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We report the results of polarized Co $K$ EXAFS experiments on a series of CoPt3 films grown by molecular beam epitaxy on (100) MgO single crystal substrates over a range of temperatures from 473 K to 1073 K. These samples exhibit substantial perpendicular magnetic anisotropy that is strongly dependent on the substrate growth temperature Tg. We measure a preference for in-plane Co-Co pairs that is correlated with the magnetic properties.

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