Polysulfonylamines. LXXXV. N-Chlorodimesylamine

In the molecule of the title compound, C₂H₆ClNO₄S₂, the N atom has a slightly pyramidal geometry characterized by the angles Cl-N-S 115.71 (7), 114.34 (6)and S-N-S 120.24 (6) degrees, and the distances S-N 1.7260 (11), 1.6992 (12), Cl-N 1.7138 (11) Å. The crystal is stabilized by five intermolecular C-H...O hydrogen bonds and an intermolecular Cl...O interaction of 2.797 (1) Å, the latter linking the molecules to form infinite chains.

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