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Pb5Al3F19 undergoes three phase transitions between 80 and 400K. The structure at 370K contains corner-sharing AlF6 octahedra and individual AlF6 octahedra. The Pb atoms occupy tunnels of 2.5Å radii.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, Pb5Al3F19

hkl

Structure factor file (CIF format)
Supplementary material

-1
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