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The title compound, (C6H11N2)2[PdCl4], is a salt that consists of a square-planar tetrachloropalladate(II) anion having interactions, via the chlorides, to ring H atoms on two 1-ethyl-3-methyl­imidazolium (MEI+) cations. The Pd atom resides at a center of inversion. Cl...H distances range from 2.75 to 3.24 Å, some of which suggest hydrogen bonding. As the title compound was obtained from an acidic room-temperature melt of the chloride salt of the MEI+ cation and AlCl3, a possible use of this type of system as an alternate medium for crystallization is indicated.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks pdmeic, global

fcf

Structure factor file (CIF format)
Contains datablock pdmeic

CCDC reference: 130559

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