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3-Aminopyrazine-2-carboxylic acid, C5H5N3O2, displays an extensive network of intra- and intermolecular hydrogen bonds which are undoubtedly responsible for the modest values of the displacement parameters. H-atom transfer to the ring N atoms did not occur and the carboxyl and amino H atoms are ordered. The virtually planar molecules lie very nearly in planes parallel to (10\overline{2}) and are stacked along a with separations of 3.324 (2) Å indicating ππ interactions.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, A

CCDC reference: 126807

-1
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