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The title structure, [Mo2(CH3O)2]0.75.[Mo2Cl2(CH3O)6(O)2]0.25, contains two crystallographically independent centrosymmetric molecules, each of which has a major disorder component of [MoO(OMe)4]2 and a minor component of [MoOCl(OMe)3]2 with a cis arrangement of chloro and oxo ligands. The oxo ligands lie in the `equatorial' plane of the metal atoms and bridging ligands. The methoxo bridges are markedly asymmetric as a consequence of the strong trans influence of the terminal oxo ligands compared with terminal methoxy ligands. Coordination of the Mo atom is distorted octahedral.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks 1, global

fcf

Structure factor file (CIF format)
Contains datablock rje52

CCDC reference: 127199

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