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The title compounds, sodium titanyl phosphate and potassium titanyl phosphate, are isostructural, belonging to a family of compounds with interesting non-linear optical properties. The effect of substitution of K by Na has been analysed by X-ray diffraction at 110 K. The substitution does not modify the geometry of the phosphate groups; however, the Ti-O coordination distances are changed, as well as the relative orientation of the Ti and P polyhedra.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks default, 1, 2

hkl

Structure factor file (CIF format)
Contains datablock 1

hkl

Structure factor file (CIF format)
Contains datablock 2

-1
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