metal-organic compounds
The Co atom in the cobaloxime, [CoCl(C14H11N2O2)2(C12H27P)], is octahedrally coordinated to the two bidentate diphenylglyoximato ligands, approximating a plane with the Cl and P atoms located above and below the plane. The diphenylglyoximato moieties are themselves bent 6.6 (1) and 9.8 (1)° from the central plane of the four N atoms by the bulk of the tri-n-butylphosphine ligand. The four phenyl rings of the two diphenylglyoximato groups form a propeller geometry with an average rotation from the central plane of 47 (5)°.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 128633