Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805032034/fl6190sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536805032034/fl6190Isup2.hkl |
CCDC reference: 289722
Data collection: KappaCCD Server Software (Nonius, 1997); cell refinement: DENZO-SMN (Otwinowski & Minor, 1997); data reduction: DENZO-SMN; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPIII (Johnson & Burnett, 1996); software used to prepare material for publication: SHELXL97 and WinGX (Farrugia, 1999).
[FePtCl2(C15H14O2P)2]·0.5CH2Cl2 | Z = 2 |
Mr = 878.77 | F(000) = 858 |
Triclinic, P1 | Dx = 1.877 Mg m−3 |
a = 10.6903 (2) Å | Mo Kα radiation, λ = 0.71073 Å |
b = 10.7487 (3) Å | Cell parameters from 3814 reflections |
c = 14.9344 (4) Å | θ = 1–27.5° |
α = 80.926 (1)° | µ = 5.36 mm−1 |
β = 78.379 (1)° | T = 110 K |
γ = 68.302 (1)° | Plate, orange |
V = 1555.24 (7) Å3 | 0.25 × 0.25 × 0.08 mm |
Nonius KappaCCD area-detector diffractometer | 6868 independent reflections |
Radiation source: fine-focus sealed tube | 6137 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.034 |
φ scans (κ = 0) + additional ω scans | θmax = 27.6°, θmin = 2.4° |
Absorption correction: multi-scan (Blessing, 1995) | h = −13→13 |
Tmin = 0.162, Tmax = 0.335 | k = −13→13 |
8983 measured reflections | l = −19→19 |
Refinement on F2 | Primary atom site location: heavy-atom method |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.033 | Hydrogen site location: difference Fourier map |
wR(F2) = 0.077 | H-atom parameters constrained |
S = 1.04 | w = 1/[σ2(Fo2) + (0.0367P)2 + 4.3017P] where P = (Fo2 + 2Fc2)/3 |
6868 reflections | (Δ/σ)max = 0.001 |
393 parameters | Δρmax = 1.21 e Å−3 |
3 restraints | Δρmin = −2.24 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Fe | 0.66901 (6) | 0.99426 (6) | 0.73235 (4) | 0.01098 (13) | |
Pt | 0.773495 (16) | 0.570653 (16) | 0.733488 (11) | 0.00973 (6) | |
Cl1 | 0.67129 (11) | 0.43310 (10) | 0.69361 (7) | 0.0151 (2) | |
Cl2 | 0.88802 (12) | 0.38708 (11) | 0.83033 (8) | 0.0191 (2) | |
P1 | 0.66854 (11) | 0.73839 (11) | 0.63459 (7) | 0.0098 (2) | |
P2 | 0.87406 (11) | 0.68294 (11) | 0.79143 (8) | 0.0109 (2) | |
O1 | 0.4097 (3) | 0.7832 (3) | 0.6072 (2) | 0.0140 (6) | |
O2 | 0.7506 (3) | 0.8469 (3) | 0.4636 (2) | 0.0157 (6) | |
O3 | 0.6872 (3) | 0.6869 (3) | 0.9412 (2) | 0.0150 (6) | |
O4 | 1.1201 (3) | 0.6713 (3) | 0.8162 (2) | 0.0149 (6) | |
C1 | 0.5759 (4) | 0.8963 (4) | 0.6814 (3) | 0.0119 (8) | |
C2 | 0.5230 (4) | 0.9094 (4) | 0.7774 (3) | 0.0121 (8) | |
H2 | 0.5258 | 0.8396 | 0.8233 | 0.015* | |
C3 | 0.4656 (4) | 1.0494 (5) | 0.7888 (3) | 0.0157 (9) | |
H3 | 0.4251 | 1.0867 | 0.8442 | 0.019* | |
C4 | 0.4801 (4) | 1.1225 (4) | 0.7027 (3) | 0.0159 (9) | |
H4 | 0.4509 | 1.2157 | 0.6919 | 0.019* | |
C5 | 0.5471 (4) | 1.0296 (4) | 0.6351 (3) | 0.0149 (9) | |
H5 | 0.5683 | 1.0511 | 0.5725 | 0.018* | |
C6 | 0.8473 (4) | 0.8601 (4) | 0.7630 (3) | 0.0131 (9) | |
C7 | 0.7936 (4) | 0.9588 (4) | 0.8282 (3) | 0.0155 (9) | |
H7 | 0.7709 | 0.9424 | 0.8913 | 0.019* | |
C8 | 0.7811 (5) | 1.0868 (5) | 0.7789 (3) | 0.0167 (9) | |
H8 | 0.7491 | 1.1686 | 0.8044 | 0.020* | |
C9 | 0.8260 (4) | 1.0677 (5) | 0.6848 (3) | 0.0155 (9) | |
H9 | 0.8283 | 1.1350 | 0.6377 | 0.019* | |
C10 | 0.8673 (4) | 0.9283 (4) | 0.6739 (3) | 0.0135 (9) | |
H10 | 0.9010 | 0.8887 | 0.6188 | 0.016* | |
C11 | 0.5456 (4) | 0.7184 (4) | 0.5768 (3) | 0.0130 (9) | |
C12 | 0.5606 (5) | 0.6508 (5) | 0.5050 (3) | 0.0164 (9) | |
H12 | 0.6424 | 0.5993 | 0.4723 | 0.020* | |
C13 | 0.4269 (5) | 0.6729 (5) | 0.4883 (3) | 0.0170 (9) | |
H13 | 0.4045 | 0.6385 | 0.4428 | 0.020* | |
C14 | 0.3397 (5) | 0.7532 (5) | 0.5511 (3) | 0.0168 (9) | |
C15 | 0.1884 (5) | 0.8165 (5) | 0.5687 (3) | 0.0210 (10) | |
H15A | 0.1625 | 0.9111 | 0.5502 | 0.032* | |
H15B | 0.1562 | 0.8029 | 0.6330 | 0.032* | |
H15C | 0.1490 | 0.7762 | 0.5343 | 0.032* | |
C16 | 0.7922 (4) | 0.7542 (4) | 0.5369 (3) | 0.0133 (9) | |
C17 | 0.9231 (5) | 0.6742 (5) | 0.5137 (3) | 0.0160 (9) | |
H17 | 0.9745 | 0.6035 | 0.5507 | 0.019* | |
C18 | 0.9677 (5) | 0.7183 (5) | 0.4221 (3) | 0.0177 (9) | |
H18 | 1.0539 | 0.6829 | 0.3880 | 0.021* | |
C19 | 0.8606 (5) | 0.8218 (5) | 0.3941 (3) | 0.0162 (9) | |
C20 | 0.8406 (5) | 0.9063 (5) | 0.3048 (3) | 0.0235 (11) | |
H20A | 0.9187 | 0.9323 | 0.2815 | 0.035* | |
H20B | 0.7607 | 0.9852 | 0.3141 | 0.035* | |
H20C | 0.8294 | 0.8555 | 0.2614 | 0.035* | |
C21 | 0.8227 (4) | 0.6735 (4) | 0.9131 (3) | 0.0139 (9) | |
C22 | 0.8835 (5) | 0.6608 (5) | 0.9870 (3) | 0.0193 (10) | |
H22 | 0.9736 | 0.6513 | 0.9867 | 0.023* | |
C23 | 0.7808 (5) | 0.6648 (5) | 1.0655 (3) | 0.0216 (10) | |
H23 | 0.7918 | 0.6586 | 1.1264 | 0.026* | |
C24 | 0.6653 (5) | 0.6793 (5) | 1.0354 (3) | 0.0170 (9) | |
C25 | 0.5239 (5) | 0.6905 (5) | 1.0796 (4) | 0.0270 (11) | |
H25A | 0.5176 | 0.6843 | 1.1450 | 0.041* | |
H25B | 0.5021 | 0.6188 | 1.0631 | 0.041* | |
H25C | 0.4609 | 0.7753 | 1.0589 | 0.041* | |
C26 | 1.0564 (5) | 0.6125 (4) | 0.7728 (3) | 0.0144 (9) | |
C27 | 1.1504 (4) | 0.5226 (5) | 0.7170 (3) | 0.0150 (9) | |
H27 | 1.1336 | 0.4699 | 0.6804 | 0.018* | |
C28 | 1.2812 (5) | 0.5246 (5) | 0.7257 (3) | 0.0167 (9) | |
H28 | 1.3656 | 0.4740 | 0.6953 | 0.020* | |
C29 | 1.2575 (5) | 0.6148 (5) | 0.7866 (3) | 0.0168 (9) | |
C30 | 1.3459 (5) | 0.6631 (5) | 0.8273 (4) | 0.0248 (11) | |
H30A | 1.4399 | 0.6135 | 0.8066 | 0.037* | |
H30B | 1.3272 | 0.6501 | 0.8931 | 0.037* | |
H30C | 1.3273 | 0.7570 | 0.8086 | 0.037* | |
C31 | 0.9556 (13) | 1.0880 (12) | 1.0023 (10) | 0.052 (4) | 0.50 |
H31A | 0.9148 | 1.1548 | 0.9548 | 0.063* | 0.50 |
H31B | 0.9732 | 1.1348 | 1.0461 | 0.063* | 0.50 |
Cl3 | 0.8386 (7) | 1.0130 (7) | 1.0580 (4) | 0.0551 (16) | 0.50 |
Cl4 | 1.1078 (8) | 0.9800 (11) | 0.9533 (6) | 0.094 (3) | 0.50 |
U11 | U22 | U33 | U12 | U13 | U23 | |
Fe | 0.0097 (3) | 0.0098 (3) | 0.0144 (3) | −0.0039 (2) | −0.0026 (2) | −0.0019 (2) |
Pt | 0.00994 (9) | 0.00915 (9) | 0.01106 (9) | −0.00362 (6) | −0.00293 (6) | −0.00135 (6) |
Cl1 | 0.0162 (5) | 0.0129 (5) | 0.0201 (5) | −0.0073 (4) | −0.0063 (4) | −0.0023 (4) |
Cl2 | 0.0254 (6) | 0.0119 (5) | 0.0222 (6) | −0.0066 (5) | −0.0133 (5) | 0.0046 (4) |
P1 | 0.0090 (5) | 0.0100 (5) | 0.0105 (5) | −0.0031 (4) | −0.0022 (4) | −0.0014 (4) |
P2 | 0.0107 (5) | 0.0107 (5) | 0.0126 (5) | −0.0038 (4) | −0.0038 (4) | −0.0024 (4) |
O1 | 0.0112 (15) | 0.0171 (16) | 0.0158 (16) | −0.0049 (13) | −0.0036 (12) | −0.0055 (13) |
O2 | 0.0133 (16) | 0.0163 (16) | 0.0139 (16) | −0.0027 (13) | −0.0017 (12) | 0.0025 (13) |
O3 | 0.0119 (15) | 0.0186 (16) | 0.0134 (15) | −0.0034 (13) | −0.0031 (12) | −0.0019 (13) |
O4 | 0.0093 (15) | 0.0169 (16) | 0.0219 (17) | −0.0061 (13) | −0.0037 (12) | −0.0061 (13) |
C1 | 0.012 (2) | 0.011 (2) | 0.014 (2) | −0.0036 (17) | −0.0040 (16) | −0.0031 (17) |
C2 | 0.008 (2) | 0.010 (2) | 0.018 (2) | −0.0040 (17) | −0.0003 (17) | −0.0031 (17) |
C3 | 0.011 (2) | 0.019 (2) | 0.019 (2) | −0.0054 (19) | 0.0003 (17) | −0.0089 (19) |
C4 | 0.012 (2) | 0.009 (2) | 0.025 (2) | −0.0006 (18) | −0.0023 (18) | −0.0046 (18) |
C5 | 0.012 (2) | 0.014 (2) | 0.021 (2) | −0.0036 (18) | −0.0060 (18) | −0.0022 (18) |
C6 | 0.010 (2) | 0.011 (2) | 0.020 (2) | −0.0042 (17) | −0.0054 (17) | −0.0024 (17) |
C7 | 0.014 (2) | 0.017 (2) | 0.017 (2) | −0.0059 (19) | −0.0056 (18) | −0.0024 (18) |
C8 | 0.015 (2) | 0.014 (2) | 0.026 (3) | −0.0056 (19) | −0.0086 (19) | −0.0066 (19) |
C9 | 0.012 (2) | 0.016 (2) | 0.021 (2) | −0.0084 (19) | −0.0039 (18) | 0.0011 (18) |
C10 | 0.008 (2) | 0.015 (2) | 0.018 (2) | −0.0021 (18) | −0.0025 (17) | −0.0041 (18) |
C11 | 0.010 (2) | 0.013 (2) | 0.017 (2) | −0.0041 (18) | −0.0037 (17) | −0.0017 (17) |
C12 | 0.016 (2) | 0.015 (2) | 0.018 (2) | −0.0039 (19) | −0.0035 (18) | −0.0048 (18) |
C13 | 0.024 (2) | 0.016 (2) | 0.015 (2) | −0.008 (2) | −0.0093 (19) | −0.0005 (18) |
C14 | 0.017 (2) | 0.020 (2) | 0.017 (2) | −0.011 (2) | −0.0073 (18) | 0.0047 (19) |
C15 | 0.013 (2) | 0.027 (3) | 0.025 (3) | −0.010 (2) | −0.0062 (19) | 0.001 (2) |
C16 | 0.014 (2) | 0.015 (2) | 0.012 (2) | −0.0066 (18) | −0.0019 (17) | −0.0028 (17) |
C17 | 0.016 (2) | 0.015 (2) | 0.019 (2) | −0.0072 (19) | −0.0039 (18) | 0.0001 (18) |
C18 | 0.013 (2) | 0.022 (2) | 0.018 (2) | −0.0047 (19) | 0.0017 (18) | −0.0072 (19) |
C19 | 0.016 (2) | 0.024 (2) | 0.014 (2) | −0.014 (2) | 0.0016 (17) | −0.0034 (18) |
C20 | 0.022 (3) | 0.029 (3) | 0.020 (2) | −0.011 (2) | −0.004 (2) | 0.005 (2) |
C21 | 0.013 (2) | 0.015 (2) | 0.015 (2) | −0.0051 (18) | −0.0014 (17) | −0.0040 (17) |
C22 | 0.016 (2) | 0.021 (2) | 0.022 (2) | −0.007 (2) | −0.0067 (19) | 0.001 (2) |
C23 | 0.029 (3) | 0.026 (3) | 0.011 (2) | −0.008 (2) | −0.0064 (19) | −0.0004 (19) |
C24 | 0.020 (2) | 0.016 (2) | 0.012 (2) | −0.0040 (19) | −0.0015 (18) | 0.0012 (18) |
C25 | 0.026 (3) | 0.028 (3) | 0.022 (3) | −0.007 (2) | 0.001 (2) | 0.001 (2) |
C26 | 0.016 (2) | 0.013 (2) | 0.017 (2) | −0.0067 (18) | −0.0039 (17) | −0.0020 (17) |
C27 | 0.014 (2) | 0.018 (2) | 0.014 (2) | −0.0065 (19) | −0.0024 (17) | −0.0020 (18) |
C28 | 0.009 (2) | 0.015 (2) | 0.023 (2) | −0.0035 (18) | −0.0005 (18) | 0.0001 (18) |
C29 | 0.011 (2) | 0.019 (2) | 0.020 (2) | −0.0046 (19) | −0.0038 (18) | −0.0002 (19) |
C30 | 0.019 (3) | 0.026 (3) | 0.034 (3) | −0.013 (2) | −0.005 (2) | −0.006 (2) |
C31 | 0.085 (12) | 0.024 (6) | 0.048 (8) | −0.009 (7) | −0.023 (8) | −0.008 (6) |
Cl3 | 0.097 (5) | 0.063 (3) | 0.026 (2) | −0.054 (4) | −0.003 (3) | −0.0084 (18) |
Cl4 | 0.085 (6) | 0.129 (7) | 0.055 (4) | −0.024 (4) | 0.004 (4) | −0.020 (4) |
Fe—Cg1 | 1.644 (5) | C8—H8 | 0.9300 |
Fe—Cg2 | 1.648 (5) | C9—C10 | 1.423 (6) |
Fe—C1 | 2.003 (4) | C9—H9 | 0.9300 |
Fe—C2 | 2.039 (4) | C10—H10 | 0.9300 |
Fe—C3 | 2.063 (4) | C11—C12 | 1.339 (6) |
Fe—C4 | 2.069 (5) | C12—C13 | 1.427 (6) |
Fe—C5 | 2.044 (4) | C12—H12 | 0.9300 |
Fe—C6 | 2.008 (4) | C13—C14 | 1.343 (7) |
Fe—C7 | 2.046 (4) | C13—H13 | 0.9300 |
Fe—C8 | 2.085 (4) | C14—C15 | 1.490 (6) |
Fe—C9 | 2.066 (4) | C15—H15A | 0.9600 |
Fe—C10 | 2.024 (4) | C15—H15B | 0.9600 |
Pt—P1 | 2.2412 (11) | C15—H15C | 0.9600 |
Pt—P2 | 2.2416 (10) | C16—C17 | 1.352 (6) |
Pt—Cl1 | 2.3385 (10) | C17—C18 | 1.423 (6) |
Pt—Cl2 | 2.3475 (11) | C17—H17 | 0.9300 |
P1—C1 | 1.790 (4) | C18—C19 | 1.352 (7) |
P1—C16 | 1.793 (4) | C18—H18 | 0.9300 |
P1—C11 | 1.801 (4) | C19—C20 | 1.496 (6) |
P2—C6 | 1.811 (4) | C20—H20A | 0.9600 |
P2—C21 | 1.787 (4) | C20—H20B | 0.9600 |
P2—C26 | 1.790 (5) | C20—H20C | 0.9600 |
O1—C14 | 1.371 (5) | C21—C22 | 1.355 (6) |
O1—C11 | 1.374 (5) | C22—C23 | 1.430 (7) |
O2—C19 | 1.377 (5) | C22—H22 | 0.9300 |
O2—C16 | 1.384 (5) | C23—C24 | 1.345 (7) |
O3—C24 | 1.374 (5) | C23—H23 | 0.9300 |
O3—C21 | 1.384 (5) | C24—C25 | 1.491 (7) |
O4—C29 | 1.373 (5) | C25—H25A | 0.9600 |
O4—C26 | 1.382 (5) | C25—H25B | 0.9600 |
C1—C2 | 1.440 (6) | C25—H25C | 0.9600 |
C1—C5 | 1.440 (6) | C26—C27 | 1.355 (6) |
C2—C3 | 1.423 (6) | C27—C28 | 1.439 (6) |
C2—H2 | 0.9300 | C27—H27 | 0.9300 |
C3—C4 | 1.409 (6) | C28—C29 | 1.355 (7) |
C3—H3 | 0.9300 | C28—H28 | 0.9300 |
C4—C5 | 1.424 (6) | C29—C30 | 1.492 (6) |
C4—H4 | 0.9300 | C30—H30A | 0.9600 |
C5—H5 | 0.9300 | C30—H30B | 0.9600 |
C6—C10 | 1.432 (6) | C30—H30C | 0.9600 |
C6—C7 | 1.432 (6) | C31—Cl4 | 1.709 (13) |
C7—C8 | 1.427 (6) | C31—Cl3 | 1.738 (13) |
C7—H7 | 0.9300 | C31—H31A | 0.9700 |
C8—C9 | 1.413 (7) | C31—H31B | 0.9700 |
Cg1—Fe—Cg2 | 177.4 (2) | P2—C6—Fe | 122.4 (2) |
C1—Fe—C6 | 107.74 (17) | C8—C7—C6 | 107.8 (4) |
C1—Fe—C10 | 106.96 (17) | C8—C7—Fe | 71.3 (3) |
C6—Fe—C10 | 41.59 (18) | C6—C7—Fe | 67.9 (2) |
C1—Fe—C2 | 41.72 (17) | C8—C7—H7 | 126.1 |
C6—Fe—C2 | 108.02 (17) | C6—C7—H7 | 126.1 |
C10—Fe—C2 | 135.49 (17) | Fe—C7—H7 | 126.3 |
C1—Fe—C5 | 41.69 (17) | C9—C8—C7 | 108.1 (4) |
C6—Fe—C5 | 138.13 (18) | C9—C8—Fe | 69.4 (2) |
C10—Fe—C5 | 109.86 (18) | C7—C8—Fe | 68.3 (2) |
C2—Fe—C5 | 69.48 (18) | C9—C8—H8 | 126.0 |
C1—Fe—C7 | 138.59 (18) | C7—C8—H8 | 126.0 |
C6—Fe—C7 | 41.35 (17) | Fe—C8—H8 | 127.9 |
C10—Fe—C7 | 69.29 (18) | C8—C9—C10 | 108.8 (4) |
C2—Fe—C7 | 111.27 (18) | C8—C9—Fe | 70.8 (2) |
C5—Fe—C7 | 179.11 (19) | C10—C9—Fe | 68.1 (2) |
C1—Fe—C3 | 69.02 (17) | C8—C9—H9 | 125.6 |
C6—Fe—C3 | 137.63 (19) | C10—C9—H9 | 125.6 |
C10—Fe—C3 | 175.81 (17) | Fe—C9—H9 | 127.1 |
C2—Fe—C3 | 40.61 (17) | C9—C10—C6 | 107.6 (4) |
C5—Fe—C3 | 68.10 (18) | C9—C10—Fe | 71.2 (2) |
C7—Fe—C3 | 112.77 (18) | C6—C10—Fe | 68.6 (2) |
C1—Fe—C9 | 136.43 (18) | C9—C10—H10 | 126.2 |
C6—Fe—C9 | 68.83 (18) | C6—C10—H10 | 126.2 |
C10—Fe—C9 | 40.71 (17) | Fe—C10—H10 | 125.5 |
C2—Fe—C9 | 176.19 (18) | C12—C11—O1 | 110.2 (4) |
C5—Fe—C9 | 111.24 (18) | C12—C11—P1 | 131.7 (4) |
C7—Fe—C9 | 67.98 (18) | O1—C11—P1 | 118.1 (3) |
C3—Fe—C9 | 143.20 (18) | C11—C12—C13 | 106.8 (4) |
C1—Fe—C4 | 69.08 (17) | C11—C12—H12 | 126.6 |
C6—Fe—C4 | 176.26 (17) | C13—C12—H12 | 126.6 |
C10—Fe—C4 | 140.58 (18) | C14—C13—C12 | 106.5 (4) |
C2—Fe—C4 | 68.33 (17) | C14—C13—H13 | 126.8 |
C5—Fe—C4 | 40.51 (18) | C12—C13—H13 | 126.8 |
C7—Fe—C4 | 140.08 (18) | C13—C14—O1 | 110.3 (4) |
C3—Fe—C4 | 39.87 (18) | C13—C14—C15 | 133.3 (4) |
C9—Fe—C4 | 114.78 (18) | O1—C14—C15 | 116.4 (4) |
C1—Fe—C8 | 175.20 (18) | C14—C15—H15A | 109.5 |
C6—Fe—C8 | 68.68 (17) | C14—C15—H15B | 109.5 |
C10—Fe—C8 | 68.25 (18) | H15A—C15—H15B | 109.5 |
C2—Fe—C8 | 141.77 (18) | C14—C15—H15C | 109.5 |
C5—Fe—C8 | 139.21 (18) | H15A—C15—H15C | 109.5 |
C7—Fe—C8 | 40.41 (17) | H15B—C15—H15C | 109.5 |
C3—Fe—C8 | 115.76 (18) | C17—C16—O2 | 109.5 (4) |
C9—Fe—C8 | 39.80 (18) | C17—C16—P1 | 130.2 (4) |
C4—Fe—C8 | 114.61 (18) | O2—C16—P1 | 119.4 (3) |
P1—Pt—P2 | 97.35 (4) | C16—C17—C18 | 107.2 (4) |
P1—Pt—Cl1 | 90.44 (4) | C16—C17—H17 | 126.4 |
P2—Pt—Cl1 | 171.47 (4) | C18—C17—H17 | 126.4 |
P1—Pt—Cl2 | 176.78 (4) | C19—C18—C17 | 106.7 (4) |
P2—Pt—Cl2 | 84.76 (4) | C19—C18—H18 | 126.6 |
Cl1—Pt—Cl2 | 87.61 (4) | C17—C18—H18 | 126.6 |
C1—P1—C16 | 111.4 (2) | C18—C19—O2 | 110.1 (4) |
C1—P1—C11 | 102.2 (2) | C18—C19—C20 | 132.7 (4) |
C16—P1—C11 | 99.2 (2) | O2—C19—C20 | 117.2 (4) |
C1—P1—Pt | 115.30 (15) | C19—C20—H20A | 109.5 |
C16—P1—Pt | 108.43 (15) | C19—C20—H20B | 109.5 |
C11—P1—Pt | 119.15 (15) | H20A—C20—H20B | 109.5 |
C21—P2—C26 | 106.1 (2) | C19—C20—H20C | 109.5 |
C21—P2—C6 | 102.3 (2) | H20A—C20—H20C | 109.5 |
C26—P2—C6 | 100.9 (2) | H20B—C20—H20C | 109.5 |
C21—P2—Pt | 107.49 (14) | C22—C21—O3 | 110.0 (4) |
C26—P2—Pt | 113.99 (15) | C22—C21—P2 | 135.5 (4) |
C6—P2—Pt | 124.35 (14) | O3—C21—P2 | 114.5 (3) |
C14—O1—C11 | 106.2 (3) | C21—C22—C23 | 106.0 (4) |
C19—O2—C16 | 106.5 (3) | C21—C22—H22 | 127.0 |
C24—O3—C21 | 106.7 (3) | C23—C22—H22 | 127.0 |
C29—O4—C26 | 106.8 (3) | C24—C23—C22 | 107.7 (4) |
C2—C1—C5 | 107.8 (4) | C24—C23—H23 | 126.1 |
C2—C1—P1 | 123.7 (3) | C22—C23—H23 | 126.1 |
C5—C1—P1 | 128.4 (3) | C23—C24—O3 | 109.6 (4) |
C2—C1—Fe | 70.5 (2) | C23—C24—C25 | 135.4 (4) |
C5—C1—Fe | 70.7 (2) | O3—C24—C25 | 115.0 (4) |
P1—C1—Fe | 121.6 (2) | C24—C25—H25A | 109.5 |
C3—C2—C1 | 107.2 (4) | C24—C25—H25B | 109.5 |
C3—C2—Fe | 70.6 (2) | H25A—C25—H25B | 109.5 |
C1—C2—Fe | 67.8 (2) | C24—C25—H25C | 109.5 |
C3—C2—H2 | 126.4 | H25A—C25—H25C | 109.5 |
C1—C2—H2 | 126.4 | H25B—C25—H25C | 109.5 |
Fe—C2—H2 | 126.7 | C27—C26—O4 | 110.0 (4) |
C4—C3—C2 | 109.1 (4) | C27—C26—P2 | 134.6 (3) |
C4—C3—Fe | 70.3 (3) | O4—C26—P2 | 115.0 (3) |
C2—C3—Fe | 68.8 (2) | C26—C27—C28 | 106.5 (4) |
C4—C3—H3 | 125.5 | C26—C27—H27 | 126.7 |
C2—C3—H3 | 125.5 | C28—C27—H27 | 126.7 |
Fe—C3—H3 | 127.0 | C29—C28—C27 | 106.6 (4) |
C3—C4—C5 | 108.5 (4) | C29—C28—H28 | 126.7 |
C3—C4—Fe | 69.8 (3) | C27—C28—H28 | 126.7 |
C5—C4—Fe | 68.8 (2) | C28—C29—O4 | 110.2 (4) |
C3—C4—H4 | 125.7 | C28—C29—C30 | 134.5 (4) |
C5—C4—H4 | 125.7 | O4—C29—C30 | 115.3 (4) |
Fe—C4—H4 | 127.2 | C29—C30—H30A | 109.5 |
C4—C5—C1 | 107.5 (4) | C29—C30—H30B | 109.5 |
C4—C5—Fe | 70.7 (3) | H30A—C30—H30B | 109.5 |
C1—C5—Fe | 67.6 (2) | C29—C30—H30C | 109.5 |
C4—C5—H5 | 126.3 | H30A—C30—H30C | 109.5 |
C1—C5—H5 | 126.3 | H30B—C30—H30C | 109.5 |
Fe—C5—H5 | 126.9 | Cl4—C31—Cl3 | 115.1 (8) |
C10—C6—C7 | 107.8 (4) | Cl4—C31—H31A | 108.5 |
C10—C6—P2 | 127.6 (3) | Cl3—C31—H31A | 108.5 |
C7—C6—P2 | 124.5 (3) | Cl4—C31—H31B | 108.5 |
C10—C6—Fe | 69.8 (2) | Cl3—C31—H31B | 108.5 |
C7—C6—Fe | 70.8 (2) | H31A—C31—H31B | 107.5 |