Download citation
Download citation
link to html
The title complex, [ReNCl(C24H20NP2S2)(C8H11P)2], is formed during the reaction of [ReNCl2(Me2PhP)3] with a stoichiometric amount of Na(SPh2PNPPh2S) in dichloromethane/methanol. The equatorial sphere of the six-coordinate complex is occupied by two Me2PhP ligands and the tetraphenyldithioimidodiphosphinate anion which binds in a bidentate manner via the sulfur donors. The chloro ligand is arranged in a position trans with respect to the terminal nitrido N atom, with exceptionally long Re-Cl bond lengths [2.598 (4) and 2.632 (5) Å for the two crystallographically independent molecules] due to the structural trans influence of `N3-'.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks renclpsp2, default

pdf

Portable Document Format (PDF) file
Supplementary material

CCDC reference: 128505

-1
Follow Acta Cryst. C
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds