3) | 0.0528 (12) | |
H19A | 0.4048 | 0.6825 | 1.1483 | 0.079* | |
H19B | 0.3671 | 0.7517 | 1.1228 | 0.079* | |
H19C | 0.4252 | 0.7675 | 1.1599 | 0.079* | |
C20 | 0.29409 (19) | 0.4865 (3) | 0.8192 (3) | 0.0522 (12) | |
H20A | 0.3204 | 0.4716 | 0.8623 | 0.078* | |
H20B | 0.2996 | 0.4571 | 0.7665 | 0.078* | |
H20C | 0.2584 | 0.4769 | 0.8415 | 0.078* | |
C21 | 0.30020 (16) | 0.5712 (2) | 0.7991 (3) | 0.0390 (10) | |
H21 | 0.2701 | 0.5852 | 0.7603 | 0.047* | |
C22 | 0.29364 (18) | 0.6179 (3) | 0.8816 (3) | 0.0484 (11) | |
H22A | 0.2612 | 0.6023 | 0.9114 | 0.073* | |
H22B | 0.2912 | 0.6717 | 0.8668 | 0.073* | |
H22C | 0.3243 | 0.6097 | 0.9191 | 0.073* | |
C23 | 0.4252 (2) | 0.4610 (2) | 0.7654 (4) | 0.0563 (13) | |
H23A | 0.4586 | 0.4396 | 0.7868 | 0.084* | |
H23B | 0.4230 | 0.4534 | 0.7030 | 0.084* | |
H23C | 0.3953 | 0.4359 | 0.7934 | 0.084* | |
C24 | 0.42352 (16) | 0.5462 (2) | 0.7854 (3) | 0.0376 (9) | |
H24 | 0.4552 | 0.5687 | 0.7565 | 0.045* | |
C25 | 0.43202 (18) | 0.5582 (2) | 0.8819 (3) | 0.0450 (11) | |
H25A | 0.4028 | 0.5350 | 0.9138 | 0.067* | |
H25B | 0.4332 | 0.6125 | 0.8943 | 0.067* | |
H25C | 0.4656 | 0.5349 | 0.8993 | 0.067* | |
C26 | 0.3207 (2) | 0.5150 (3) | 0.5934 (3) | 0.0606 (14) | |
H26A | 0.3183 | 0.5131 | 0.5305 | 0.091* | |
H26B | 0.2855 | 0.5245 | 0.6176 | 0.091* | |
H26C | 0.3342 | 0.4667 | 0.6150 | 0.091* | |
C27 | 0.35826 (17) | 0.5782 (2) | 0.6199 (3) | 0.0407 (10) | |
H27 | 0.3429 | 0.6253 | 0.5944 | 0.049* | |
C28 | 0.41262 (18) | 0.5685 (3) | 0.5765 (3) | 0.0467 (11) | |
H28A | 0.4259 | 0.5173 | 0.5871 | 0.070* | |
H28B | 0.4376 | 0.6054 | 0.6003 | 0.070* | |
H28C | 0.4090 | 0.5767 | 0.5144 | 0.070* | |
C29 | 0.3572 (3) | 0.6956 (3) | 0.4095 (4) | 0.0757 (17) | |
H29A | 0.3351 | 0.6561 | 0.4371 | 0.091* | |
H29B | 0.3908 | 0.6722 | 0.3901 | 0.091* | |
C30 | 0.3282 (3) | 0.7295 (3) | 0.3344 (3) | 0.0718 (15) | |
H30A | 0.3405 | 0.7070 | 0.2796 | 0.086* | |
H30B | 0.2895 | 0.7217 | 0.3398 | 0.086* | |
C31 | 0.3417 (2) | 0.8109 (3) | 0.3387 (4) | 0.0745 (15) | |
H31A | 0.3137 | 0.8426 | 0.3124 | 0.089* | |
H31B | 0.3761 | 0.8217 | 0.3104 | 0.089* | |
C32 | 0.3448 (3) | 0.8224 (4) | 0.4343 (5) | 0.100 (2) | |
H32A | 0.3672 | 0.8668 | 0.4480 | 0.120* | |
H32B | 0.3090 | 0.8307 | 0.4586 | 0.120* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Mn1 | 0.0210 (3) | 0.0221 (3) | 0.0218 (3) | −0.0003 (2) | 0.0002 (2) | −0.0020 (2) |
Si1 | 0.0308 (5) | 0.0298 (5) | 0.0245 (5) | 0.0002 (4) | 0.0022 (4) | −0.0050 (4) |
Na1 | 0.0359 (9) | 0.0592 (10) | 0.0348 (9) | −0.0016 (8) | −0.0039 (7) | 0.0007 (8) |
O1 | 0.0220 (12) | 0.0293 (12) | 0.0211 (13) | 0.0007 (10) | 0.0004 (10) | −0.0017 (10) |
N1 | 0.0269 (15) | 0.0223 (14) | 0.0241 (16) | 0.0004 (12) | 0.0014 (12) | −0.0060 (12) |
C1 | 0.0299 (19) | 0.0295 (18) | 0.0237 (19) | 0.0028 (15) | 0.0079 (15) | −0.0015 (15) |
Si2 | 0.0282 (5) | 0.0280 (5) | 0.0316 (6) | −0.0072 (4) | 0.0016 (4) | −0.0039 (4) |
O2 | 0.057 (2) | 0.065 (2) | 0.0574 (19) | 0.0079 (17) | −0.0162 (16) | −0.0167 (16) |
N2 | 0.0205 (14) | 0.0280 (15) | 0.0321 (17) | −0.0023 (12) | 0.0006 (13) | −0.0037 (13) |
C2 | 0.049 (2) | 0.0295 (19) | 0.033 (2) | −0.0041 (18) | 0.0042 (19) | −0.0016 (17) |
C3 | 0.075 (3) | 0.025 (2) | 0.042 (3) | 0.003 (2) | 0.014 (2) | 0.0032 (19) |
C4 | 0.068 (3) | 0.037 (2) | 0.035 (2) | 0.021 (2) | 0.007 (2) | 0.0090 (19) |
C5 | 0.045 (2) | 0.043 (2) | 0.025 (2) | 0.0132 (19) | 0.0038 (18) | −0.0012 (17) |
C6 | 0.054 (3) | 0.055 (3) | 0.037 (2) | 0.027 (2) | −0.009 (2) | 0.001 (2) |
C7 | 0.033 (2) | 0.070 (3) | 0.041 (3) | 0.015 (2) | −0.0073 (19) | −0.006 (2) |
C8 | 0.030 (2) | 0.049 (2) | 0.033 (2) | 0.0015 (18) | −0.0020 (17) | −0.0031 (19) |
C9 | 0.0241 (18) | 0.0332 (18) | 0.0223 (18) | 0.0052 (15) | 0.0041 (14) | −0.0040 (15) |
C10 | 0.0305 (19) | 0.0298 (18) | 0.0251 (19) | 0.0056 (16) | 0.0071 (15) | −0.0014 (15) |
C11 | 0.036 (2) | 0.066 (3) | 0.051 (3) | −0.004 (2) | 0.011 (2) | −0.003 (2) |
C12 | 0.039 (2) | 0.045 (2) | 0.028 (2) | 0.0061 (18) | 0.0065 (17) | −0.0081 (18) |
C13 | 0.038 (2) | 0.051 (3) | 0.048 (3) | 0.012 (2) | 0.005 (2) | −0.007 (2) |
C14 | 0.037 (2) | 0.037 (2) | 0.058 (3) | −0.0043 (18) | 0.000 (2) | −0.015 (2) |
C15 | 0.038 (2) | 0.033 (2) | 0.039 (2) | −0.0009 (17) | −0.0030 (18) | −0.0084 (18) |
C16 | 0.062 (3) | 0.053 (3) | 0.045 (3) | −0.004 (2) | −0.009 (2) | −0.020 (2) |
C17 | 0.047 (3) | 0.041 (2) | 0.037 (2) | 0.005 (2) | −0.0013 (19) | 0.0031 (19) |
C18 | 0.042 (2) | 0.036 (2) | 0.032 (2) | 0.0010 (18) | 0.0043 (18) | 0.0027 (17) |
C19 | 0.067 (3) | 0.057 (3) | 0.033 (2) | 0.009 (2) | 0.013 (2) | 0.011 (2) |
C20 | 0.051 (3) | 0.052 (3) | 0.054 (3) | −0.026 (2) | 0.006 (2) | 0.005 (2) |
C21 | 0.031 (2) | 0.046 (2) | 0.040 (2) | −0.0123 (18) | 0.0027 (18) | 0.0040 (19) |
C22 | 0.042 (2) | 0.057 (3) | 0.046 (3) | −0.002 (2) | 0.014 (2) | 0.002 (2) |
C23 | 0.062 (3) | 0.027 (2) | 0.080 (4) | 0.001 (2) | 0.005 (3) | 0.000 (2) |
C24 | 0.035 (2) | 0.0240 (18) | 0.054 (3) | −0.0046 (16) | 0.0028 (19) | 0.0024 (18) |
C25 | 0.045 (3) | 0.038 (2) | 0.052 (3) | −0.0003 (19) | −0.008 (2) | 0.015 (2) |
C26 | 0.069 (3) | 0.066 (3) | 0.047 (3) | −0.031 (3) | −0.007 (2) | −0.010 (2) |
C27 | 0.046 (2) | 0.040 (2) | 0.037 (2) | −0.0123 (19) | 0.0006 (19) | −0.0081 (19) |
C28 | 0.055 (3) | 0.045 (2) | 0.040 (3) | −0.008 (2) | 0.008 (2) | −0.011 (2) |
C29 | 0.102 (5) | 0.065 (2) | 0.060 (4) | −0.010 (3) | −0.022 (3) | −0.007 (2) |
C30 | 0.090 (4) | 0.090 (4) | 0.036 (2) | −0.005 (3) | −0.008 (2) | 0.003 (2) |
C31 | 0.068 (4) | 0.087 (3) | 0.068 (3) | 0.014 (3) | 0.005 (3) | 0.013 (3) |
C32 | 0.103 (5) | 0.087 (3) | 0.109 (5) | 0.050 (4) | −0.061 (4) | −0.031 (3) |
Mn1—O1i | 1.853 (2) | C14—H14B | 0.9800 |
Mn1—O1 | 1.876 (2) | C14—H14C | 0.9800 |
Mn1—N1 | 1.949 (3) | C15—C16 | 1.537 (6) |
Mn1—N2 | 1.999 (3) | C15—H15 | 1.0000 |
Mn1—C1 | 2.608 (4) | C16—H16A | 0.9800 |
Mn1—Mn1i | 2.7037 (10) | C16—H16B | 0.9800 |
Mn1—Na1 | 3.1585 (17) | C16—H16C | 0.9800 |
Si1—N1 | 1.723 (3) | C17—C18 | 1.530 (6) |
Si1—C18 | 1.901 (4) | C17—H17A | 0.9800 |
Si1—C15 | 1.903 (4) | C17—H17B | 0.9800 |
Si1—C12 | 1.915 (4) | C17—H17C | 0.9800 |
Na1—O1 | 2.201 (3) | C18—C19 | 1.548 (6) |
Na1—O2 | 2.254 (4) | C18—H18 | 1.0000 |
Na1—C9 | 2.665 (4) | C19—H19A | 0.9800 |
Na1—N2 | 2.706 (4) | C19—H19B | 0.9800 |
Na1—C14i | 2.994 (4) | C19—H19C | 0.9800 |
Na1—C10 | 3.010 (4) | C20—C21 | 1.539 (6) |
O1—Mn1i | 1.853 (2) | C20—H20A | 0.9800 |
N1—C1 | 1.408 (5) | C20—H20B | 0.9800 |
C1—C2 | 1.394 (5) | C20—H20C | 0.9800 |
C1—C10 | 1.447 (5) | C21—C22 | 1.535 (6) |
Si2—N2 | 1.746 (3) | C21—H21 | 1.0000 |
Si2—C24 | 1.893 (4) | C22—H22A | 0.9800 |
Si2—C21 | 1.910 (4) | C22—H22B | 0.9800 |
Si2—C27 | 1.913 (4) | C22—H22C | 0.9800 |
O2—C29 | 1.425 (6) | C23—C24 | 1.540 (5) |
O2—C32 | 1.431 (7) | C23—H23A | 0.9800 |
N2—C9 | 1.391 (5) | C23—H23B | 0.9800 |
C2—C3 | 1.398 (6) | C23—H23C | 0.9800 |
C2—H2 | 0.9500 | C24—C25 | 1.530 (6) |
C3—C4 | 1.343 (7) | C24—H24 | 1.0000 |
C3—H3 | 0.9500 | C25—H25A | 0.9800 |
C4—C5 | 1.426 (6) | C25—H25B | 0.9800 |
C4—H4 | 0.9500 | C25—H25C | 0.9800 |
C5—C6 | 1.406 (6) | C26—C27 | 1.521 (6) |
C5—C10 | 1.439 (5) | C26—H26A | 0.9800 |
C6—C7 | 1.345 (7) | C26—H26B | 0.9800 |
C6—H6 | 0.9500 | C26—H26C | 0.9800 |
C7—C8 | 1.406 (6) | C27—C28 | 1.537 (6) |
C7—H7 | 0.9500 | C27—H27 | 1.0000 |
C8—C9 | 1.402 (5) | C28—H28A | 0.9800 |
C8—H8 | 0.9500 | C28—H28B | 0.9800 |
C9—C10 | 1.442 (5) | C28—H28C | 0.9800 |
C11—C12 | 1.529 (6) | C29—C30 | 1.503 (7) |
C11—H11A | 0.9800 | C29—H29A | 0.9900 |
C11—H11B | 0.9800 | C29—H29B | 0.9900 |
C11—H11C | 0.9800 | C30—C31 | 1.481 (8) |
C12—C13 | 1.525 (6) | C30—H30A | 0.9900 |
C12—H12 | 1.0000 | C30—H30B | 0.9900 |
C13—H13A | 0.9800 | C31—C32 | 1.503 (9) |
C13—H13B | 0.9800 | C31—H31A | 0.9900 |
C13—H13C | 0.9800 | C31—H31B | 0.9900 |
C14—C15 | 1.538 (6) | C32—H32A | 0.9900 |
C14—H14A | 0.9800 | C32—H32B | 0.9900 |
O1i—Mn1—O1 | 86.37 (11) | C12—C13—H13A | 109.5 |
O1i—Mn1—N1 | 102.86 (11) | C12—C13—H13B | 109.5 |
O1—Mn1—N1 | 139.12 (11) | H13A—C13—H13B | 109.5 |
O1i—Mn1—N2 | 159.45 (11) | C12—C13—H13C | 109.5 |
O1—Mn1—N2 | 94.67 (12) | H13A—C13—H13C | 109.5 |
N1—Mn1—N2 | 89.78 (12) | H13B—C13—H13C | 109.5 |
O1i—Mn1—C1 | 120.12 (11) | C15—C14—H14A | 109.5 |
O1—Mn1—C1 | 109.50 (11) | C15—C14—H14B | 109.5 |
N1—Mn1—C1 | 32.04 (12) | H14A—C14—H14B | 109.5 |
N2—Mn1—C1 | 78.89 (12) | C15—C14—H14C | 109.5 |
O1i—Mn1—Mn1i | 43.85 (7) | H14A—C14—H14C | 109.5 |
O1—Mn1—Mn1i | 43.19 (7) | H14B—C14—H14C | 109.5 |
N1—Mn1—Mn1i | 127.09 (9) | C16—C15—C14 | 110.5 (4) |
N2—Mn1—Mn1i | 136.66 (9) | C16—C15—Si1 | 114.0 (3) |
C1—Mn1—Mn1i | 118.93 (8) | C14—C15—Si1 | 113.8 (3) |
O1i—Mn1—Na1 | 128.71 (8) | C16—C15—H15 | 105.9 |
O1—Mn1—Na1 | 43.12 (8) | C14—C15—H15 | 105.9 |
N1—Mn1—Na1 | 111.02 (9) | Si1—C15—H15 | 105.9 |
N2—Mn1—Na1 | 58.22 (10) | C15—C16—H16A | 109.5 |
C1—Mn1—Na1 | 79.78 (9) | C15—C16—H16B | 109.5 |
Mn1i—Mn1—Na1 | 84.86 (4) | H16A—C16—H16B | 109.5 |
N1—Si1—C18 | 106.49 (16) | C15—C16—H16C | 109.5 |
N1—Si1—C15 | 113.25 (17) | H16A—C16—H16C | 109.5 |
C18—Si1—C15 | 112.14 (19) | H16B—C16—H16C | 109.5 |
N1—Si1—C12 | 111.51 (17) | C18—C17—H17A | 109.5 |
C18—Si1—C12 | 106.66 (18) | C18—C17—H17B | 109.5 |
C15—Si1—C12 | 106.66 (18) | H17A—C17—H17B | 109.5 |
O1—Na1—O2 | 151.22 (13) | C18—C17—H17C | 109.5 |
O1—Na1—C9 | 94.31 (11) | H17A—C17—H17C | 109.5 |
O2—Na1—C9 | 113.70 (14) | H17B—C17—H17C | 109.5 |
O1—Na1—N2 | 70.15 (10) | C17—C18—C19 | 109.3 (3) |
O2—Na1—N2 | 133.26 (13) | C17—C18—Si1 | 114.6 (3) |
C9—Na1—N2 | 30.00 (10) | C19—C18—Si1 | 115.1 (3) |
O1—Na1—C14i | 85.47 (11) | C17—C18—H18 | 105.6 |
O2—Na1—C14i | 85.41 (14) | C19—C18—H18 | 105.6 |
C9—Na1—C14i | 121.31 (13) | Si1—C18—H18 | 105.6 |
N2—Na1—C14i | 133.09 (13) | C18—C19—H19A | 109.5 |
O1—Na1—C10 | 91.78 (11) | C18—C19—H19B | 109.5 |
O2—Na1—C10 | 115.87 (13) | H19A—C19—H19B | 109.5 |
C9—Na1—C10 | 28.62 (10) | C18—C19—H19C | 109.5 |
N2—Na1—C10 | 50.60 (10) | H19A—C19—H19C | 109.5 |
C14i—Na1—C10 | 92.70 (12) | H19B—C19—H19C | 109.5 |
O1—Na1—Mn1 | 35.62 (6) | C21—C20—H20A | 109.5 |
O2—Na1—Mn1 | 172.06 (12) | C21—C20—H20B | 109.5 |
C9—Na1—Mn1 | 58.86 (8) | H20A—C20—H20B | 109.5 |
N2—Na1—Mn1 | 38.89 (7) | C21—C20—H20C | 109.5 |
C14i—Na1—Mn1 | 100.81 (10) | H20A—C20—H20C | 109.5 |
C10—Na1—Mn1 | 59.33 (8) | H20B—C20—H20C | 109.5 |
Mn1i—O1—Mn1 | 92.96 (10) | C22—C21—C20 | 110.1 (4) |
Mn1i—O1—Na1 | 156.41 (14) | C22—C21—Si2 | 110.8 (3) |
Mn1—O1—Na1 | 101.25 (11) | C20—C21—Si2 | 115.1 (3) |
C1—N1—Si1 | 119.6 (2) | C22—C21—H21 | 106.8 |
C1—N1—Mn1 | 100.7 (2) | C20—C21—H21 | 106.8 |
Si1—N1—Mn1 | 139.41 (17) | Si2—C21—H21 | 106.8 |
C2—C1—N1 | 120.5 (3) | C21—C22—H22A | 109.5 |
C2—C1—C10 | 118.2 (3) | C21—C22—H22B | 109.5 |
N1—C1—C10 | 121.3 (3) | H22A—C22—H22B | 109.5 |
C2—C1—Mn1 | 131.6 (3) | C21—C22—H22C | 109.5 |
N1—C1—Mn1 | 47.27 (15) | H22A—C22—H22C | 109.5 |
C10—C1—Mn1 | 93.4 (2) | H22B—C22—H22C | 109.5 |
N2—Si2—C24 | 105.61 (16) | C24—C23—H23A | 109.5 |
N2—Si2—C21 | 111.08 (17) | C24—C23—H23B | 109.5 |
C24—Si2—C21 | 111.68 (19) | H23A—C23—H23B | 109.5 |
N2—Si2—C27 | 107.79 (17) | C24—C23—H23C | 109.5 |
C24—Si2—C27 | 109.5 (2) | H23A—C23—H23C | 109.5 |
C21—Si2—C27 | 111.02 (18) | H23B—C23—H23C | 109.5 |
C29—O2—C32 | 107.2 (4) | C25—C24—C23 | 109.3 (4) |
C29—O2—Na1 | 127.0 (3) | C25—C24—Si2 | 114.0 (3) |
C32—O2—Na1 | 125.7 (3) | C23—C24—Si2 | 115.0 (3) |
C9—N2—Si2 | 124.5 (2) | C25—C24—H24 | 105.9 |
C9—N2—Mn1 | 116.1 (2) | C23—C24—H24 | 105.9 |
Si2—N2—Mn1 | 118.97 (16) | Si2—C24—H24 | 105.9 |
C9—N2—Na1 | 73.36 (19) | C24—C25—H25A | 109.5 |
Si2—N2—Na1 | 106.36 (14) | C24—C25—H25B | 109.5 |
Mn1—N2—Na1 | 82.88 (10) | H25A—C25—H25B | 109.5 |
C1—C2—C3 | 121.8 (4) | C24—C25—H25C | 109.5 |
C1—C2—H2 | 119.1 | H25A—C25—H25C | 109.5 |
C3—C2—H2 | 119.1 | H25B—C25—H25C | 109.5 |
C4—C3—C2 | 120.9 (4) | C27—C26—H26A | 109.5 |
C4—C3—H3 | 119.6 | C27—C26—H26B | 109.5 |
C2—C3—H3 | 119.6 | H26A—C26—H26B | 109.5 |
C3—C4—C5 | 120.8 (4) | C27—C26—H26C | 109.5 |
C3—C4—H4 | 119.6 | H26A—C26—H26C | 109.5 |
C5—C4—H4 | 119.6 | H26B—C26—H26C | 109.5 |
C6—C5—C4 | 121.0 (4) | C26—C27—C28 | 110.7 (4) |
C6—C5—C10 | 119.5 (4) | C26—C27—Si2 | 116.6 (3) |
C4—C5—C10 | 119.5 (4) | C28—C27—Si2 | 112.5 (3) |
C7—C6—C5 | 120.6 (4) | C26—C27—H27 | 105.3 |
C7—C6—H6 | 119.7 | C28—C27—H27 | 105.3 |
C5—C6—H6 | 119.7 | Si2—C27—H27 | 105.3 |
C6—C7—C8 | 121.2 (4) | C27—C28—H28A | 109.5 |
C6—C7—H7 | 119.4 | C27—C28—H28B | 109.5 |
C8—C7—H7 | 119.4 | H28A—C28—H28B | 109.5 |
C9—C8—C7 | 121.7 (4) | C27—C28—H28C | 109.5 |
C9—C8—H8 | 119.2 | H28A—C28—H28C | 109.5 |
C7—C8—H8 | 119.2 | H28B—C28—H28C | 109.5 |
N2—C9—C8 | 122.3 (3) | O2—C29—C30 | 107.5 (5) |
N2—C9—C10 | 120.4 (3) | O2—C29—H29A | 110.2 |
C8—C9—C10 | 116.9 (3) | C30—C29—H29A | 110.2 |
N2—C9—Na1 | 76.64 (19) | O2—C29—H29B | 110.2 |
C8—C9—Na1 | 98.9 (2) | C30—C29—H29B | 110.2 |
C10—C9—Na1 | 89.1 (2) | H29A—C29—H29B | 108.5 |
C5—C10—C9 | 119.2 (3) | C31—C30—C29 | 104.0 (5) |
C5—C10—C1 | 117.8 (3) | C31—C30—H30A | 111.0 |
C9—C10—C1 | 123.0 (3) | C29—C30—H30A | 111.0 |
C5—C10—Na1 | 101.9 (2) | C31—C30—H30B | 111.0 |
C9—C10—Na1 | 62.26 (19) | C29—C30—H30B | 111.0 |
C1—C10—Na1 | 108.0 (2) | H30A—C30—H30B | 109.0 |
C12—C11—H11A | 109.5 | C30—C31—C32 | 100.9 (5) |
C12—C11—H11B | 109.5 | C30—C31—H31A | 111.6 |
H11A—C11—H11B | 109.5 | C32—C31—H31A | 111.6 |
C12—C11—H11C | 109.5 | C30—C31—H31B | 111.6 |
H11A—C11—H11C | 109.5 | C32—C31—H31B | 111.6 |
H11B—C11—H11C | 109.5 | H31A—C31—H31B | 109.4 |
C13—C12—C11 | 110.0 (4) | O2—C32—C31 | 106.3 (5) |
C13—C12—Si1 | 117.4 (3) | O2—C32—H32A | 110.5 |
C11—C12—Si1 | 111.2 (3) | C31—C32—H32A | 110.5 |
C13—C12—H12 | 105.8 | O2—C32—H32B | 110.5 |
C11—C12—H12 | 105.8 | C31—C32—H32B | 110.5 |
Si1—C12—H12 | 105.8 | H32A—C32—H32B | 108.7 |
Symmetry code: (i) −x+1, y, −z+3/2. |
D—H···A | D—H | H···A | D···A | D—H···A |
C17—H17B···O1i | 0.98 | 2.44 | 3.401 (5) | 167 |
C28—H28B···O1 | 0.98 | 2.52 | 3.475 (5) | 165 |
C13—H13A···Cg1 | 0.98 | 2.83 | 3.714 (5) | 150 |
Symmetry code: (i) −x+1, y, −z+3/2. |
Experimental details
Crystal data | |
Chemical formula | [Na2Mn2(C32H56N2OSi2)2O2] |
Mr | 1269.80 |
Crystal system, space group | Orthorhombic, Pbcn |
Temperature (K) | 150 |
a, b, c (Å) | 25.209 (2), 17.6946 (15), 15.5541 (13) |
V (Å3) | 6938.0 (10) |
Z | 4 |
Radiation type | Mo Kα |
µ (mm−1) | 0.49 |
Crystal size (mm) | 0.27 × 0.27 × 0.07 |
Data collection | |
Diffractometer | Bruker SMART APEX CCD area-detector diffractometer |
Absorption correction | Multi-scan (SADABS; Sheldrick, 1996) |
Tmin, Tmax | 0.652, 0.746 |
No. of measured, independent and observed [I > 2σ(I)] reflections | 34383, 6173, 5327 |
Rint | 0.047 |
(sin θ/λ)max (Å−1) | 0.597 |
Refinement | |
R[F2 > 2σ(F2)], wR(F2), S | 0.067, 0.155, 1.21 |
No. of reflections | 6173 |
No. of parameters | 373 |
No. of restraints | 10 |
H-atom treatment | H-atom parameters constrained |
Δρmax, Δρmin (e Å−3) | 0.59, −0.35 |
Computer programs: SMART (Bruker, 2001), SAINT (Bruker, 2002) and SHELXTL (Sheldrick, 2008), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008), publCIF (Westrip, 2010) and PLATON (Spek, 2009).
Mn1—O1i | 1.853 (2) | Na1—O1 | 2.201 (3) |
Mn1—O1 | 1.876 (2) | Na1—O2 | 2.254 (4) |
Mn1—N1 | 1.949 (3) | Na1—C9 | 2.665 (4) |
Mn1—N2 | 1.999 (3) | Na1—N2 | 2.706 (4) |
Mn1—C1 | 2.608 (4) | Na1—C14i | 2.994 (4) |
Mn1—Mn1i | 2.7037 (10) | Na1—C10 | 3.010 (4) |
N1—Mn1—N2 | 89.78 (12) | Mn1i—O1—Na1 | 156.41 (14) |
Mn1i—O1—Mn1 | 92.96 (10) | Mn1—O1—Na1 | 101.25 (11) |
Symmetry code: (i) −x+1, y, −z+3/2. |
D—H···A | D—H | H···A | D···A | D—H···A |
C17—H17B···O1i | 0.98 | 2.44 | 3.401 (5) | 167 |
C28—H28B···O1 | 0.98 | 2.52 | 3.475 (5) | 165 |
C13—H13A···Cg1 | 0.98 | 2.83 | 3.714 (5) | 150 |
Symmetry code: (i) −x+1, y, −z+3/2. |
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Polynuclear transition metal complexes containing oxygen-based bridging ligands are of significant interest as models for bioinorganic systems (Vincent et al., 1989; Christou, 1989; Libby et al., 1991; Wang et al., 1991). In the case of manganese, complexes such as [Mn4O2(O2CR)xLn]y (x = 6 or 7; y = -1, 0, 1) have been used to model the photosynthetic water oxidation centre (WOC) within green plants and cyanobacteria. In this paper we describe the crystallographic characterization of the title compound, [1,8-C10H6(NSiiPr3)2Mn(µ3-O)Na(THF)]2 (THF is tetrahydrofuran), (I), which features a central [Mn2O2Na2]4+ core.
The crystal structure of (I) is shown in Fig. 1, and important bond distances and angles are shown in Table 1. The complex lies across a crystallographic twofold axis and consists of a central [Mn2O2Na2]4+ core, with two oxide groups, each triply bridging, between the two MnIII ions and an Na+ ion. Additional coordination to each MnIII centre is provided by a 1,8-C10H6(NSiiPr3)2 ligand and to the Na+ centres by a THF molecule.
The MnIII centres in (I) are each coordinated by two amide N atoms and two bridging oxides in a tetrahedrally distorted square-planar environment where the mean tetrahedral distortion, defined as the mean of the absolute deviations of the ligand atoms from the MnN2O2 least-squares mean plane, is 0.51 (3) Å. The N1—Mn1—N2 angle is wider than that in 1,8-C10H6(NSiiPr3)2Li(THF)MnCl(THF), (II) [85.83 (7)°; Blake et al., 2009], presumably in part a reflection of the different coordination environments of the metal cations in these two complexes. The Mn—N distances in (I) are significantly shorter than that in (II) [2.1093 (17) Å], due to the smaller ionic radius of MnIII compared with MnII (Shannon & Prewitt, 1969, 1970). In (I), the MnIII centre lies 1.150 (3) Å out of the N1/C1/C10/C9/N2 plane of the ligand, which exhibits a significant twisting of the framework: the amide N atoms are significantly distorted from the naphthalenyl plane [N···naphthalenyl plane distances are 0.460 (5) and -0.518 (5) Å for atoms N1 and N2, respectively].
The Mn2O2 moiety deviates somewhat from planarity, the angle between the O1—Mn1—O1i and O1—Mn1i—O1i planes being 12.10 (4)° [symmetry code: (i) -x + 1, y, -z + 3/2]. The Mn1···Mn1i distance in (I) is longer than that found in [HC(CMeNDipp)2Mn(µ-O)]2, (III) [2.659 (1) Å; Dipp = 2,6-diisopropylphenyl; Chai et al., 2005], but shorter than that for the central Mn2O2 core in [nBu4N][Mn4O2(O2CPh)9H2O], (IV) [2.816 (4) Å; Wang et al., 1991]. The Mn—O distances in (I) are slightly shorter than the analogous values for (IV) [1.900 (11), 1.905 (11), 1.913 (10) and 1.909 (10) Å]. Both these complexes feature µ3-bridging oxides, between two MnIII centres and one Na+ centre in the case of (I), and between three MnIII centres in the case of (IV).
The Na—O distances in (I) (Table 1) reflect the differing coordination environments around each O atom. The Na1—O1 distance is somewhat shorter than that found in other triply-bridged complexes, e.g. [Ph2SiO]8[AlO2Na]4.5THF, which has these distances in the range 2.204 (5)–2.392 (6) Å (Veith et al., 2007). These differences are presumably a consequence of the differing coordination environments in these two complexes. The Na1—O2 distance in (I) is significantly longer than the Na1—O1 distance, but it lies within the range of other Na—THF interactions in the literature (Allen, 2002) and is very similar to analogous Na—O distances in other complexes, such as [(THF)3Na][(N2)Mo{N(Ad)C6H3-2,6-Me2}3] [2.254 (10) Å; Peters et al., 1999] and Na2Ga4(SitBu3)4.2THF [2.252 (3) Å; Wiberg et al., 2002]. The geometry around atom O1 is highly distorted trigonal pyramidal [Na1—O1—Mn1i = 156.41 (14)°], with atom O1 lying 0.286 (2) Å out of the plane defined by atoms Mn1, Mn1i and Na1.
In addition to the coordination by the triply bridging oxide and the THF molecule, the Na+ centre interacts significantly with atoms C9, C10 and N2 of the 1,8-bis(triisopropylsilylamido)naphthalene ligand (Table 1, Fig. 2). Finally, there is an additional agostic interaction with H14C [Na1···H14Ci = 2.41 Å, Na1···C14i = 2.994 (4) Å and Na1···H14Ci—C14i = 118°], which potentially contributes to the distortion around the bridging oxide.
The dimer of (I) features possible C—H···O interactions (Table 2). However, as these involve bridging O atoms, are quite long and involve unactivated methyl H atoms, they may not be significant in themselves but a result of steric crowding. One methyl H atom is also implicated in a possible intramolecular C—H···π interaction with the ring C1–C5/C10 (Table 2). There are no specific directional intermolecular interactions.