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The title compound, [AuCl2{C2B9H10(Ph2P)2}].CHCl3, contains the expected cis square-planar gold(III) units with Au-P 2.306, 2.296 (2) and Au-Cl 2.335 and 2.326 (2) Å. The dicarbaundecaborate anion acts as a P,P'bidentate ligand. The open B2C3 face contains one bridging (B-H-B) H atom.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks small, global

fcf

Structure factor file (CIF format)
Contains datablocks small, small

CCDC reference: 128636

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