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The manganese(II) coordination polymer, poly[bis­(2,2′-bipyridine)tris­(μ-1,4-phenyl­enediacetato-κ4O,O′:O′′,O′′′)­tri­manganese(II)], [Mn3(C10H8O4)3(C10H8N2)2]n, consists of linear trinuclear building blocks with two crystallographically unique Mn atoms. One MnII ion and the geometric centre of one 1,4-phenyl­enediacetate ligand in the trinuclear unit both lie on inversion centres. Trinuclear units are bridged by 1,4-phenyl­enediacetate ligands to yield a two-dimensional network which stacks into a three-dimensional supra­molecular structure via π–π stacking inter­actions.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806034556/ez2028sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806034556/ez2028Isup2.hkl
Contains datablock I

CCDC reference: 614328

Key indicators

  • Single-crystal X-ray study
  • T = 298 K
  • Mean [sigma](C-C) = 0.006 Å
  • R factor = 0.045
  • wR factor = 0.136
  • Data-to-parameter ratio = 13.0

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT094_ALERT_2_B Ratio of Maximum / Minimum Residual Density .... 5.08
Alert level C PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for O2 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for O4 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for O6 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C7 PLAT601_ALERT_2_C Structure Contains Solvent Accessible VOIDS of . 45.00 A   3
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 5 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 6 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXTL.

poly[bis(2,2'-bipyridine)tris(µ-1,4-phenylenediacetato- κ4O,O':O'',O''')trimanganese(II)] top
Crystal data top
[Mn3(C10H8O4)3(C10H8N2)2]Z = 1
Mr = 1053.68F(000) = 539
Triclinic, P1Dx = 1.498 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 8.604 (3) ÅCell parameters from 2138 reflections
b = 11.207 (3) Åθ = 2.4–25.8°
c = 13.444 (4) ŵ = 0.87 mm1
α = 111.958 (3)°T = 298 K
β = 100.522 (4)°Block, yellow
γ = 94.042 (4)°0.28 × 0.15 × 0.13 mm
V = 1168.4 (6) Å3
Data collection top
Bruker SMART CCD area-detector
diffractometer
4060 independent reflections
Radiation source: fine-focus sealed tube2912 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.021
φ and ω scansθmax = 25.0°, θmin = 1.7°
Absorption correction: multi-scan
(SADABS; Bruker, 1998)
h = 610
Tmin = 0.793, Tmax = 0.896k = 1312
6109 measured reflectionsl = 1515
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.045Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.136H-atom parameters constrained
S = 1.00 w = 1/[σ2(Fo2) + (0.0765P)2 + 0.5301P]
where P = (Fo2 + 2Fc2)/3
4060 reflections(Δ/σ)max < 0.001
313 parametersΔρmax = 1.27 e Å3
0 restraintsΔρmin = 0.25 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Mn10.50000.50000.50000.0289 (2)
Mn20.22039 (7)0.37896 (5)0.23004 (4)0.03285 (19)
N10.1455 (4)0.2962 (3)0.0446 (2)0.0393 (8)
N20.0258 (4)0.4236 (3)0.1851 (3)0.0384 (8)
O10.2889 (3)0.3714 (3)0.4887 (2)0.0407 (6)
O20.1299 (4)0.2866 (3)0.3215 (2)0.0523 (8)
O30.3546 (3)0.5509 (2)0.37072 (19)0.0364 (6)
O40.3247 (4)0.5780 (3)0.2165 (2)0.0514 (8)
O50.5746 (3)0.3382 (3)0.3799 (2)0.0447 (7)
O60.4176 (4)0.2821 (3)0.2147 (2)0.0555 (9)
C10.1789 (5)0.2906 (3)0.4162 (3)0.0330 (8)
C20.0977 (5)0.1846 (4)0.4427 (3)0.0414 (10)
H2A0.08980.22050.51910.050*
H2B0.00990.15470.39710.050*
C30.1889 (4)0.0704 (3)0.4233 (3)0.0344 (9)
C40.2021 (5)0.0042 (4)0.4930 (3)0.0437 (10)
H40.15300.03000.55230.052*
C50.2640 (5)0.0266 (4)0.3362 (3)0.0435 (10)
H50.25600.06720.28690.052*
C60.3771 (4)0.6209 (3)0.3179 (3)0.0325 (8)
C70.4686 (5)0.7559 (4)0.3793 (4)0.0562 (12)
H7A0.52340.76430.45200.067*
H7B0.54930.76850.34090.067*
C80.3652 (5)0.8606 (4)0.3915 (3)0.0391 (10)
C90.3496 (5)0.9252 (4)0.3206 (4)0.0448 (10)
H90.39840.89890.26130.054*
C100.2870 (5)0.9006 (4)0.4756 (4)0.0465 (11)
H100.29110.85680.52250.056*
C110.5289 (5)0.2680 (4)0.2803 (3)0.0348 (9)
C120.6197 (5)0.1540 (4)0.2351 (3)0.0441 (10)
H12A0.73170.18790.24820.053*
H12B0.61250.09860.27540.053*
C130.5585 (5)0.0723 (3)0.1136 (3)0.0353 (9)
C140.4153 (5)0.0095 (4)0.0732 (3)0.0433 (10)
H140.35580.01730.12230.052*
C150.6434 (5)0.0809 (4)0.0386 (3)0.0421 (10)
H150.74130.13520.06320.050*
C160.2365 (6)0.2327 (4)0.0221 (3)0.0521 (12)
H160.33120.21160.00830.063*
C170.1950 (6)0.1975 (5)0.1342 (3)0.0589 (13)
H170.26090.15320.17860.071*
C180.0566 (6)0.2280 (5)0.1796 (4)0.0580 (13)
H180.02700.20500.25520.070*
C190.0392 (5)0.2936 (4)0.1120 (3)0.0474 (11)
H190.13370.31600.14130.057*
C200.0071 (5)0.3253 (4)0.0005 (3)0.0376 (9)
C210.0917 (5)0.3923 (4)0.0786 (3)0.0360 (9)
C220.2446 (5)0.4166 (5)0.0448 (4)0.0543 (12)
H220.28830.39540.02940.065*
C230.3299 (5)0.4723 (5)0.1228 (4)0.0587 (13)
H230.43290.48810.10160.070*
C240.2632 (6)0.5049 (5)0.2320 (4)0.0622 (14)
H240.31900.54340.28590.075*
C250.1101 (6)0.4785 (5)0.2596 (4)0.0548 (12)
H250.06410.50010.33350.066*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Mn10.0422 (5)0.0229 (4)0.0177 (4)0.0039 (3)0.0026 (3)0.0056 (3)
Mn20.0398 (4)0.0278 (3)0.0251 (3)0.0081 (3)0.0024 (2)0.0080 (2)
N10.048 (2)0.0368 (18)0.0286 (17)0.0130 (16)0.0025 (15)0.0113 (14)
N20.0398 (19)0.0438 (19)0.0337 (18)0.0121 (16)0.0038 (15)0.0187 (15)
O10.0431 (16)0.0377 (15)0.0393 (16)0.0008 (13)0.0029 (13)0.0168 (13)
O20.061 (2)0.0482 (17)0.0458 (18)0.0036 (15)0.0072 (15)0.0278 (15)
O30.0490 (16)0.0289 (13)0.0286 (14)0.0009 (12)0.0001 (12)0.0133 (11)
O40.0591 (19)0.0609 (19)0.0372 (17)0.0066 (16)0.0029 (15)0.0294 (15)
O50.0564 (18)0.0413 (15)0.0236 (15)0.0176 (14)0.0024 (13)0.0002 (12)
O60.065 (2)0.0540 (18)0.0304 (15)0.0358 (16)0.0054 (14)0.0000 (13)
C10.035 (2)0.0292 (19)0.036 (2)0.0095 (17)0.0076 (18)0.0136 (17)
C20.041 (2)0.038 (2)0.051 (3)0.0025 (18)0.012 (2)0.024 (2)
C30.037 (2)0.0285 (19)0.035 (2)0.0063 (16)0.0016 (17)0.0157 (16)
C40.050 (3)0.045 (2)0.038 (2)0.003 (2)0.007 (2)0.0223 (19)
C50.066 (3)0.036 (2)0.040 (2)0.013 (2)0.012 (2)0.0271 (19)
C60.030 (2)0.0303 (19)0.037 (2)0.0078 (16)0.0010 (17)0.0166 (17)
C70.047 (3)0.038 (2)0.079 (3)0.002 (2)0.012 (2)0.031 (2)
C80.037 (2)0.0270 (19)0.048 (2)0.0042 (17)0.0087 (19)0.0190 (18)
C90.059 (3)0.037 (2)0.043 (2)0.009 (2)0.012 (2)0.0196 (19)
C100.052 (3)0.045 (2)0.047 (3)0.006 (2)0.007 (2)0.033 (2)
C110.042 (2)0.0315 (19)0.025 (2)0.0086 (17)0.0060 (18)0.0054 (16)
C120.061 (3)0.042 (2)0.0209 (19)0.025 (2)0.0016 (18)0.0031 (17)
C130.048 (2)0.032 (2)0.0246 (19)0.0201 (19)0.0090 (18)0.0074 (16)
C140.061 (3)0.041 (2)0.029 (2)0.011 (2)0.017 (2)0.0116 (18)
C150.049 (3)0.034 (2)0.036 (2)0.0096 (19)0.007 (2)0.0071 (18)
C160.063 (3)0.053 (3)0.037 (2)0.026 (2)0.008 (2)0.012 (2)
C170.079 (4)0.060 (3)0.033 (2)0.024 (3)0.012 (2)0.010 (2)
C180.080 (4)0.058 (3)0.028 (2)0.008 (3)0.002 (2)0.014 (2)
C190.056 (3)0.048 (2)0.033 (2)0.006 (2)0.005 (2)0.017 (2)
C200.043 (2)0.033 (2)0.033 (2)0.0041 (18)0.0029 (18)0.0152 (17)
C210.037 (2)0.033 (2)0.038 (2)0.0041 (17)0.0006 (18)0.0182 (17)
C220.049 (3)0.065 (3)0.049 (3)0.007 (2)0.007 (2)0.030 (2)
C230.039 (3)0.080 (3)0.067 (3)0.018 (2)0.010 (2)0.040 (3)
C240.054 (3)0.081 (4)0.077 (4)0.031 (3)0.030 (3)0.048 (3)
C250.057 (3)0.071 (3)0.050 (3)0.023 (3)0.017 (2)0.035 (3)
Geometric parameters (Å, º) top
Mn1—O52.158 (2)C7—H7B0.9700
Mn1—O5i2.158 (2)C8—C101.368 (6)
Mn1—O1i2.183 (3)C8—C91.391 (5)
Mn1—O12.183 (3)C9—C5iii1.369 (5)
Mn1—O32.227 (2)C9—H90.9300
Mn1—O3i2.227 (2)C10—C4iii1.384 (6)
Mn2—O62.078 (3)C10—H100.9300
Mn2—O22.092 (3)C11—C121.532 (5)
Mn2—O32.188 (2)C12—C131.511 (5)
Mn2—N22.238 (3)C12—H12A0.9700
Mn2—N12.256 (3)C12—H12B0.9700
Mn2—O42.428 (3)C13—C141.370 (6)
N1—C161.335 (5)C13—C151.375 (5)
N1—C201.353 (5)C14—C15iv1.386 (5)
N2—C251.333 (5)C14—H140.9300
N2—C211.339 (5)C15—C14iv1.386 (5)
O1—C11.244 (4)C15—H150.9300
O2—C11.249 (4)C16—C171.377 (6)
O3—C61.266 (4)C16—H160.9300
O4—C61.244 (4)C17—C181.363 (6)
O5—C111.242 (4)C17—H170.9300
O6—C111.240 (4)C18—C191.380 (6)
C1—C21.521 (5)C18—H180.9300
C2—C31.513 (5)C19—C201.377 (5)
C2—H2A0.9700C19—H190.9300
C2—H2B0.9700C20—C211.496 (5)
C3—C51.386 (5)C21—C221.392 (6)
C3—C41.391 (5)C22—C231.373 (6)
C4—C10ii1.384 (6)C22—H220.9300
C4—H40.9300C23—C241.372 (7)
C5—C9ii1.369 (5)C23—H230.9300
C5—H50.9300C24—C251.385 (6)
C6—C71.501 (6)C24—H240.9300
C7—C81.501 (5)C25—H250.9300
C7—H7A0.9700
O5—Mn1—O5i180.00 (12)O3—C6—C7119.0 (4)
O5—Mn1—O1i90.43 (11)C8—C7—C6113.4 (3)
O5i—Mn1—O1i89.57 (11)C8—C7—H7A108.9
O5—Mn1—O189.57 (11)C6—C7—H7A108.9
O5i—Mn1—O190.43 (11)C8—C7—H7B108.9
O1i—Mn1—O1180.000 (1)C6—C7—H7B108.9
O5—Mn1—O392.58 (10)H7A—C7—H7B107.7
O5i—Mn1—O387.42 (9)C10—C8—C9116.8 (4)
O1i—Mn1—O391.70 (10)C10—C8—C7121.5 (4)
O1—Mn1—O388.30 (10)C9—C8—C7121.6 (4)
O5—Mn1—O3i87.42 (9)C5iii—C9—C8121.6 (4)
O5i—Mn1—O3i92.58 (9)C5iii—C9—H9119.2
O1i—Mn1—O3i88.30 (10)C8—C9—H9119.2
O1—Mn1—O3i91.70 (10)C8—C10—C4iii122.1 (4)
O3—Mn1—O3i180.000 (1)C8—C10—H10119.0
O6—Mn2—O294.96 (13)C4iii—C10—H10119.0
O6—Mn2—O393.67 (11)O6—C11—O5126.1 (3)
O2—Mn2—O396.55 (11)O6—C11—C12117.4 (3)
O6—Mn2—N2158.67 (11)O5—C11—C12116.5 (3)
O2—Mn2—N287.72 (12)C13—C12—C11114.0 (3)
O3—Mn2—N2107.08 (11)C13—C12—H12A108.8
O6—Mn2—N188.13 (11)C11—C12—H12A108.8
O2—Mn2—N1121.26 (12)C13—C12—H12B108.8
O3—Mn2—N1141.87 (11)C11—C12—H12B108.8
N2—Mn2—N172.56 (12)H12A—C12—H12B107.7
O6—Mn2—O499.96 (12)C14—C13—C15117.4 (3)
O2—Mn2—O4149.27 (11)C14—C13—C12121.9 (4)
O3—Mn2—O456.02 (9)C15—C13—C12120.7 (4)
N2—Mn2—O487.96 (11)C13—C14—C15iv121.9 (4)
N1—Mn2—O486.14 (11)C13—C14—H14119.1
C16—N1—C20118.4 (3)C15iv—C14—H14119.1
C16—N1—Mn2124.0 (3)C13—C15—C14iv120.7 (4)
C20—N1—Mn2117.1 (2)C13—C15—H15119.6
C25—N2—C21118.7 (3)C14iv—C15—H15119.6
C25—N2—Mn2122.8 (3)N1—C16—C17122.2 (4)
C21—N2—Mn2118.5 (2)N1—C16—H16118.9
C1—O1—Mn1138.5 (2)C17—C16—H16118.9
C1—O2—Mn2133.0 (3)C18—C17—C16119.4 (4)
C6—O3—Mn297.1 (2)C18—C17—H17120.3
C6—O3—Mn1137.0 (2)C16—C17—H17120.3
Mn2—O3—Mn1112.48 (10)C17—C18—C19119.2 (4)
C6—O4—Mn286.5 (2)C17—C18—H18120.4
C11—O5—Mn1137.6 (2)C19—C18—H18120.4
C11—O6—Mn2134.8 (3)C20—C19—C18119.0 (4)
O1—C1—O2125.7 (4)C20—C19—H19120.5
O1—C1—C2118.1 (3)C18—C19—H19120.5
O2—C1—C2116.2 (3)N1—C20—C19121.7 (4)
C3—C2—C1111.7 (3)N1—C20—C21115.5 (3)
C3—C2—H2A109.3C19—C20—C21122.8 (4)
C1—C2—H2A109.3N2—C21—C22121.5 (4)
C3—C2—H2B109.3N2—C21—C20115.6 (3)
C1—C2—H2B109.3C22—C21—C20122.8 (4)
H2A—C2—H2B107.9C23—C22—C21118.8 (4)
C5—C3—C4116.6 (4)C23—C22—H22120.6
C5—C3—C2122.2 (3)C21—C22—H22120.6
C4—C3—C2121.3 (4)C24—C23—C22120.0 (4)
C10ii—C4—C3121.1 (4)C24—C23—H23120.0
C10ii—C4—H4119.5C22—C23—H23120.0
C3—C4—H4119.5C23—C24—C25118.0 (4)
C9ii—C5—C3121.8 (4)C23—C24—H24121.0
C9ii—C5—H5119.1C25—C24—H24121.0
C3—C5—H5119.1N2—C25—C24122.9 (4)
O4—C6—O3120.4 (3)N2—C25—H25118.5
O4—C6—C7120.6 (4)C24—C25—H25118.5
O6—Mn2—N1—C169.0 (3)Mn2—O2—C1—O112.3 (6)
O2—Mn2—N1—C16103.7 (3)Mn2—O2—C1—C2166.2 (3)
O3—Mn2—N1—C1684.5 (4)O1—C1—C2—C384.3 (4)
N2—Mn2—N1—C16179.9 (4)O2—C1—C2—C394.3 (4)
O4—Mn2—N1—C1691.1 (3)C1—C2—C3—C537.4 (5)
O6—Mn2—N1—C20178.2 (3)C1—C2—C3—C4142.3 (4)
O2—Mn2—N1—C2083.5 (3)C5—C3—C4—C10ii0.4 (6)
O3—Mn2—N1—C2088.2 (3)C2—C3—C4—C10ii179.3 (4)
N2—Mn2—N1—C207.4 (3)C4—C3—C5—C9ii1.3 (6)
O4—Mn2—N1—C2081.7 (3)C2—C3—C5—C9ii178.4 (4)
O6—Mn2—N2—C25148.3 (4)Mn2—O4—C6—O30.1 (3)
O2—Mn2—N2—C2550.5 (3)Mn2—O4—C6—C7179.8 (3)
O3—Mn2—N2—C2545.7 (3)Mn2—O3—C6—O40.2 (4)
N1—Mn2—N2—C25174.3 (4)Mn1—O3—C6—O4134.1 (3)
O4—Mn2—N2—C2599.1 (3)Mn2—O3—C6—C7179.8 (3)
O6—Mn2—N2—C2130.9 (5)Mn1—O3—C6—C745.6 (5)
O2—Mn2—N2—C21128.7 (3)O4—C6—C7—C873.5 (5)
O3—Mn2—N2—C21135.2 (3)O3—C6—C7—C8106.8 (4)
N1—Mn2—N2—C214.8 (3)C6—C7—C8—C1085.1 (5)
O4—Mn2—N2—C2181.8 (3)C6—C7—C8—C997.6 (5)
O5—Mn1—O1—C150.1 (4)C10—C8—C9—C5iii1.9 (6)
O5i—Mn1—O1—C1129.9 (4)C7—C8—C9—C5iii175.5 (4)
O3—Mn1—O1—C142.5 (4)C9—C8—C10—C4iii2.9 (6)
O3i—Mn1—O1—C1137.5 (4)C7—C8—C10—C4iii174.6 (4)
O6—Mn2—O2—C167.4 (4)Mn2—O6—C11—O519.8 (7)
O3—Mn2—O2—C126.8 (4)Mn2—O6—C11—C12160.5 (3)
N2—Mn2—O2—C1133.8 (4)Mn1—O5—C11—O65.8 (7)
N1—Mn2—O2—C1158.2 (3)Mn1—O5—C11—C12174.5 (3)
O4—Mn2—O2—C151.6 (5)O6—C11—C12—C130.2 (6)
O6—Mn2—O3—C699.6 (2)O5—C11—C12—C13180.0 (4)
O2—Mn2—O3—C6164.9 (2)C11—C12—C13—C1472.1 (5)
N2—Mn2—O3—C675.3 (2)C11—C12—C13—C15105.8 (4)
N1—Mn2—O3—C68.0 (3)C15—C13—C14—C15iv0.3 (6)
O4—Mn2—O3—C60.1 (2)C12—C13—C14—C15iv177.7 (3)
O6—Mn2—O3—Mn148.45 (14)C14—C13—C15—C14iv0.3 (6)
O2—Mn2—O3—Mn146.98 (14)C12—C13—C15—C14iv177.7 (3)
N2—Mn2—O3—Mn1136.60 (12)C20—N1—C16—C170.7 (7)
N1—Mn2—O3—Mn1140.08 (15)Mn2—N1—C16—C17172.0 (4)
O4—Mn2—O3—Mn1147.99 (17)N1—C16—C17—C180.0 (7)
O5—Mn1—O3—C688.2 (3)C16—C17—C18—C190.1 (7)
O5i—Mn1—O3—C691.8 (3)C17—C18—C19—C200.6 (7)
O1i—Mn1—O3—C62.3 (3)C16—N1—C20—C191.4 (6)
O1—Mn1—O3—C6177.7 (3)Mn2—N1—C20—C19171.8 (3)
O5—Mn1—O3—Mn241.55 (13)C16—N1—C20—C21177.9 (3)
O5i—Mn1—O3—Mn2138.45 (13)Mn2—N1—C20—C218.9 (4)
O1i—Mn1—O3—Mn2132.06 (12)C18—C19—C20—N11.4 (6)
O1—Mn1—O3—Mn247.94 (12)C18—C19—C20—C21177.9 (4)
O6—Mn2—O4—C687.8 (2)C25—N2—C21—C220.5 (6)
O2—Mn2—O4—C630.1 (3)Mn2—N2—C21—C22179.6 (3)
O3—Mn2—O4—C60.1 (2)C25—N2—C21—C20177.2 (4)
N2—Mn2—O4—C6112.1 (2)Mn2—N2—C21—C202.0 (4)
N1—Mn2—O4—C6175.2 (2)N1—C20—C21—N24.6 (5)
O1i—Mn1—O5—C11111.7 (4)C19—C20—C21—N2176.1 (4)
O1—Mn1—O5—C1168.3 (4)N1—C20—C21—C22173.0 (4)
O3—Mn1—O5—C1119.9 (4)C19—C20—C21—C226.3 (6)
O3i—Mn1—O5—C11160.1 (4)N2—C21—C22—C230.9 (6)
O2—Mn2—O6—C1155.2 (4)C20—C21—C22—C23176.6 (4)
O3—Mn2—O6—C1141.7 (4)C21—C22—C23—C241.0 (7)
N2—Mn2—O6—C11151.7 (4)C22—C23—C24—C250.6 (7)
N1—Mn2—O6—C11176.4 (4)C21—N2—C25—C240.1 (7)
O4—Mn2—O6—C1197.8 (4)Mn2—N2—C25—C24179.2 (4)
Mn1—O1—C1—O223.9 (6)C23—C24—C25—N20.1 (7)
Mn1—O1—C1—C2154.7 (3)
Symmetry codes: (i) x+1, y+1, z+1; (ii) x, y1, z; (iii) x, y+1, z; (iv) x+1, y, z.
 

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