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The title compound, [Cr2(CO)10(C14H10F4P2)], displays inversion symmetry. The P-CF2 bond is somewhat lengthened on complexation and the phenyl-diphosphetane interplanar angle reduced from 89.15 (6)° in the free ligand to 61.4 (1)° in the complex. The P-Cr bond is short [2.3149 (6) Å].

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks run2, global

fcf

Structure factor file (CIF format)
Contains datablock run2

CCDC reference: 127088

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