The exopolyhedral ligand orientation (ELO) in 3-(nitrato-κO)-3,3-bis­(tri­phenyl­phosphane-κP)-3-rhoda-1,2-dicarba-closo-dodeca­borane(11) di­chloro­methane 2.2-solvate

In the title compound, [Rh(C₂H₁₁B₉)(NO₃)(C₁₈H₁₅P)₂]·2.2CH₂Cl₂, studied as a 2.2-solvate of what was assumed to be di­chloro­methane, the nitrate ligand lies cis with respect to both cage C atoms. Accordingly, the compound displays a pronounced preferred exopolyhedral ligand orientation (ELO) which is traced to both the greater trans influence of the cage B over the cage C atoms and the greater trans influence of the tri­phenyl­phosphane ligands over the nitrate ligand. The overall mol­ecular architecture therefore agrees with that of a number of similar 3-L-3,3-L′₂-3,1,2-closo-MC₂B₉H₁₁ species in the literature.

Computing details

Data collection: APEX2 (Bruker, 2009); cell refinement: APEX2 (Bruker, 2009); data reduction: SAINT (Bruker, 2009); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008) and publCIF (Westrip, 2010); program(s) used to refine structure: SHEXL2014 (Sheldrick, 2015); molecular graphics: OLEX2 (Dolomanov et al., 2009); software used to prepare material for publication: OLEX2 (Dolomanov et al., 2009).

3-(Nitrato-κO)-3,3-bis(triphenylphosphane-κP)-3-rhoda-1,2-dicarba-closo-dodecaborane(11) dichloromethane 2.2-solvate

Crystal data

[Rh(C2H11B9)(NO3)(C18H15P)2]·2.2CH2Cl2	Z = 2
Mr = 1008.69	F(000) = 1025
Triclinic, P1	Dx = 1.562 Mg m^−3
a = 11.2934 (9) Å	Mo Kα radiation, λ = 0.71073 Å
b = 13.0083 (10) Å	Cell parameters from 9956 reflections
c = 15.8655 (13) Å	θ = 2.4–28.3°
α = 91.083 (4)°	µ = 0.79 mm^−1
β = 110.514 (4)°	T = 100 K
γ = 99.713 (4)°	PLATE, orange
V = 2144.0 (3) Å^3	0.56 × 0.32 × 0.08 mm

Data collection

Bruker APEXII CCD diffractometer	8793 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.035
φ and ω scans	θmax = 28.5°, θmin = 2.2°
Absorption correction: multi-scan (SADABS; Bruker, 2008)	h = −15→14
Tmin = 0.660, Tmax = 0.746	k = −17→17
40881 measured reflections	l = −21→20
10603 independent reflections

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	Hydrogen site location: mixed
R[F^2 > 2σ(F^2)] = 0.035	H atoms treated by a mixture of independent and constrained refinement
wR(F^2) = 0.089	w = 1/[σ^2(Fo^2) + (0.0442P)^2 + 1.0745P] where P = (Fo^2 + 2Fc^2)/3
S = 1.05	(Δ/σ)max = 0.002
10597 reflections	Δρmax = 1.04 e Å^−3
520 parameters	Δρmin = −0.74 e Å^−3

Special details

Experimental. Absorption correction: SADABS-2008/1 (Bruker,2008) was used for absorption correction. wR2(int) was 0.0598 before and 0.0451 after correction. The ratio of minimum to maximum transmission is 0.8849.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
P1	0.77241 (5)	0.67698 (4)	0.74878 (3)	0.01271 (11)
N1	0.87860 (18)	0.65330 (15)	0.52152 (13)	0.0215 (4)
C1	0.9582 (2)	0.92169 (16)	0.61657 (14)	0.0137 (4)
H1	0.997 (2)	0.8910 (19)	0.5816 (16)	0.016*
P2	1.10932 (5)	0.74601 (4)	0.77396 (4)	0.01356 (11)
C2	0.8018 (2)	0.88723 (17)	0.58661 (14)	0.0151 (4)
H2	0.765 (2)	0.841 (2)	0.5386 (17)	0.018*
Rh3	0.90764 (2)	0.79625 (2)	0.69438 (2)	0.01151 (5)
B4	1.0307 (2)	0.95430 (19)	0.73121 (17)	0.0167 (5)
H4	1.131 (2)	0.953 (2)	0.7639 (16)	0.020*
B5	1.0059 (3)	1.0516 (2)	0.64997 (17)	0.0194 (5)
H5	1.090 (2)	1.097 (2)	0.6397 (17)	0.023*
B6	0.8624 (3)	1.00666 (19)	0.55738 (17)	0.0184 (5)
H6	0.848 (2)	1.017 (2)	0.4851 (17)	0.022*
B7	0.7524 (2)	0.89183 (19)	0.67575 (16)	0.0149 (5)
H7	0.667 (2)	0.847 (2)	0.6730 (16)	0.018*
B8	0.8979 (2)	0.93764 (19)	0.77311 (16)	0.0161 (5)
H8	0.905 (2)	0.927 (2)	0.8480 (16)	0.019*
B9	0.9657 (3)	1.06382 (19)	0.74833 (17)	0.0186 (5)
H9	1.023 (2)	1.125 (2)	0.8029 (17)	0.022*
B10	0.8633 (3)	1.0969 (2)	0.64256 (17)	0.0195 (5)
H10	0.854 (2)	1.173 (2)	0.6309 (17)	0.023*
B11	0.7322 (3)	0.9899 (2)	0.59632 (17)	0.0188 (5)
H11	0.636 (2)	0.996 (2)	0.5488 (17)	0.023*
B12	0.7956 (3)	1.0254 (2)	0.71529 (17)	0.0186 (5)
H12	0.739 (2)	1.068 (2)	0.7481 (17)	0.022*
O31	0.89962 (15)	0.66171 (11)	0.60529 (11)	0.0190 (3)
O32	0.91609 (17)	0.58184 (14)	0.49219 (11)	0.0283 (4)
O33	0.8204 (2)	0.71454 (16)	0.47201 (12)	0.0383 (5)
C101	0.7601 (2)	0.73522 (16)	0.84977 (14)	0.0154 (4)
C102	0.8653 (2)	0.74040 (17)	0.93054 (14)	0.0164 (4)
H102	0.9351	0.7078	0.9320	0.020*
C103	0.8682 (2)	0.79282 (18)	1.00855 (15)	0.0208 (5)
H103	0.9397	0.7959	1.0632	0.025*
C104	0.7667 (2)	0.84065 (19)	1.00641 (16)	0.0238 (5)
H104	0.7685	0.8767	1.0596	0.029*
C105	0.6621 (2)	0.83591 (19)	0.92634 (16)	0.0234 (5)
H105	0.5929	0.8692	0.9251	0.028*
C106	0.6579 (2)	0.78303 (17)	0.84843 (15)	0.0179 (4)
H106	0.5856	0.7794	0.7942	0.022*
C107	0.7981 (2)	0.54445 (16)	0.77742 (14)	0.0148 (4)
C108	0.7805 (2)	0.50118 (18)	0.85334 (15)	0.0187 (4)
H108	0.7688	0.5446	0.8975	0.022*
C109	0.7799 (2)	0.39519 (18)	0.86463 (16)	0.0227 (5)
H109	0.7686	0.3666	0.9166	0.027*
C110	0.7958 (2)	0.33164 (18)	0.79988 (16)	0.0243 (5)
H110	0.7951	0.2593	0.8072	0.029*
C111	0.8127 (2)	0.37379 (18)	0.72415 (16)	0.0231 (5)
H111	0.8231	0.3299	0.6797	0.028*
C112	0.8146 (2)	0.47955 (17)	0.71287 (15)	0.0186 (4)
H112	0.8270	0.5078	0.6612	0.022*
C113	0.6081 (2)	0.63853 (17)	0.66624 (14)	0.0154 (4)
C114	0.5795 (2)	0.65316 (17)	0.57549 (15)	0.0185 (4)
H114	0.6447	0.6881	0.5556	0.022*
C115	0.4552 (2)	0.61682 (19)	0.51286 (16)	0.0233 (5)
H115	0.4363	0.6268	0.4507	0.028*
C116	0.3602 (2)	0.56643 (18)	0.54162 (16)	0.0229 (5)
H116	0.2754	0.5431	0.4994	0.028*
C117	0.3888 (2)	0.54987 (18)	0.63250 (16)	0.0218 (5)
H117	0.3237	0.5143	0.6521	0.026*
C118	0.5122 (2)	0.58524 (18)	0.69455 (16)	0.0201 (5)
H118	0.5315	0.5732	0.7564	0.024*
C201	1.1125 (2)	0.60599 (17)	0.78369 (14)	0.0155 (4)
C202	1.1095 (2)	0.56430 (18)	0.86388 (15)	0.0190 (5)
H202	1.1021	0.6079	0.9098	0.023*
C203	1.1172 (2)	0.45993 (19)	0.87707 (16)	0.0233 (5)
H203	1.1147	0.4324	0.9316	0.028*
C204	1.1285 (2)	0.39596 (19)	0.81007 (17)	0.0252 (5)
H204	1.1365	0.3252	0.8196	0.030*
C205	1.1282 (2)	0.43527 (18)	0.72979 (16)	0.0223 (5)
H205	1.1340	0.3909	0.6837	0.027*
C206	1.1193 (2)	0.53952 (18)	0.71585 (15)	0.0186 (4)
H206	1.1180	0.5656	0.6601	0.022*
C207	1.2198 (2)	0.79311 (17)	0.71462 (14)	0.0163 (4)
C208	1.3287 (2)	0.87055 (18)	0.75613 (16)	0.0214 (5)
H208	1.3480	0.8976	0.8164	0.026*
C209	1.4090 (2)	0.9083 (2)	0.71018 (17)	0.0258 (5)
H209	1.4825	0.9611	0.7393	0.031*
C210	1.3833 (2)	0.8699 (2)	0.62250 (17)	0.0258 (5)
H210	1.4395	0.8952	0.5917	0.031*
C211	1.2745 (2)	0.79390 (19)	0.57993 (16)	0.0215 (5)
H211	1.2558	0.7675	0.5195	0.026*
C212	1.1927 (2)	0.75624 (17)	0.62513 (14)	0.0170 (4)
H212	1.1177	0.7050	0.5950	0.020*
C213	1.2025 (2)	0.79606 (17)	0.89153 (14)	0.0173 (4)
C214	1.1578 (2)	0.85900 (17)	0.94137 (15)	0.0191 (5)
H214	1.0777	0.8805	0.9135	0.023*
C215	1.2303 (2)	0.89048 (18)	1.03202 (15)	0.0217 (5)
H215	1.1983	0.9322	1.0658	0.026*
C216	1.3480 (2)	0.86155 (19)	1.07301 (16)	0.0257 (5)
H216	1.3968	0.8833	1.1348	0.031*
C217	1.3952 (2)	0.80033 (19)	1.02359 (16)	0.0252 (5)
H217	1.4771	0.7816	1.0512	0.030*
C218	1.3221 (2)	0.76673 (19)	0.93362 (15)	0.0216 (5)
H218	1.3534	0.7236	0.9005	0.026*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
P1	0.0157 (3)	0.0113 (3)	0.0117 (2)	0.0039 (2)	0.0050 (2)	0.00183 (19)
N1	0.0206 (10)	0.0178 (10)	0.0248 (10)	0.0050 (8)	0.0059 (8)	0.0033 (8)
C1	0.0180 (10)	0.0117 (10)	0.0138 (10)	0.0050 (8)	0.0076 (8)	0.0046 (8)
P2	0.0155 (3)	0.0129 (3)	0.0126 (3)	0.0047 (2)	0.0044 (2)	0.0025 (2)
C2	0.0195 (11)	0.0135 (10)	0.0118 (10)	0.0059 (8)	0.0039 (8)	0.0025 (8)
Rh3	0.01449 (9)	0.00958 (8)	0.01125 (8)	0.00430 (6)	0.00461 (6)	0.00194 (6)
B4	0.0203 (12)	0.0104 (11)	0.0195 (12)	0.0028 (9)	0.0072 (10)	0.0027 (9)
B5	0.0282 (14)	0.0115 (12)	0.0200 (12)	0.0039 (10)	0.0103 (11)	0.0020 (9)
B6	0.0270 (13)	0.0138 (12)	0.0187 (12)	0.0083 (10)	0.0109 (11)	0.0079 (9)
B7	0.0196 (12)	0.0128 (11)	0.0141 (11)	0.0080 (9)	0.0060 (10)	0.0024 (9)
B8	0.0218 (12)	0.0135 (12)	0.0150 (11)	0.0082 (9)	0.0067 (10)	0.0024 (9)
B9	0.0279 (13)	0.0114 (11)	0.0177 (12)	0.0048 (10)	0.0090 (11)	0.0026 (9)
B10	0.0279 (14)	0.0133 (12)	0.0190 (12)	0.0075 (10)	0.0088 (11)	0.0025 (10)
B11	0.0250 (13)	0.0169 (12)	0.0160 (12)	0.0100 (10)	0.0063 (10)	0.0039 (9)
B12	0.0272 (13)	0.0163 (12)	0.0156 (12)	0.0097 (10)	0.0089 (10)	0.0035 (9)
O31	0.0262 (8)	0.0080 (7)	0.0302 (9)	0.0043 (6)	0.0186 (7)	−0.0006 (6)
O32	0.0341 (10)	0.0276 (10)	0.0256 (9)	0.0122 (8)	0.0111 (8)	−0.0055 (7)
O33	0.0647 (13)	0.0356 (11)	0.0199 (9)	0.0301 (10)	0.0120 (9)	0.0071 (8)
C101	0.0207 (11)	0.0120 (10)	0.0158 (10)	0.0035 (8)	0.0090 (9)	0.0031 (8)
C102	0.0182 (11)	0.0152 (10)	0.0171 (10)	0.0036 (8)	0.0076 (9)	0.0032 (8)
C103	0.0267 (12)	0.0187 (11)	0.0159 (11)	0.0028 (9)	0.0071 (9)	0.0020 (9)
C104	0.0349 (13)	0.0207 (12)	0.0199 (11)	0.0049 (10)	0.0149 (10)	−0.0001 (9)
C105	0.0282 (13)	0.0200 (12)	0.0268 (12)	0.0084 (10)	0.0140 (10)	0.0016 (10)
C106	0.0204 (11)	0.0161 (11)	0.0186 (11)	0.0056 (9)	0.0075 (9)	0.0045 (8)
C107	0.0146 (10)	0.0121 (10)	0.0164 (10)	0.0028 (8)	0.0037 (8)	0.0015 (8)
C108	0.0219 (11)	0.0166 (11)	0.0178 (11)	0.0045 (9)	0.0070 (9)	0.0032 (8)
C109	0.0273 (12)	0.0171 (11)	0.0227 (12)	0.0018 (9)	0.0084 (10)	0.0073 (9)
C110	0.0278 (12)	0.0119 (11)	0.0281 (12)	0.0026 (9)	0.0044 (10)	0.0036 (9)
C111	0.0289 (13)	0.0148 (11)	0.0235 (12)	0.0064 (9)	0.0061 (10)	−0.0020 (9)
C112	0.0236 (11)	0.0162 (11)	0.0150 (10)	0.0030 (9)	0.0060 (9)	0.0014 (8)
C113	0.0144 (10)	0.0133 (10)	0.0171 (10)	0.0048 (8)	0.0031 (8)	−0.0009 (8)
C114	0.0203 (11)	0.0156 (11)	0.0186 (11)	0.0023 (9)	0.0065 (9)	−0.0006 (8)
C115	0.0251 (12)	0.0240 (12)	0.0168 (11)	0.0037 (10)	0.0033 (9)	−0.0015 (9)
C116	0.0181 (11)	0.0178 (12)	0.0275 (12)	0.0053 (9)	0.0009 (10)	−0.0027 (9)
C117	0.0185 (11)	0.0177 (11)	0.0314 (13)	0.0032 (9)	0.0117 (10)	0.0024 (9)
C118	0.0218 (11)	0.0163 (11)	0.0217 (11)	0.0034 (9)	0.0073 (9)	0.0040 (9)
C201	0.0138 (10)	0.0143 (10)	0.0180 (10)	0.0058 (8)	0.0035 (8)	0.0037 (8)
C202	0.0220 (11)	0.0196 (11)	0.0176 (11)	0.0058 (9)	0.0086 (9)	0.0035 (9)
C203	0.0276 (12)	0.0223 (12)	0.0218 (12)	0.0089 (10)	0.0088 (10)	0.0107 (9)
C204	0.0315 (13)	0.0161 (11)	0.0308 (13)	0.0109 (10)	0.0111 (11)	0.0101 (10)
C205	0.0269 (12)	0.0188 (12)	0.0255 (12)	0.0073 (9)	0.0131 (10)	0.0025 (9)
C206	0.0207 (11)	0.0197 (11)	0.0184 (11)	0.0066 (9)	0.0091 (9)	0.0052 (9)
C207	0.0168 (10)	0.0173 (11)	0.0180 (10)	0.0083 (8)	0.0074 (9)	0.0087 (8)
C208	0.0215 (11)	0.0205 (12)	0.0209 (11)	0.0043 (9)	0.0057 (9)	0.0047 (9)
C209	0.0168 (11)	0.0267 (13)	0.0306 (13)	0.0032 (9)	0.0047 (10)	0.0097 (10)
C210	0.0222 (12)	0.0307 (14)	0.0327 (13)	0.0135 (10)	0.0149 (11)	0.0185 (11)
C211	0.0234 (12)	0.0268 (13)	0.0197 (11)	0.0131 (10)	0.0100 (9)	0.0103 (9)
C212	0.0168 (10)	0.0182 (11)	0.0189 (11)	0.0080 (8)	0.0077 (9)	0.0076 (8)
C213	0.0187 (11)	0.0158 (11)	0.0151 (10)	0.0024 (8)	0.0035 (9)	0.0033 (8)
C214	0.0227 (11)	0.0165 (11)	0.0169 (11)	0.0031 (9)	0.0058 (9)	0.0041 (8)
C215	0.0304 (13)	0.0166 (11)	0.0171 (11)	0.0023 (9)	0.0083 (10)	0.0009 (9)
C216	0.0308 (13)	0.0235 (13)	0.0156 (11)	−0.0022 (10)	0.0026 (10)	0.0024 (9)
C217	0.0221 (12)	0.0261 (13)	0.0218 (12)	0.0028 (10)	0.0015 (10)	0.0048 (10)
C218	0.0193 (11)	0.0273 (13)	0.0176 (11)	0.0069 (9)	0.0045 (9)	0.0038 (9)

Geometric parameters (Å, º)

P1—Rh3	2.3789 (6)	C104—C105	1.391 (4)
P1—C101	1.818 (2)	C105—H105	0.9500
P1—C107	1.836 (2)	C105—C106	1.385 (3)
P1—C113	1.835 (2)	C106—H106	0.9500
N1—O31	1.265 (2)	C107—C108	1.401 (3)
N1—O32	1.231 (2)	C107—C112	1.396 (3)
N1—O33	1.234 (3)	C108—H108	0.9500
C1—H1	0.93 (2)	C108—C109	1.393 (3)
C1—C2	1.639 (3)	C109—H109	0.9500
C1—Rh3	2.184 (2)	C109—C110	1.385 (3)
C1—B4	1.723 (3)	C110—H110	0.9500
C1—B5	1.698 (3)	C110—C111	1.390 (3)
C1—B6	1.734 (3)	C111—H111	0.9500
P2—Rh3	2.3931 (6)	C111—C112	1.388 (3)
P2—C201	1.836 (2)	C112—H112	0.9500
P2—C207	1.845 (2)	C113—C114	1.385 (3)
P2—C213	1.832 (2)	C113—C118	1.398 (3)
C2—H2	0.89 (3)	C114—H114	0.9500
C2—Rh3	2.208 (2)	C114—C115	1.401 (3)
C2—B6	1.729 (3)	C115—H115	0.9500
C2—B7	1.695 (3)	C115—C116	1.381 (3)
C2—B11	1.690 (3)	C116—H116	0.9500
Rh3—B4	2.219 (2)	C116—C117	1.392 (3)
Rh3—B7	2.256 (2)	C117—H117	0.9500
Rh3—B8	2.243 (2)	C117—C118	1.388 (3)
Rh3—O31	2.1982 (14)	C118—H118	0.9500
B4—H4	1.07 (3)	C201—C202	1.401 (3)
B4—B5	1.808 (4)	C201—C206	1.399 (3)
B4—B8	1.826 (4)	C202—H202	0.9500
B4—B9	1.767 (4)	C202—C203	1.390 (3)
B5—H5	1.10 (3)	C203—H203	0.9500
B5—B6	1.762 (4)	C203—C204	1.392 (3)
B5—B9	1.783 (4)	C204—H204	0.9500
B5—B10	1.773 (4)	C204—C205	1.380 (3)
B6—H6	1.11 (2)	C205—H205	0.9500
B6—B10	1.769 (4)	C205—C206	1.393 (3)
B6—B11	1.768 (4)	C206—H206	0.9500
B7—H7	1.02 (2)	C207—C208	1.397 (3)
B7—B8	1.816 (3)	C207—C212	1.400 (3)
B7—B11	1.796 (4)	C208—H208	0.9500
B7—B12	1.764 (3)	C208—C209	1.385 (3)
B8—H8	1.17 (2)	C209—H209	0.9500
B8—B9	1.802 (4)	C209—C210	1.382 (4)
B8—B12	1.795 (4)	C210—H210	0.9500
B9—H9	1.10 (2)	C210—C211	1.388 (4)
B9—B10	1.782 (4)	C211—H211	0.9500
B9—B12	1.782 (4)	C211—C212	1.390 (3)
B10—H10	1.02 (3)	C212—H212	0.9500
B10—B11	1.782 (4)	C213—C214	1.394 (3)
B10—B12	1.789 (4)	C213—C218	1.402 (3)
B11—H11	1.10 (3)	C214—H214	0.9500
B11—B12	1.788 (4)	C214—C215	1.395 (3)
B12—H12	1.15 (2)	C215—H215	0.9500
C101—C102	1.400 (3)	C215—C216	1.380 (4)
C101—C106	1.394 (3)	C216—H216	0.9500
C102—H102	0.9500	C216—C217	1.395 (4)
C102—C103	1.389 (3)	C217—H217	0.9500
C103—H103	0.9500	C217—C218	1.393 (3)
C103—C104	1.385 (3)	C218—H218	0.9500
C104—H104	0.9500
C101—P1—Rh3	110.47 (7)	B10—B9—B12	60.26 (15)
C101—P1—C107	103.72 (10)	B12—B9—B5	107.79 (18)
C101—P1—C113	107.10 (10)	B12—B9—B8	60.12 (14)
C107—P1—Rh3	124.16 (7)	B12—B9—H9	123.2 (13)
C113—P1—Rh3	112.86 (7)	B5—B10—B9	60.20 (15)
C113—P1—C107	96.77 (10)	B5—B10—H10	121.8 (14)
O32—N1—O31	117.74 (19)	B5—B10—B11	107.49 (18)
O32—N1—O33	122.3 (2)	B5—B10—B12	107.91 (18)
O33—N1—O31	119.99 (19)	B6—B10—B5	59.66 (14)
C2—C1—H1	116.8 (15)	B6—B10—B9	107.85 (18)
C2—C1—Rh3	68.87 (11)	B6—B10—H10	122.0 (14)
C2—C1—B4	111.42 (16)	B6—B10—B11	59.72 (14)
C2—C1—B5	110.57 (17)	B6—B10—B12	107.82 (18)
C2—C1—B6	61.60 (14)	B9—B10—H10	121.6 (14)
Rh3—C1—H1	104.4 (15)	B9—B10—B11	107.87 (18)
B4—C1—H1	123.9 (15)	B9—B10—B12	59.88 (15)
B4—C1—Rh3	68.03 (11)	B11—B10—H10	122.0 (14)
B4—C1—B6	115.20 (17)	B11—B10—B12	60.10 (15)
B5—C1—H1	119.3 (15)	B12—B10—H10	121.8 (14)
B5—C1—Rh3	127.33 (14)	C2—B11—B6	59.93 (14)
B5—C1—B4	63.80 (14)	C2—B11—B7	58.11 (13)
B5—C1—B6	61.77 (14)	C2—B11—B10	104.58 (18)
B6—C1—H1	112.0 (15)	C2—B11—H11	121.2 (13)
B6—C1—Rh3	127.60 (14)	C2—B11—B12	102.95 (17)
C201—P2—Rh3	118.20 (7)	B6—B11—B7	108.97 (17)
C201—P2—C207	105.89 (10)	B6—B11—B10	59.79 (15)
C207—P2—Rh3	107.49 (7)	B6—B11—H11	118.7 (13)
C213—P2—Rh3	120.79 (7)	B6—B11—B12	107.91 (18)
C213—P2—C201	99.56 (10)	B7—B11—H11	120.9 (14)
C213—P2—C207	103.15 (10)	B10—B11—B7	107.76 (18)
C1—C2—H2	114.6 (16)	B10—B11—H11	125.2 (14)
C1—C2—Rh3	67.32 (10)	B10—B11—B12	60.15 (14)
C1—C2—B6	61.91 (14)	B12—B11—B7	58.96 (14)
C1—C2—B7	112.36 (16)	B12—B11—H11	126.9 (13)
C1—C2—B11	111.92 (17)	B7—B12—B8	61.34 (14)
Rh3—C2—H2	104.1 (17)	B7—B12—B9	108.44 (18)
B6—C2—H2	111.3 (16)	B7—B12—B10	108.87 (17)
B6—C2—Rh3	126.43 (14)	B7—B12—B11	60.74 (14)
B7—C2—H2	124.6 (16)	B7—B12—H12	124.4 (13)
B7—C2—Rh3	69.21 (11)	B8—B12—H12	123.0 (13)
B7—C2—B6	115.82 (17)	B9—B12—B8	60.49 (14)
B11—C2—H2	119.7 (17)	B9—B12—B10	59.86 (15)
B11—C2—Rh3	128.37 (14)	B9—B12—B11	107.58 (17)
B11—C2—B6	62.28 (15)	B9—B12—H12	120.6 (13)
B11—C2—B7	64.07 (14)	B10—B12—B8	109.85 (18)
P1—Rh3—P2	99.23 (2)	B10—B12—H12	117.2 (13)
C1—Rh3—P1	157.40 (6)	B11—B12—B8	110.37 (17)
C1—Rh3—P2	103.37 (6)	B11—B12—B10	59.75 (14)
C1—Rh3—C2	43.81 (8)	B11—B12—H12	120.1 (13)
C1—Rh3—B4	46.07 (9)	N1—O31—Rh3	130.71 (14)
C1—Rh3—B7	77.18 (9)	C102—C101—P1	117.22 (16)
C1—Rh3—B8	78.75 (8)	C106—C101—P1	123.19 (17)
C1—Rh3—O31	98.65 (7)	C106—C101—C102	119.29 (19)
C2—Rh3—P1	113.77 (6)	C101—C102—H102	119.8
C2—Rh3—P2	146.33 (6)	C103—C102—C101	120.5 (2)
C2—Rh3—B4	77.74 (9)	C103—C102—H102	119.8
C2—Rh3—B7	44.62 (8)	C102—C103—H103	120.1
C2—Rh3—B8	77.71 (8)	C104—C103—C102	119.8 (2)
B4—Rh3—P1	139.94 (7)	C104—C103—H103	120.1
B4—Rh3—P2	81.33 (7)	C103—C104—H104	120.0
B4—Rh3—B7	81.22 (9)	C103—C104—C105	120.0 (2)
B4—Rh3—B8	48.30 (9)	C105—C104—H104	120.0
B7—Rh3—P1	82.54 (7)	C104—C105—H105	119.7
B7—Rh3—P2	154.43 (6)	C106—C105—C104	120.6 (2)
B8—Rh3—P1	94.89 (7)	C106—C105—H105	119.7
B8—Rh3—P2	107.01 (7)	C101—C106—H106	120.1
B8—Rh3—B7	47.59 (9)	C105—C106—C101	119.9 (2)
O31—Rh3—P1	85.43 (4)	C105—C106—H106	120.1
O31—Rh3—P2	78.95 (5)	C108—C107—P1	122.52 (16)
O31—Rh3—C2	96.54 (7)	C112—C107—P1	117.62 (16)
O31—Rh3—B4	133.01 (8)	C112—C107—C108	119.0 (2)
O31—Rh3—B7	126.52 (8)	C107—C108—H108	119.7
O31—Rh3—B8	173.86 (8)	C109—C108—C107	120.6 (2)
C1—B4—Rh3	65.90 (11)	C109—C108—H108	119.7
C1—B4—H4	119.7 (13)	C108—C109—H109	120.1
C1—B4—B5	57.44 (13)	C110—C109—C108	119.8 (2)
C1—B4—B8	104.62 (17)	C110—C109—H109	120.1
C1—B4—B9	103.14 (17)	C109—C110—H110	120.0
Rh3—B4—H4	113.8 (14)	C109—C110—C111	120.0 (2)
B5—B4—Rh3	119.58 (15)	C111—C110—H110	120.0
B5—B4—H4	111.1 (14)	C110—C111—H111	119.7
B5—B4—B8	108.24 (17)	C112—C111—C110	120.6 (2)
B8—B4—Rh3	66.55 (11)	C112—C111—H111	119.7
B8—B4—H4	131.7 (13)	C107—C112—H112	120.0
B9—B4—Rh3	120.33 (16)	C111—C112—C107	120.1 (2)
B9—B4—H4	120.9 (13)	C111—C112—H112	120.0
B9—B4—B5	59.81 (14)	C114—C113—P1	121.47 (17)
B9—B4—B8	60.18 (14)	C114—C113—C118	119.3 (2)
C1—B5—B4	58.76 (13)	C118—C113—P1	118.97 (17)
C1—B5—H5	121.1 (13)	C113—C114—H114	119.8
C1—B5—B6	60.09 (14)	C113—C114—C115	120.4 (2)
C1—B5—B9	103.47 (18)	C115—C114—H114	119.8
C1—B5—B10	105.25 (18)	C114—C115—H115	120.0
B4—B5—H5	118.8 (14)	C116—C115—C114	119.9 (2)
B6—B5—B4	109.65 (18)	C116—C115—H115	120.0
B6—B5—H5	120.4 (13)	C115—C116—H116	120.0
B6—B5—B9	108.13 (19)	C115—C116—C117	120.0 (2)
B6—B5—B10	60.07 (15)	C117—C116—H116	120.0
B9—B5—B4	58.93 (14)	C116—C117—H117	119.9
B9—B5—H5	125.4 (13)	C118—C117—C116	120.2 (2)
B10—B5—B4	108.17 (18)	C118—C117—H117	119.9
B10—B5—H5	125.8 (14)	C113—C118—H118	119.9
B10—B5—B9	60.14 (15)	C117—C118—C113	120.2 (2)
C1—B6—B5	58.13 (14)	C117—C118—H118	119.9
C1—B6—H6	120.8 (13)	C202—C201—P2	117.99 (16)
C1—B6—B10	103.93 (17)	C206—C201—P2	123.43 (17)
C1—B6—B11	103.95 (17)	C206—C201—C202	118.6 (2)
C2—B6—C1	56.50 (13)	C201—C202—H202	119.6
C2—B6—B5	103.61 (17)	C203—C202—C201	120.8 (2)
C2—B6—H6	119.0 (13)	C203—C202—H202	119.6
C2—B6—B10	103.50 (17)	C202—C203—H203	120.1
C2—B6—B11	57.79 (14)	C202—C203—C204	119.7 (2)
B5—B6—H6	125.8 (13)	C204—C203—H203	120.1
B5—B6—B10	60.28 (15)	C203—C204—H204	120.0
B5—B6—B11	108.59 (18)	C205—C204—C203	120.1 (2)
B10—B6—H6	129.9 (13)	C205—C204—H204	120.0
B11—B6—H6	121.7 (13)	C204—C205—H205	119.8
B11—B6—B10	60.49 (15)	C204—C205—C206	120.5 (2)
C2—B7—Rh3	66.17 (11)	C206—C205—H205	119.8
C2—B7—H7	120.6 (13)	C201—C206—H206	119.9
C2—B7—B8	105.33 (17)	C205—C206—C201	120.3 (2)
C2—B7—B11	57.82 (13)	C205—C206—H206	119.9
C2—B7—B12	103.76 (17)	C208—C207—P2	120.85 (17)
Rh3—B7—H7	112.7 (14)	C208—C207—C212	118.3 (2)
B8—B7—Rh3	65.82 (11)	C212—C207—P2	120.77 (17)
B8—B7—H7	129.2 (14)	C207—C208—H208	119.7
B11—B7—Rh3	119.97 (15)	C209—C208—C207	120.6 (2)
B11—B7—H7	113.0 (14)	C209—C208—H208	119.7
B11—B7—B8	109.10 (18)	C208—C209—H209	119.6
B12—B7—Rh3	119.56 (15)	C210—C209—C208	120.8 (2)
B12—B7—H7	121.5 (14)	C210—C209—H209	119.6
B12—B7—B8	60.19 (14)	C209—C210—H210	120.4
B12—B7—B11	60.30 (14)	C209—C210—C211	119.3 (2)
Rh3—B8—H8	116.4 (12)	C211—C210—H210	120.4
B4—B8—Rh3	65.14 (10)	C210—C211—H211	119.8
B4—B8—H8	126.6 (12)	C210—C211—C212	120.4 (2)
B7—B8—Rh3	66.58 (10)	C212—C211—H211	119.8
B7—B8—B4	106.26 (16)	C207—C212—H212	119.7
B7—B8—H8	123.6 (12)	C211—C212—C207	120.6 (2)
B9—B8—Rh3	117.42 (14)	C211—C212—H212	119.7
B9—B8—B4	58.28 (14)	C214—C213—P2	122.89 (17)
B9—B8—B7	105.34 (17)	C214—C213—C218	118.9 (2)
B9—B8—H8	117.6 (12)	C218—C213—P2	118.18 (16)
B12—B8—Rh3	118.74 (14)	C213—C214—H214	119.9
B12—B8—B4	105.78 (17)	C213—C214—C215	120.3 (2)
B12—B8—B7	58.47 (14)	C215—C214—H214	119.9
B12—B8—H8	115.3 (12)	C214—C215—H215	119.7
B12—B8—B9	59.39 (14)	C216—C215—C214	120.5 (2)
B4—B9—B5	61.26 (14)	C216—C215—H215	119.7
B4—B9—B8	61.54 (14)	C215—C216—H216	120.1
B4—B9—H9	119.7 (14)	C215—C216—C217	119.9 (2)
B4—B9—B10	109.66 (17)	C217—C216—H216	120.1
B4—B9—B12	108.93 (18)	C216—C217—H217	120.1
B5—B9—B8	110.46 (17)	C218—C217—C216	119.8 (2)
B5—B9—H9	120.0 (13)	C218—C217—H217	120.1
B8—B9—H9	120.8 (14)	C213—C218—H218	119.7
B10—B9—B5	59.66 (15)	C217—C218—C213	120.5 (2)
B10—B9—B8	109.89 (18)	C217—C218—H218	119.7
B10—B9—H9	120.9 (14)
P1—C101—C102—C103	173.70 (17)	B5—B9—B12—B8	103.83 (18)
P1—C101—C106—C105	−172.80 (18)	B5—B9—B12—B10	−37.42 (17)
P1—C107—C108—C109	169.21 (18)	B5—B9—B12—B11	−0.1 (2)
P1—C107—C112—C111	−169.17 (17)	B5—B10—B11—C2	4.2 (2)
P1—C113—C114—C115	175.69 (18)	B5—B10—B11—B6	−37.13 (17)
P1—C113—C118—C117	−176.25 (17)	B5—B10—B11—B7	64.9 (2)
C1—C2—B6—B5	−35.74 (15)	B5—B10—B11—B12	100.99 (19)
C1—C2—B6—B10	−97.93 (18)	B5—B10—B12—B7	−63.2 (2)
C1—C2—B6—B11	−139.34 (17)	B5—B10—B12—B8	2.3 (2)
C1—C2—B7—Rh3	−52.97 (14)	B5—B10—B12—B9	37.69 (17)
C1—C2—B7—B8	1.2 (2)	B5—B10—B12—B11	−100.28 (19)
C1—C2—B7—B11	104.41 (19)	B6—C1—C2—Rh3	−162.30 (13)
C1—C2—B7—B12	63.6 (2)	B6—C1—C2—B7	−108.31 (19)
C1—C2—B11—B6	38.29 (17)	B6—C1—C2—B11	−38.44 (17)
C1—C2—B11—B7	−105.09 (18)	B6—C1—B4—Rh3	122.50 (16)
C1—C2—B11—B10	−3.0 (2)	B6—C1—B4—B5	−35.51 (18)
C1—C2—B11—B12	−65.1 (2)	B6—C1—B4—B8	67.0 (2)
C1—B4—B5—B6	33.30 (16)	B6—C1—B4—B9	4.9 (2)
C1—B4—B5—B9	133.12 (19)	B6—C1—B5—B4	143.38 (18)
C1—B4—B5—B10	97.17 (19)	B6—C1—B5—B9	103.37 (19)
C1—B4—B8—Rh3	55.04 (12)	B6—C1—B5—B10	41.11 (16)
C1—B4—B8—B7	1.3 (2)	B6—C2—B7—Rh3	−121.46 (17)
C1—B4—B8—B9	−96.97 (18)	B6—C2—B7—B8	−67.3 (2)
C1—B4—B8—B12	−59.78 (19)	B6—C2—B7—B11	35.92 (18)
C1—B4—B9—B5	−39.18 (16)	B6—C2—B7—B12	−4.9 (2)
C1—B4—B9—B8	99.49 (17)	B6—C2—B11—B7	−143.38 (18)
C1—B4—B9—B10	−3.1 (2)	B6—C2—B11—B10	−41.29 (16)
C1—B4—B9—B12	61.2 (2)	B6—C2—B11—B12	−103.39 (19)
C1—B5—B6—C2	34.99 (15)	B6—B5—B9—B4	102.47 (19)
C1—B5—B6—B10	132.95 (18)	B6—B5—B9—B8	64.2 (2)
C1—B5—B6—B11	95.18 (18)	B6—B5—B9—B10	−37.50 (17)
C1—B5—B9—B4	39.92 (16)	B6—B5—B9—B12	0.2 (2)
C1—B5—B9—B8	1.6 (2)	B6—B5—B10—B9	138.12 (19)
C1—B5—B9—B10	−100.05 (19)	B6—B5—B10—B11	37.15 (17)
C1—B5—B9—B12	−62.4 (2)	B6—B5—B10—B12	100.58 (19)
C1—B5—B10—B6	−41.12 (16)	B6—B10—B11—C2	41.36 (16)
C1—B5—B10—B9	97.00 (19)	B6—B10—B11—B7	102.03 (18)
C1—B5—B10—B11	−4.0 (2)	B6—B10—B11—B12	138.12 (18)
C1—B5—B10—B12	59.5 (2)	B6—B10—B12—B7	−0.1 (2)
C1—B6—B10—B5	39.83 (16)	B6—B10—B12—B8	65.3 (2)
C1—B6—B10—B9	2.3 (2)	B6—B10—B12—B9	100.70 (19)
C1—B6—B10—B11	−98.33 (18)	B6—B10—B12—B11	−37.27 (17)
C1—B6—B10—B12	−60.9 (2)	B6—B11—B12—B7	−101.78 (19)
C1—B6—B11—C2	−34.04 (15)	B6—B11—B12—B8	−64.4 (2)
C1—B6—B11—B7	−1.7 (2)	B6—B11—B12—B9	−0.1 (2)
C1—B6—B11—B10	98.31 (18)	B6—B11—B12—B10	37.32 (17)
C1—B6—B11—B12	60.8 (2)	B7—C2—B6—C1	102.76 (19)
P2—C201—C202—C203	−177.24 (18)	B7—C2—B6—B5	67.0 (2)
P2—C201—C206—C205	176.63 (17)	B7—C2—B6—B10	4.8 (2)
P2—C207—C208—C209	−177.74 (18)	B7—C2—B6—B11	−36.58 (18)
P2—C207—C212—C211	178.36 (17)	B7—C2—B11—B6	143.38 (18)
P2—C213—C214—C215	176.81 (18)	B7—C2—B11—B10	102.08 (18)
P2—C213—C218—C217	−178.32 (19)	B7—C2—B11—B12	39.99 (16)
C2—C1—B4—Rh3	54.84 (14)	B7—B8—B9—B4	−99.89 (17)
C2—C1—B4—B5	−103.16 (19)	B7—B8—B9—B5	−61.7 (2)
C2—C1—B4—B8	−0.6 (2)	B7—B8—B9—B10	2.3 (2)
C2—C1—B4—B9	−62.8 (2)	B7—B8—B9—B12	37.60 (15)
C2—C1—B5—B4	104.48 (18)	B7—B8—B12—B9	−136.35 (18)
C2—C1—B5—B6	−38.90 (17)	B7—B8—B12—B10	−101.22 (19)
C2—C1—B5—B9	64.5 (2)	B7—B8—B12—B11	−37.14 (17)
C2—C1—B5—B10	2.2 (2)	B7—B11—B12—B8	37.40 (17)
C2—C1—B6—B5	138.05 (18)	B7—B11—B12—B9	101.70 (19)
C2—C1—B6—B10	97.14 (18)	B7—B11—B12—B10	139.10 (19)
C2—C1—B6—B11	34.62 (15)	B8—B4—B5—C1	−96.01 (18)
C2—B6—B10—B5	98.14 (18)	B8—B4—B5—B6	−62.7 (2)
C2—B6—B10—B9	60.7 (2)	B8—B4—B5—B9	37.11 (16)
C2—B6—B10—B11	−40.02 (16)	B8—B4—B5—B10	1.2 (2)
C2—B6—B10—B12	−2.6 (2)	B8—B4—B9—B5	−138.67 (18)
C2—B6—B11—B7	32.38 (16)	B8—B4—B9—B10	−102.5 (2)
C2—B6—B11—B10	132.35 (18)	B8—B4—B9—B12	−38.28 (16)
C2—B6—B11—B12	94.87 (19)	B8—B7—B11—C2	96.47 (18)
C2—B7—B8—Rh3	−54.39 (13)	B8—B7—B11—B6	63.4 (2)
C2—B7—B8—B4	−1.5 (2)	B8—B7—B11—B10	0.0 (2)
C2—B7—B8—B9	59.3 (2)	B8—B7—B11—B12	−36.57 (16)
C2—B7—B8—B12	97.31 (18)	B8—B7—B12—B9	39.29 (17)
C2—B7—B11—B6	−33.09 (16)	B8—B7—B12—B10	102.84 (19)
C2—B7—B11—B10	−96.43 (19)	B8—B7—B12—B11	139.54 (18)
C2—B7—B11—B12	−133.03 (19)	B8—B9—B10—B5	−102.66 (19)
C2—B7—B12—B8	−99.98 (17)	B8—B9—B10—B6	−65.4 (2)
C2—B7—B12—B9	−60.7 (2)	B8—B9—B10—B11	−2.3 (2)
C2—B7—B12—B10	2.9 (2)	B8—B9—B10—B12	35.25 (16)
C2—B7—B12—B11	39.57 (16)	B8—B9—B12—B7	−39.68 (16)
C2—B11—B12—B7	−39.55 (16)	B8—B9—B12—B10	−141.25 (17)
C2—B11—B12—B8	−2.2 (2)	B8—B9—B12—B11	−103.90 (18)
C2—B11—B12—B9	62.1 (2)	B9—B4—B5—C1	−133.12 (19)
C2—B11—B12—B10	99.55 (19)	B9—B4—B5—B6	−99.8 (2)
Rh3—P1—C101—C102	−76.38 (17)	B9—B4—B5—B10	−35.95 (17)
Rh3—P1—C101—C106	97.27 (18)	B9—B4—B8—Rh3	152.01 (15)
Rh3—P1—C107—C108	139.30 (16)	B9—B4—B8—B7	98.26 (18)
Rh3—P1—C107—C112	−51.64 (19)	B9—B4—B8—B12	37.19 (16)
Rh3—P1—C113—C114	17.7 (2)	B9—B5—B6—C1	−95.42 (19)
Rh3—P1—C113—C118	−167.90 (15)	B9—B5—B6—C2	−60.4 (2)
Rh3—C1—C2—B6	162.30 (13)	B9—B5—B6—B10	37.53 (17)
Rh3—C1—C2—B7	53.99 (14)	B9—B5—B6—B11	−0.2 (2)
Rh3—C1—C2—B11	123.85 (16)	B9—B5—B10—B6	−138.12 (19)
Rh3—C1—B4—B5	−158.01 (15)	B9—B5—B10—B11	−100.96 (19)
Rh3—C1—B4—B8	−55.45 (12)	B9—B5—B10—B12	−37.54 (17)
Rh3—C1—B4—B9	−117.62 (15)	B9—B8—B12—B7	136.35 (18)
Rh3—C1—B5—B4	25.90 (17)	B9—B8—B12—B10	35.13 (17)
Rh3—C1—B5—B6	−117.49 (19)	B9—B8—B12—B11	99.2 (2)
Rh3—C1—B5—B9	−14.1 (2)	B9—B10—B11—C2	−59.3 (2)
Rh3—C1—B5—B10	−76.4 (2)	B9—B10—B11—B6	−100.64 (19)
Rh3—C1—B6—C2	−20.98 (16)	B9—B10—B11—B7	1.4 (2)
Rh3—C1—B6—B5	117.08 (19)	B9—B10—B11—B12	37.48 (16)
Rh3—C1—B6—B10	76.2 (2)	B9—B10—B12—B7	−100.84 (19)
Rh3—C1—B6—B11	13.6 (2)	B9—B10—B12—B8	−35.39 (16)
Rh3—P2—C201—C202	−98.22 (17)	B9—B10—B12—B11	−137.97 (18)
Rh3—P2—C201—C206	82.64 (19)	B10—B5—B6—C1	−132.95 (18)
Rh3—P2—C207—C208	114.23 (18)	B10—B5—B6—C2	−97.96 (18)
Rh3—P2—C207—C212	−62.25 (18)	B10—B5—B6—B11	−37.77 (17)
Rh3—P2—C213—C214	4.2 (2)	B10—B5—B9—B4	139.97 (19)
Rh3—P2—C213—C218	−177.81 (15)	B10—B5—B9—B8	101.7 (2)
Rh3—C2—B6—C1	20.41 (15)	B10—B5—B9—B12	37.69 (17)
Rh3—C2—B6—B5	−15.3 (2)	B10—B6—B11—C2	−132.35 (18)
Rh3—C2—B6—B10	−77.5 (2)	B10—B6—B11—B7	−99.97 (19)
Rh3—C2—B6—B11	−118.93 (18)	B10—B6—B11—B12	−37.48 (17)
Rh3—C2—B7—B8	54.18 (13)	B10—B9—B12—B7	101.57 (18)
Rh3—C2—B7—B11	157.38 (15)	B10—B9—B12—B8	141.25 (17)
Rh3—C2—B7—B12	116.55 (15)	B10—B9—B12—B11	37.35 (17)
Rh3—C2—B11—B6	116.1 (2)	B10—B11—B12—B7	−139.10 (18)
Rh3—C2—B11—B7	−27.30 (18)	B10—B11—B12—B8	−101.7 (2)
Rh3—C2—B11—B10	74.8 (2)	B10—B11—B12—B9	−37.40 (17)
Rh3—C2—B11—B12	12.7 (3)	B11—C2—B6—C1	139.34 (17)
Rh3—B4—B5—C1	−23.15 (15)	B11—C2—B6—B5	103.60 (18)
Rh3—B4—B5—B6	10.2 (2)	B11—C2—B6—B10	41.41 (16)
Rh3—B4—B5—B9	109.97 (18)	B11—C2—B7—Rh3	−157.38 (15)
Rh3—B4—B5—B10	74.0 (2)	B11—C2—B7—B8	−103.20 (18)
Rh3—B4—B8—B7	−53.75 (13)	B11—C2—B7—B12	−40.82 (17)
Rh3—B4—B8—B9	−152.01 (15)	B11—B6—B10—B5	138.16 (19)
Rh3—B4—B8—B12	−114.82 (15)	B11—B6—B10—B9	100.7 (2)
Rh3—B4—B9—B5	−108.74 (19)	B11—B6—B10—B12	37.44 (17)
Rh3—B4—B9—B8	29.92 (16)	B11—B7—B8—Rh3	−115.09 (15)
Rh3—B4—B9—B10	−72.6 (2)	B11—B7—B8—B4	−62.2 (2)
Rh3—B4—B9—B12	−8.4 (2)	B11—B7—B8—B9	−1.4 (2)
Rh3—B7—B8—B4	52.88 (13)	B11—B7—B8—B12	36.62 (16)
Rh3—B7—B8—B9	113.68 (15)	B11—B7—B12—B8	−139.54 (18)
Rh3—B7—B8—B12	151.71 (15)	B11—B7—B12—B9	−100.26 (19)
Rh3—B7—B11—C2	23.97 (15)	B11—B7—B12—B10	−36.71 (17)
Rh3—B7—B11—B6	−9.1 (2)	B11—B10—B12—B7	37.13 (17)
Rh3—B7—B11—B10	−72.5 (2)	B11—B10—B12—B8	102.58 (19)
Rh3—B7—B11—B12	−109.07 (18)	B11—B10—B12—B9	137.97 (18)
Rh3—B7—B12—B8	−29.81 (15)	B12—B7—B8—Rh3	−151.71 (15)
Rh3—B7—B12—B9	9.5 (2)	B12—B7—B8—B4	−98.82 (18)
Rh3—B7—B12—B10	73.0 (2)	B12—B7—B8—B9	−38.03 (16)
Rh3—B7—B12—B11	109.73 (18)	B12—B7—B11—C2	133.03 (19)
Rh3—B8—B9—B4	−28.67 (15)	B12—B7—B11—B6	99.9 (2)
Rh3—B8—B9—B5	9.5 (2)	B12—B7—B11—B10	36.60 (17)
Rh3—B8—B9—B10	73.5 (2)	B12—B8—B9—B4	−137.48 (17)
Rh3—B8—B9—B12	108.82 (17)	B12—B8—B9—B5	−99.3 (2)
Rh3—B8—B12—B7	29.74 (16)	B12—B8—B9—B10	−35.30 (16)
Rh3—B8—B12—B9	−106.61 (17)	B12—B9—B10—B5	−137.90 (18)
Rh3—B8—B12—B10	−71.5 (2)	B12—B9—B10—B6	−100.66 (19)
Rh3—B8—B12—B11	−7.4 (2)	B12—B9—B10—B11	−37.58 (16)
B4—C1—C2—Rh3	−54.37 (14)	B12—B10—B11—C2	−96.76 (18)
B4—C1—C2—B6	107.92 (18)	B12—B10—B11—B6	−138.12 (18)
B4—C1—C2—B7	−0.4 (2)	B12—B10—B11—B7	−36.09 (16)
B4—C1—C2—B11	69.5 (2)	O32—N1—O31—Rh3	158.66 (15)
B4—C1—B5—B6	−143.38 (18)	O33—N1—O31—Rh3	−22.5 (3)
B4—C1—B5—B9	−40.01 (17)	C101—P1—C107—C108	12.4 (2)
B4—C1—B5—B10	−102.28 (19)	C101—P1—C107—C112	−178.56 (17)
B4—C1—B6—C2	−101.79 (19)	C101—P1—C113—C114	139.44 (18)
B4—C1—B6—B5	36.26 (18)	C101—P1—C113—C118	−46.1 (2)
B4—C1—B6—B10	−4.7 (2)	C101—C102—C103—C104	−0.2 (3)
B4—C1—B6—B11	−67.2 (2)	C102—C101—C106—C105	0.7 (3)
B4—B5—B6—C1	−32.79 (16)	C102—C103—C104—C105	0.1 (4)
B4—B5—B6—C2	2.2 (2)	C103—C104—C105—C106	0.4 (4)
B4—B5—B6—B10	100.2 (2)	C104—C105—C106—C101	−0.8 (4)
B4—B5—B6—B11	62.4 (2)	C106—C101—C102—C103	−0.2 (3)
B4—B5—B9—B8	−38.30 (17)	C107—P1—C101—C102	58.69 (19)
B4—B5—B9—B10	−139.97 (19)	C107—P1—C101—C106	−127.66 (19)
B4—B5—B9—B12	−102.28 (19)	C107—P1—C113—C114	−113.92 (19)
B4—B5—B10—B6	−102.68 (19)	C107—P1—C113—C118	60.53 (19)
B4—B5—B10—B9	35.44 (17)	C107—C108—C109—C110	−0.5 (3)
B4—B5—B10—B11	−65.5 (2)	C108—C107—C112—C111	0.3 (3)
B4—B5—B10—B12	−2.1 (2)	C108—C109—C110—C111	0.2 (4)
B4—B8—B9—B5	38.17 (17)	C109—C110—C111—C112	0.4 (4)
B4—B8—B9—B10	102.18 (19)	C110—C111—C112—C107	−0.6 (3)
B4—B8—B9—B12	137.48 (17)	C112—C107—C108—C109	0.3 (3)
B4—B8—B12—B7	99.67 (17)	C113—P1—C101—C102	160.35 (17)
B4—B8—B12—B9	−36.68 (15)	C113—P1—C101—C106	−26.0 (2)
B4—B8—B12—B10	−1.5 (2)	C113—P1—C107—C108	−97.11 (19)
B4—B8—B12—B11	62.5 (2)	C113—P1—C107—C112	71.94 (18)
B4—B9—B10—B5	−36.79 (17)	C113—C114—C115—C116	0.2 (3)
B4—B9—B10—B6	0.5 (2)	C114—C113—C118—C117	−1.7 (3)
B4—B9—B10—B11	63.5 (2)	C114—C115—C116—C117	−1.3 (4)
B4—B9—B10—B12	101.11 (19)	C115—C116—C117—C118	0.9 (3)
B4—B9—B12—B7	−0.8 (2)	C116—C117—C118—C113	0.6 (3)
B4—B9—B12—B8	38.91 (16)	C118—C113—C114—C115	1.3 (3)
B4—B9—B12—B10	−102.34 (19)	C201—P2—C207—C208	−118.55 (19)
B4—B9—B12—B11	−65.0 (2)	C201—P2—C207—C212	64.97 (19)
B5—C1—C2—Rh3	−123.32 (15)	C201—P2—C213—C214	−126.9 (2)
B5—C1—C2—B6	38.98 (17)	C201—P2—C213—C218	51.0 (2)
B5—C1—C2—B7	−69.3 (2)	C201—C202—C203—C204	0.3 (4)
B5—C1—C2—B11	0.5 (2)	C202—C201—C206—C205	−2.5 (3)
B5—C1—B4—Rh3	158.01 (15)	C202—C203—C204—C205	−2.0 (4)
B5—C1—B4—B8	102.55 (18)	C203—C204—C205—C206	1.4 (4)
B5—C1—B4—B9	40.38 (17)	C204—C205—C206—C201	0.9 (4)
B5—C1—B6—C2	−138.05 (18)	C206—C201—C202—C203	1.9 (3)
B5—C1—B6—B10	−40.91 (17)	C207—P2—C201—C202	141.30 (17)
B5—C1—B6—B11	−103.44 (19)	C207—P2—C201—C206	−37.8 (2)
B5—B4—B8—Rh3	115.06 (16)	C207—P2—C213—C214	124.14 (19)
B5—B4—B8—B7	61.3 (2)	C207—P2—C213—C218	−57.9 (2)
B5—B4—B8—B9	−36.95 (16)	C207—C208—C209—C210	−0.3 (4)
B5—B4—B8—B12	0.2 (2)	C208—C207—C212—C211	1.8 (3)
B5—B4—B9—B8	138.67 (18)	C208—C209—C210—C211	1.1 (4)
B5—B4—B9—B10	36.13 (18)	C209—C210—C211—C212	−0.5 (4)
B5—B4—B9—B12	100.39 (19)	C210—C211—C212—C207	−1.0 (3)
B5—B6—B10—B9	−37.49 (18)	C212—C207—C208—C209	−1.2 (3)
B5—B6—B10—B11	−138.16 (19)	C213—P2—C201—C202	34.57 (19)
B5—B6—B10—B12	−100.7 (2)	C213—P2—C201—C206	−144.57 (19)
B5—B6—B11—C2	−94.68 (19)	C213—P2—C207—C208	−14.4 (2)
B5—B6—B11—B7	−62.3 (2)	C213—P2—C207—C212	169.08 (18)
B5—B6—B11—B10	37.67 (17)	C213—C214—C215—C216	1.3 (3)
B5—B6—B11—B12	0.2 (2)	C214—C213—C218—C217	−0.3 (3)
B5—B9—B10—B6	37.25 (17)	C214—C215—C216—C217	0.0 (4)
B5—B9—B10—B11	100.33 (19)	C215—C216—C217—C218	−1.4 (4)
B5—B9—B10—B12	137.90 (18)	C216—C217—C218—C213	1.6 (4)
B5—B9—B12—B7	64.2 (2)	C218—C213—C214—C215	−1.1 (3)

Selected geometric parameters (Å, °).

Rh3—C1	2.184 (2)	Rh3—P1	2.3789 (6)
Rh3—C2	2.208 (2)	Rh3—P2	2.3931 (6)
Rh3—B7	2.256 (2)	Rh3—O31	2.1982 (14)
Rh3—B8	2.243 (2)	O31—N1	1.265 (2)
Rh3—B4	2.219 (2)	N1—O32	1.231 (2)
C1—C2	1.639 (3)	N1—O33	1.234 (3)
P1—Rh3—P2	99.23 (2)	O31—N1—O32	117.74 (19)
P1—Rh3—O31	85.43 (4)	O31—N1—O33	119.99 (19)
P2—Rh3—O31	78.95 (5)	O32—N1—O33	122.3 (2)
Rh3—O31—N1	130.71 (14)