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The title compound, [Pr(C5HF6O2)3(C6H14O3)] or [Pr(hfpd)3(2g)], was prepared by the reaction of PrCl3·7H2O and hfpd-H (1,1,1,5,5,5-hexafluoropentane-2,4-dione) in the presence of aqueous ammonia and recrystallization of the product from n-hexane in the presence of diglyme (2g). The metal atom is nine-coordinate, bonded to three bidentate β-diketonato ligands and the polyether molecule.
Supporting information
CCDC reference: 225648
Key indicators
- Single-crystal X-ray study
- T = 293 K
- Mean (C-C) = 0.003 Å
- R factor = 0.035
- wR factor = 0.086
- Data-to-parameter ratio = 8.6
checkCIF/PLATON results
No syntax errors found
Alert level A
PLAT027_ALERT_3_A _diffrn_reflns_theta_full too Low .............. 24.94 Deg.
PLAT029_ALERT_3_A _diffrn_measured_fraction_theta_full Low ....... 0.82
PLAT242_ALERT_2_A Check Low U(eq) as Compared to Neighbors .... C15
| Author Response: This alarm is due to the high ADPs of all fluorine atoms in the six
CF3 groups. In particular, four (out of six) -CF~3~ groups of the compound
were disordered between two orientations and were assigned partial occupancy.
|
Alert level B
REFLT03_ALERT_3_B Reflection count < 90% complete (theta max?)
From the CIF: _diffrn_reflns_theta_max 24.94
From the CIF: _diffrn_reflns_theta_full 0.00
From the CIF: _reflns_number_total 4785
TEST2: Reflns within _diffrn_reflns_theta_max
Count of symmetry unique reflns 5629
Completeness (_total/calc) 85.01%
PLAT022_ALERT_3_B Ratio Unique / Expected Reflections too Low .... 0.85
| Author Response: Same as above.
|
PLAT242_ALERT_2_B Check Low U(eq) as Compared to Neighbors .... C1
| Author Response: This alarm is due to the high ADPs of all fluorine atoms in the six
CF3 groups. In particular, four (out of six) -CF~3~ groups of the compound
were disordered between two orientations and were assigned partial occupancy.
|
PLAT242_ALERT_2_B Check Low U(eq) as Compared to Neighbors .... C5
| Author Response: This alarm is due to the high ADPs of all fluorine atoms in the six
CF3 groups. In particular, four (out of six) -CF~3~ groups of the compound
were disordered between two orientations and were assigned partial occupancy.
|
PLAT242_ALERT_2_B Check Low U(eq) as Compared to Neighbors .... C6
| Author Response: This alarm is due to the high ADPs of all fluorine atoms in the six
CF3 groups. In particular, four (out of six) -CF~3~ groups of the compound
were disordered between two orientations and were assigned partial occupancy.
|
PLAT242_ALERT_2_B Check Low U(eq) as Compared to Neighbors .... C10
| Author Response: This alarm is due to the high ADPs of all fluorine atoms in the six
CF3 groups. In particular, four (out of six) -CF~3~ groups of the compound
were disordered between two orientations and were assigned partial occupancy.
|
PLAT242_ALERT_2_B Check Low U(eq) as Compared to Neighbors .... C11
| Author Response: This alarm is due to the high ADPs of all fluorine atoms in the six
CF3 groups. In particular, four (out of six) -CF~3~ groups of the compound
were disordered between two orientations and were assigned partial occupancy.
|
Alert level C
REFNR01_ALERT_3_C Ratio of reflections to parameters is < 10 for a
centrosymmetric structure
sine(theta)/lambda -0.2695
Proportion of unique data used 1.0000
Ratio reflections to parameters 8.6216
PLAT062_ALERT_4_C Rescale T(min) & T(max) by ..................... 0.97
PLAT088_ALERT_3_C Poor Data / Parameter Ratio .................... 8.62
| Author Response: This is an inevitable consequence of the introduction of additional
parameters to treat the disordered F atoms.
|
PLAT213_ALERT_2_C Atom F2B has ADP max/min Ratio ............. 3.70 prolat
| Author Response: The high ADP max/min ratio for the F atoms is attributed to
disorder. In particular, four (out of six) -CF~3~ groups of the compound
were disordered between two orientations and were assigned partial occupancy.
|
PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors .... C2
| Author Response: This alarm is due to the high ADPs of all fluorine atoms in the six
CF3 groups. In particular, four (out of six) -CF~3~ groups of the compound
were disordered between two orientations and were assigned partial occupancy.
|
PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors .... C7
| Author Response: This alarm is due to the high ADPs of all fluorine atoms in the six
CF3 groups. In particular, four (out of six) -CF~3~ groups of the compound
were disordered between two orientations and were assigned partial occupancy.
|
PLAT301_ALERT_3_C Main Residue Disorder ......................... 20.00 Perc.
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ...... 39.50 Deg.
F1A -C1 -F1B 1.555 1.555 1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ...... 43.20 Deg.
F2B -C1 -F2A 1.555 1.555 1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ...... 37.50 Deg.
F12B -C10 -F12A 1.555 1.555 1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ...... 43.20 Deg.
F11A -C10 -F11B 1.555 1.555 1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ...... 43.10 Deg.
F15B -C11 -F15A 1.555 1.555 1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ...... 41.90 Deg.
F14B -C11 -F14A 1.555 1.555 1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ...... 42.90 Deg.
F13A -C11 -F13B 1.555 1.555 1.555
3 ALERT level A = In general: serious problem
7 ALERT level B = Potentially serious problem
14 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
16 ALERT type 2 Indicator that the structure model may be wrong or deficient
7 ALERT type 3 Indicator that the structure quality may be low
1 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: Mar Research image-plate scanner software; cell refinement: XDS (Kabsch, 1993); data reduction: XDS; program(s) used to solve structure: SIR97 (Altomare et al., 1999) and SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.
Crystal data top
[Pr(C6H14O3)(C5HF6O2)3] | F(000) = 1744 |
Mr = 896.26 | Dx = 1.848 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2ybc | Cell parameters from 4409 reflections |
a = 10.013 (3) Å | θ = 2.5–24.0° |
b = 15.656 (4) Å | µ = 1.66 mm−1 |
c = 21.133 (5) Å | T = 293 K |
β = 103.48 (4)° | Prism, green |
V = 3221.7 (15) Å3 | 0.45 × 0.30 × 0.20 mm |
Z = 4 | |
Data collection top
Mar Research Image Plate Scanner diffractometer | 4785 independent reflections |
Radiation source: fine-focus sealed tube | 4219 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.039 |
rotation method scans | θmax = 24.9°, θmin = 2.5° |
Absorption correction: empirical (using intensity measurements) (XDS; Kabsch, 1993) | h = −11→11 |
Tmin = 0.542, Tmax = 0.741 | k = 0→18 |
9202 measured reflections | l = −24→24 |
Refinement top
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.035 | H-atom parameters constrained |
wR(F2) = 0.086 | w = 1/[σ2(Fo2) + (0.0312P)2 + 8.0994P] where P = (Fo2 + 2Fc2)/3 |
S = 1.09 | (Δ/σ)max = 0.010 |
4785 reflections | Δρmax = 0.84 e Å−3 |
555 parameters | Δρmin = −0.71 e Å−3 |
228 restraints | Extinction correction: SHELXL97, Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
Primary atom site location: structure-invariant direct methods | Extinction coefficient: 0.00417 (8) |
Special details top
Experimental. Each crystal was mounted on a Mar Research Image Plate Scanner and 95 frames
were measured with an exposure time of 120 s per frame. Scan mode:
omega/2theta. The crystal-detector distance was 75 mm. Data were processed
using the XDS package. |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | Occ. (<1) |
Pr1 | 0.069057 (10) | 0.188557 (7) | 0.375402 (5) | 0.04224 (3) | |
O1 | −0.13948 (15) | 0.12542 (10) | 0.30245 (7) | 0.0603 (5) | |
O2 | 0.08399 (14) | 0.18612 (10) | 0.26125 (7) | 0.0563 (4) | |
O3 | −0.07670 (15) | 0.30667 (9) | 0.32247 (7) | 0.0571 (4) | |
O4 | −0.10505 (14) | 0.21586 (9) | 0.43552 (7) | 0.0525 (4) | |
O5 | 0.14084 (15) | 0.32476 (9) | 0.43135 (7) | 0.0578 (5) | |
O6 | 0.22596 (14) | 0.16472 (8) | 0.48402 (7) | 0.0509 (4) | |
O7 | 0.30949 (14) | 0.23393 (10) | 0.35791 (7) | 0.0618 (5) | |
O8 | 0.23969 (15) | 0.06558 (9) | 0.36708 (7) | 0.0581 (4) | |
O9 | 0.01139 (15) | 0.03882 (9) | 0.41508 (8) | 0.0631 (5) | |
C2 | −0.1872 (2) | 0.11907 (14) | 0.24269 (10) | 0.0556 (6) | |
C3 | −0.1233 (2) | 0.13855 (17) | 0.19336 (11) | 0.0655 (8) | |
H3 | −0.1703 | 0.1306 | 0.1503 | 0.079* | |
C4 | 0.0094 (2) | 0.16973 (14) | 0.20684 (10) | 0.0524 (6) | |
C7 | −0.1727 (2) | 0.34812 (13) | 0.33597 (11) | 0.0560 (7) | |
C8 | −0.2325 (2) | 0.33367 (15) | 0.38621 (12) | 0.0649 (8) | |
H8 | −0.3031 | 0.3704 | 0.3902 | 0.078* | |
C9 | −0.1991 (2) | 0.27019 (13) | 0.43169 (10) | 0.0511 (6) | |
C12 | 0.2285 (2) | 0.34887 (13) | 0.47987 (10) | 0.0517 (6) | |
C13 | 0.3135 (2) | 0.29909 (13) | 0.52667 (11) | 0.0540 (6) | |
H13 | 0.3772 | 0.3253 | 0.5601 | 0.065* | |
C14 | 0.3050 (2) | 0.21078 (13) | 0.52447 (10) | 0.0482 (6) | |
C16 | 0.3199 (3) | 0.31355 (17) | 0.32600 (15) | 0.0888 (10) | |
H16A | 0.2697 | 0.3567 | 0.3430 | 0.133* | |
H16B | 0.2823 | 0.3074 | 0.2801 | 0.133* | |
H16C | 0.4146 | 0.3300 | 0.3335 | 0.133* | |
C17 | 0.3851 (2) | 0.16765 (17) | 0.33431 (12) | 0.0708 (8) | |
H17A | 0.4797 | 0.1853 | 0.3386 | 0.085* | |
H17B | 0.3449 | 0.1566 | 0.2887 | 0.085* | |
C18 | 0.3801 (2) | 0.08940 (17) | 0.37303 (13) | 0.0709 (8) | |
H18A | 0.4290 | 0.0435 | 0.3574 | 0.085* | |
H18B | 0.4239 | 0.0999 | 0.4184 | 0.085* | |
C19 | 0.2275 (3) | −0.01017 (15) | 0.40322 (13) | 0.0754 (9) | |
H19A | 0.2676 | −0.0009 | 0.4491 | 0.090* | |
H19B | 0.2758 | −0.0570 | 0.3883 | 0.090* | |
C20 | 0.0799 (3) | −0.03094 (14) | 0.39315 (13) | 0.0833 (10) | |
H20A | 0.0406 | −0.0414 | 0.3473 | 0.100* | |
H20B | 0.0687 | −0.0822 | 0.4172 | 0.100* | |
C21 | −0.1245 (3) | 0.01409 (17) | 0.41996 (13) | 0.0842 (9) | |
H21A | −0.1686 | 0.0615 | 0.4355 | 0.126* | |
H21B | −0.1181 | −0.0328 | 0.4498 | 0.126* | |
H21C | −0.1773 | −0.0029 | 0.3779 | 0.126* | |
C1 | −0.3335 (3) | 0.08497 (17) | 0.22402 (12) | 0.0893 (10) | |
F1A | −0.3732 (3) | 0.0455 (2) | 0.16808 (15) | 0.1251 (12) | 0.513 (2) |
F2A | −0.4167 (3) | 0.1525 (3) | 0.22269 (19) | 0.1410 (16) | 0.513 (2) |
F3A | −0.3691 (3) | 0.0337 (3) | 0.26662 (18) | 0.1528 (14) | 0.513 (2) |
F1B | −0.3936 (3) | 0.1010 (3) | 0.16187 (15) | 0.1162 (14) | 0.487 (2) |
F2B | −0.4124 (3) | 0.1134 (3) | 0.25827 (17) | 0.1455 (15) | 0.487 (2) |
F3B | −0.3242 (4) | 0.0009 (3) | 0.2344 (2) | 0.1479 (17) | 0.487 (2) |
C5 | 0.0765 (3) | 0.18856 (18) | 0.14975 (12) | 0.0715 (8) | |
F4 | 0.20657 (16) | 0.16964 (15) | 0.16407 (8) | 0.1161 (8) | |
F5 | 0.0204 (2) | 0.14662 (16) | 0.09587 (8) | 0.1253 (8) | |
F6 | 0.0668 (2) | 0.26896 (12) | 0.13475 (9) | 0.1318 (7) | |
C6 | −0.22559 (18) | 0.42011 (13) | 0.28763 (10) | 0.1005 (12) | |
F7A | −0.1827 (8) | 0.4903 (3) | 0.3201 (3) | 0.158 (3) | 0.175 (2) |
F8A | −0.3601 (4) | 0.4133 (6) | 0.2697 (4) | 0.150 (3) | 0.175 (2) |
F9A | −0.1777 (6) | 0.4129 (6) | 0.23526 (19) | 0.147 (3) | 0.175 (2) |
F7B | −0.3146 (2) | 0.47148 (14) | 0.30611 (13) | 0.1539 (10) | 0.825 (2) |
F8B | −0.2858 (3) | 0.38816 (18) | 0.23078 (10) | 0.1648 (13) | 0.825 (2) |
F9B | −0.1263 (3) | 0.46869 (13) | 0.27741 (13) | 0.1432 (10) | 0.825 (2) |
C10 | −0.2833 (2) | 0.25884 (15) | 0.48230 (11) | 0.0704 (8) | |
F10A | −0.3045 (4) | 0.3319 (2) | 0.51236 (15) | 0.1082 (11) | 0.5178 (18) |
F11A | −0.3997 (3) | 0.2229 (3) | 0.45974 (17) | 0.1325 (14) | 0.5178 (18) |
F12A | −0.2226 (3) | 0.2120 (2) | 0.53337 (14) | 0.0956 (10) | 0.5178 (18) |
F10B | −0.3939 (3) | 0.3058 (3) | 0.47125 (19) | 0.1170 (14) | 0.4822 (18) |
F11B | −0.3333 (3) | 0.1790 (2) | 0.47713 (19) | 0.1109 (13) | 0.4822 (18) |
F12B | −0.2152 (4) | 0.2643 (3) | 0.53961 (16) | 0.1280 (16) | 0.4822 (18) |
C11 | 0.2446 (2) | 0.44698 (15) | 0.48712 (11) | 0.0755 (9) | |
F13A | 0.2482 (3) | 0.48447 (19) | 0.43297 (16) | 0.1293 (15) | 0.514 (2) |
F14A | 0.3568 (3) | 0.4718 (2) | 0.52958 (17) | 0.1234 (15) | 0.514 (2) |
F15A | 0.1377 (4) | 0.4794 (2) | 0.50489 (14) | 0.1262 (14) | 0.514 (2) |
F13B | 0.3396 (3) | 0.4702 (2) | 0.45603 (19) | 0.1300 (15) | 0.486 (2) |
F14B | 0.2791 (4) | 0.4712 (2) | 0.54695 (14) | 0.1229 (15) | 0.486 (2) |
F15B | 0.1322 (4) | 0.4863 (2) | 0.45923 (17) | 0.1459 (18) | 0.486 (2) |
C15 | 0.4018 (3) | 0.16205 (16) | 0.57834 (12) | 0.0655 (8) | |
F16 | 0.51845 (18) | 0.20016 (13) | 0.60288 (10) | 0.1298 (8) | |
F17 | 0.3473 (2) | 0.14388 (14) | 0.62608 (8) | 0.1299 (7) | |
F18 | 0.4370 (2) | 0.08789 (12) | 0.55864 (10) | 0.1590 (8) | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Pr1 | 0.04514 (5) | 0.04373 (5) | 0.03962 (5) | 0.00202 (4) | 0.01347 (5) | 0.00231 (4) |
O1 | 0.0584 (8) | 0.0752 (9) | 0.0485 (7) | −0.0124 (7) | 0.0153 (7) | 0.0008 (7) |
O2 | 0.0532 (7) | 0.0735 (9) | 0.0446 (7) | −0.0017 (7) | 0.0162 (6) | 0.0013 (6) |
O3 | 0.0653 (8) | 0.0578 (8) | 0.0495 (7) | 0.0097 (7) | 0.0157 (7) | 0.0097 (6) |
O4 | 0.0537 (7) | 0.0562 (7) | 0.0519 (7) | 0.0058 (6) | 0.0208 (6) | 0.0059 (6) |
O5 | 0.0666 (8) | 0.0475 (7) | 0.0575 (8) | 0.0063 (6) | 0.0107 (7) | −0.0004 (6) |
O6 | 0.0535 (7) | 0.0465 (7) | 0.0490 (7) | 0.0020 (6) | 0.0043 (7) | 0.0009 (6) |
O7 | 0.0571 (7) | 0.0719 (9) | 0.0617 (8) | −0.0058 (7) | 0.0244 (7) | −0.0019 (7) |
O8 | 0.0622 (8) | 0.0553 (8) | 0.0569 (8) | 0.0135 (7) | 0.0142 (7) | −0.0060 (6) |
O9 | 0.0673 (8) | 0.0497 (7) | 0.0715 (9) | −0.0046 (7) | 0.0143 (8) | 0.0110 (7) |
C2 | 0.0479 (10) | 0.0658 (12) | 0.0538 (11) | −0.0005 (10) | 0.0131 (10) | −0.0045 (10) |
C3 | 0.0586 (12) | 0.0934 (16) | 0.0445 (11) | 0.0007 (12) | 0.0120 (11) | −0.0040 (11) |
C4 | 0.0536 (10) | 0.0613 (12) | 0.0452 (10) | 0.0111 (9) | 0.0173 (9) | 0.0066 (9) |
C7 | 0.0611 (12) | 0.0481 (10) | 0.0553 (12) | 0.0015 (10) | 0.0062 (11) | 0.0075 (9) |
C8 | 0.0535 (12) | 0.0710 (14) | 0.0660 (14) | 0.0041 (11) | 0.0053 (12) | 0.0143 (11) |
C9 | 0.0458 (10) | 0.0562 (11) | 0.0520 (11) | −0.0044 (9) | 0.0131 (9) | −0.0098 (9) |
C12 | 0.0616 (10) | 0.0458 (10) | 0.0548 (11) | −0.0026 (9) | 0.0279 (9) | −0.0071 (8) |
C13 | 0.0548 (11) | 0.0529 (11) | 0.0525 (11) | −0.0061 (9) | 0.0087 (10) | −0.0084 (9) |
C14 | 0.0462 (10) | 0.0567 (11) | 0.0429 (10) | 0.0017 (9) | 0.0132 (9) | 0.0020 (8) |
C16 | 0.0954 (16) | 0.0830 (17) | 0.0968 (19) | −0.0261 (14) | 0.0400 (14) | 0.0064 (14) |
C17 | 0.0437 (10) | 0.1028 (18) | 0.0700 (14) | −0.0002 (11) | 0.0218 (10) | −0.0162 (13) |
C18 | 0.0551 (11) | 0.0847 (15) | 0.0735 (15) | 0.0185 (11) | 0.0162 (11) | −0.0067 (12) |
C19 | 0.0947 (16) | 0.0477 (11) | 0.0824 (16) | 0.0175 (12) | 0.0178 (14) | −0.0015 (11) |
C20 | 0.131 (2) | 0.0356 (11) | 0.0804 (16) | −0.0079 (13) | 0.0197 (16) | −0.0078 (11) |
C21 | 0.0786 (15) | 0.0817 (15) | 0.0901 (17) | −0.0238 (13) | 0.0154 (14) | 0.0277 (13) |
C1 | 0.0645 (14) | 0.116 (2) | 0.0850 (18) | −0.0199 (15) | 0.0124 (14) | −0.0202 (16) |
F1A | 0.0956 (18) | 0.191 (3) | 0.0911 (18) | −0.0702 (18) | 0.0269 (16) | −0.0764 (17) |
F2A | 0.0764 (16) | 0.241 (4) | 0.120 (3) | −0.006 (2) | 0.0517 (17) | 0.007 (3) |
F3A | 0.1082 (18) | 0.232 (3) | 0.117 (2) | −0.1030 (18) | 0.0238 (18) | 0.021 (2) |
F1B | 0.0677 (18) | 0.194 (3) | 0.075 (2) | −0.041 (2) | −0.0093 (17) | −0.001 (2) |
F2B | 0.0737 (14) | 0.274 (4) | 0.114 (2) | −0.049 (2) | 0.0727 (14) | −0.078 (2) |
F3B | 0.129 (2) | 0.170 (3) | 0.144 (3) | −0.084 (2) | 0.032 (2) | −0.029 (3) |
C5 | 0.0645 (13) | 0.1029 (18) | 0.0480 (12) | 0.0027 (13) | 0.0148 (11) | 0.0096 (12) |
F4 | 0.0752 (8) | 0.209 (2) | 0.0736 (9) | 0.0257 (11) | 0.0369 (8) | 0.0277 (11) |
F5 | 0.1299 (12) | 0.1939 (19) | 0.0642 (9) | −0.0312 (13) | 0.0472 (9) | −0.0284 (11) |
F6 | 0.1822 (16) | 0.1083 (12) | 0.1277 (12) | 0.0137 (12) | 0.0821 (11) | 0.0540 (9) |
C6 | 0.120 (2) | 0.0730 (16) | 0.102 (2) | 0.0349 (15) | 0.0121 (19) | 0.0240 (15) |
F7A | 0.197 (6) | 0.096 (5) | 0.181 (6) | 0.033 (5) | 0.048 (5) | 0.067 (5) |
F8A | 0.176 (6) | 0.138 (5) | 0.127 (5) | 0.072 (5) | 0.012 (5) | 0.054 (5) |
F9A | 0.201 (6) | 0.117 (5) | 0.115 (5) | 0.020 (5) | 0.018 (5) | 0.082 (4) |
F7B | 0.1808 (17) | 0.1188 (13) | 0.171 (2) | 0.0982 (12) | 0.0603 (16) | 0.0646 (13) |
F8B | 0.215 (3) | 0.156 (2) | 0.0849 (13) | 0.019 (2) | −0.0426 (17) | 0.0387 (14) |
F9B | 0.178 (2) | 0.0852 (12) | 0.1711 (18) | 0.0047 (14) | 0.0507 (16) | 0.0703 (11) |
C10 | 0.0593 (11) | 0.0851 (16) | 0.0758 (14) | 0.0027 (11) | 0.0342 (10) | −0.0028 (12) |
F10A | 0.161 (2) | 0.0919 (19) | 0.0932 (18) | 0.0151 (18) | 0.0724 (17) | −0.0173 (15) |
F11A | 0.0605 (14) | 0.239 (3) | 0.100 (2) | −0.0748 (18) | 0.0219 (15) | −0.033 (2) |
F12A | 0.0988 (16) | 0.1085 (19) | 0.0974 (17) | 0.0337 (15) | 0.0591 (14) | 0.0459 (14) |
F10B | 0.0790 (15) | 0.164 (3) | 0.129 (2) | 0.0311 (18) | 0.0674 (15) | 0.007 (2) |
F11B | 0.0826 (17) | 0.145 (3) | 0.119 (2) | −0.0285 (18) | 0.0520 (16) | 0.015 (2) |
F12B | 0.114 (2) | 0.209 (4) | 0.0667 (18) | −0.030 (3) | 0.0311 (19) | −0.043 (2) |
C11 | 0.0943 (17) | 0.0506 (12) | 0.0808 (16) | −0.0046 (12) | 0.0188 (14) | −0.0053 (12) |
F13A | 0.233 (3) | 0.0517 (15) | 0.109 (2) | −0.010 (2) | 0.051 (2) | 0.0191 (15) |
F14A | 0.126 (2) | 0.0607 (16) | 0.161 (3) | −0.0278 (17) | −0.012 (2) | −0.0174 (19) |
F15A | 0.157 (2) | 0.0668 (17) | 0.172 (3) | 0.0231 (18) | 0.074 (2) | −0.0243 (18) |
F13B | 0.173 (3) | 0.0711 (19) | 0.158 (3) | −0.0423 (19) | 0.063 (2) | 0.013 (2) |
F14B | 0.219 (4) | 0.0640 (17) | 0.0878 (19) | −0.015 (2) | 0.039 (2) | −0.0365 (15) |
F15B | 0.167 (3) | 0.0576 (18) | 0.191 (4) | 0.035 (2) | −0.004 (3) | −0.012 (2) |
C15 | 0.0635 (13) | 0.0750 (14) | 0.0537 (12) | −0.0010 (12) | 0.0049 (12) | 0.0077 (11) |
F16 | 0.0808 (11) | 0.1421 (14) | 0.1335 (14) | −0.0282 (10) | −0.0420 (11) | 0.0533 (11) |
F17 | 0.1129 (12) | 0.1845 (16) | 0.0950 (10) | 0.0283 (12) | 0.0300 (10) | 0.0784 (10) |
F18 | 0.1773 (15) | 0.1196 (12) | 0.1318 (15) | 0.0932 (10) | −0.0619 (13) | −0.0226 (11) |
Geometric parameters (Å, º) top
Pr1—O4 | 2.4225 (17) | C17—H17B | 0.9700 |
Pr1—O2 | 2.4517 (16) | C18—H18A | 0.9700 |
Pr1—O3 | 2.4576 (15) | C18—H18B | 0.9700 |
Pr1—O5 | 2.4629 (15) | C19—C20 | 1.480 (4) |
Pr1—O6 | 2.4891 (17) | C19—H19A | 0.9700 |
Pr1—O1 | 2.4927 (17) | C19—H19B | 0.9700 |
Pr1—O9 | 2.5995 (16) | C20—H20A | 0.9700 |
Pr1—O8 | 2.6072 (15) | C20—H20B | 0.9700 |
Pr1—O7 | 2.6176 (17) | C21—H21A | 0.9600 |
O1—C2 | 1.246 (3) | C21—H21B | 0.9600 |
O2—C4 | 1.243 (2) | C21—H21C | 0.9600 |
O3—C7 | 1.247 (3) | C1—F2B | 1.270 (4) |
O4—C9 | 1.258 (2) | C1—F1A | 1.311 (4) |
O5—C12 | 1.243 (2) | C1—F3A | 1.316 (5) |
O6—C14 | 1.250 (2) | C1—F3B | 1.334 (5) |
O7—C16 | 1.433 (3) | C1—F1B | 1.335 (4) |
O7—C17 | 1.441 (3) | C1—F2A | 1.342 (5) |
O8—C19 | 1.431 (3) | C5—F6 | 1.296 (3) |
O8—C18 | 1.432 (3) | C5—F4 | 1.301 (3) |
O9—C20 | 1.424 (3) | C5—F5 | 1.321 (3) |
O9—C21 | 1.441 (3) | C6—F9B | 1.309 (3) |
C2—C3 | 1.378 (3) | C6—F9A | 1.310 (5) |
C2—C1 | 1.522 (3) | C6—F8B | 1.311 (3) |
C3—C4 | 1.382 (3) | C6—F7A | 1.315 (5) |
C3—H3 | 0.9300 | C6—F8A | 1.316 (4) |
C4—C5 | 1.540 (4) | C6—F7B | 1.325 (3) |
C7—C8 | 1.354 (4) | C10—F12B | 1.247 (4) |
C7—C6 | 1.530 (3) | C10—F11A | 1.282 (4) |
C8—C9 | 1.369 (3) | C10—F10B | 1.305 (4) |
C8—H8 | 0.9300 | C10—F12A | 1.329 (4) |
C9—C10 | 1.518 (3) | C10—F11B | 1.342 (4) |
C12—C13 | 1.385 (3) | C10—F10A | 1.349 (4) |
C12—C11 | 1.548 (3) | C11—F14B | 1.288 (4) |
C13—C14 | 1.385 (3) | C11—F13A | 1.294 (4) |
C13—H13 | 0.9300 | C11—F15B | 1.298 (4) |
C14—C15 | 1.518 (3) | C11—F15A | 1.316 (4) |
C16—H16A | 0.9600 | C11—F14A | 1.322 (4) |
C16—H16B | 0.9600 | C11—F13B | 1.326 (5) |
C16—H16C | 0.9600 | C15—F17 | 1.286 (3) |
C17—C18 | 1.481 (4) | C15—F16 | 1.306 (3) |
C17—H17A | 0.9700 | C15—F18 | 1.309 (3) |
| | | |
O4—Pr1—O2 | 137.32 (5) | O9—C20—H20B | 109.9 |
O4—Pr1—O3 | 71.48 (5) | C19—C20—H20B | 109.9 |
O2—Pr1—O3 | 74.32 (5) | H20A—C20—H20B | 108.3 |
O4—Pr1—O5 | 76.15 (5) | O9—C21—H21A | 109.5 |
O2—Pr1—O5 | 114.08 (5) | O9—C21—H21B | 109.5 |
O3—Pr1—O5 | 69.08 (5) | H21A—C21—H21B | 109.5 |
O4—Pr1—O6 | 85.38 (5) | O9—C21—H21C | 109.5 |
O2—Pr1—O6 | 137.30 (5) | H21A—C21—H21C | 109.5 |
O3—Pr1—O6 | 135.46 (5) | H21B—C21—H21C | 109.5 |
O5—Pr1—O6 | 68.67 (5) | F2B—C1—F1A | 125.5 (3) |
O4—Pr1—O1 | 78.05 (5) | F2B—C1—F3A | 61.3 (3) |
O2—Pr1—O1 | 67.64 (6) | F1A—C1—F3A | 104.8 (3) |
O3—Pr1—O1 | 72.17 (6) | F2B—C1—F3B | 106.3 (4) |
O5—Pr1—O1 | 138.50 (5) | F1A—C1—F3B | 71.2 (3) |
O6—Pr1—O1 | 140.23 (5) | F3A—C1—F3B | 46.0 (3) |
O4—Pr1—O9 | 75.46 (5) | F2B—C1—F1B | 107.3 (3) |
O2—Pr1—O9 | 111.86 (5) | F1A—C1—F1B | 39.5 (3) |
O3—Pr1—O9 | 132.25 (5) | F3A—C1—F1B | 131.0 (3) |
O5—Pr1—O9 | 133.46 (5) | F3B—C1—F1B | 110.2 (3) |
O6—Pr1—O9 | 72.98 (5) | F2B—C1—F2A | 43.2 (3) |
O1—Pr1—O9 | 67.97 (5) | F1A—C1—F2A | 107.2 (3) |
O4—Pr1—O8 | 136.78 (5) | F3A—C1—F2A | 103.2 (3) |
O2—Pr1—O8 | 74.39 (5) | F3B—C1—F2A | 143.1 (3) |
O3—Pr1—O8 | 148.64 (5) | F1B—C1—F2A | 72.3 (3) |
O5—Pr1—O8 | 123.32 (5) | F2B—C1—C2 | 114.7 (3) |
O6—Pr1—O8 | 70.66 (5) | F1A—C1—C2 | 118.0 (3) |
O1—Pr1—O8 | 97.65 (5) | F3A—C1—C2 | 115.7 (2) |
O9—Pr1—O8 | 63.52 (5) | F3B—C1—C2 | 106.1 (3) |
O4—Pr1—O7 | 145.50 (5) | F1B—C1—C2 | 112.0 (3) |
O2—Pr1—O7 | 66.19 (6) | F2A—C1—C2 | 106.5 (2) |
O3—Pr1—O7 | 101.52 (5) | F6—C5—F4 | 107.0 (2) |
O5—Pr1—O7 | 69.98 (5) | F6—C5—F5 | 106.2 (2) |
O6—Pr1—O7 | 76.54 (6) | F4—C5—F5 | 106.8 (2) |
O1—Pr1—O7 | 133.29 (5) | F6—C5—C4 | 110.9 (2) |
O9—Pr1—O7 | 124.82 (5) | F4—C5—C4 | 111.71 (19) |
O8—Pr1—O7 | 63.39 (5) | F5—C5—C4 | 113.9 (2) |
C2—O1—Pr1 | 136.62 (15) | F9B—C6—F9A | 57.9 (4) |
C4—O2—Pr1 | 138.77 (15) | F9B—C6—F8B | 106.0 (2) |
C7—O3—Pr1 | 134.04 (14) | F9A—C6—F8B | 51.2 (3) |
C9—O4—Pr1 | 134.85 (14) | F9B—C6—F7A | 55.4 (4) |
C12—O5—Pr1 | 136.88 (13) | F9A—C6—F7A | 112.0 (5) |
C14—O6—Pr1 | 135.01 (13) | F8B—C6—F7A | 145.3 (4) |
C16—O7—C17 | 111.2 (2) | F9B—C6—F8A | 139.9 (5) |
C16—O7—Pr1 | 118.21 (14) | F9A—C6—F8A | 107.5 (5) |
C17—O7—Pr1 | 115.37 (13) | F8B—C6—F8A | 58.9 (4) |
C19—O8—C18 | 111.89 (17) | F7A—C6—F8A | 114.0 (6) |
C19—O8—Pr1 | 115.94 (14) | F9B—C6—F7B | 106.5 (2) |
C18—O8—Pr1 | 116.57 (13) | F9A—C6—F7B | 134.9 (4) |
C20—O9—C21 | 110.60 (19) | F8B—C6—F7B | 107.7 (2) |
C20—O9—Pr1 | 115.26 (15) | F7A—C6—F7B | 59.9 (4) |
C21—O9—Pr1 | 123.35 (13) | F8A—C6—F7B | 54.6 (4) |
O1—C2—C3 | 127.8 (2) | F9B—C6—C7 | 112.35 (18) |
O1—C2—C1 | 114.2 (2) | F9A—C6—C7 | 111.3 (4) |
C3—C2—C1 | 118.02 (19) | F8B—C6—C7 | 110.1 (2) |
C2—C3—C4 | 121.0 (2) | F7A—C6—C7 | 104.3 (3) |
C2—C3—H3 | 119.5 | F8A—C6—C7 | 107.7 (5) |
C4—C3—H3 | 119.5 | F7B—C6—C7 | 113.7 (2) |
O2—C4—C3 | 127.2 (2) | F12B—C10—F11A | 129.4 (3) |
O2—C4—C5 | 114.06 (19) | F12B—C10—F10B | 112.6 (3) |
C3—C4—C5 | 118.69 (19) | F11A—C10—F10B | 61.3 (3) |
O3—C7—C8 | 126.7 (2) | F12B—C10—F12A | 37.5 (3) |
O3—C7—C6 | 113.3 (2) | F11A—C10—F12A | 105.3 (3) |
C8—C7—C6 | 120.0 (2) | F10B—C10—F12A | 131.7 (3) |
C7—C8—C9 | 126.3 (2) | F12B—C10—F11B | 104.6 (3) |
C7—C8—H8 | 116.9 | F11A—C10—F11B | 43.2 (2) |
C9—C8—H8 | 116.9 | F10B—C10—F11B | 103.0 (3) |
O4—C9—C8 | 126.4 (2) | F12A—C10—F11B | 69.1 (2) |
O4—C9—C10 | 113.93 (18) | F12B—C10—F10A | 66.1 (3) |
C8—C9—C10 | 119.7 (2) | F11A—C10—F10A | 108.5 (3) |
O5—C12—C13 | 128.07 (19) | F10B—C10—F10A | 52.1 (2) |
O5—C12—C11 | 114.85 (17) | F12A—C10—F10A | 100.3 (2) |
C13—C12—C11 | 117.08 (17) | F11B—C10—F10A | 137.0 (3) |
C12—C13—C14 | 121.01 (18) | F12B—C10—C9 | 114.1 (3) |
C12—C13—H13 | 119.5 | F11A—C10—C9 | 113.3 (2) |
C14—C13—H13 | 119.5 | F10B—C10—C9 | 113.3 (3) |
O6—C14—C13 | 128.53 (18) | F12A—C10—C9 | 114.4 (2) |
O6—C14—C15 | 114.52 (18) | F11B—C10—C9 | 108.0 (2) |
C13—C14—C15 | 116.94 (18) | F10A—C10—C9 | 114.0 (2) |
O7—C16—H16A | 109.5 | F14B—C11—F13A | 132.7 (3) |
O7—C16—H16B | 109.5 | F14B—C11—F15B | 108.2 (3) |
H16A—C16—H16B | 109.5 | F13A—C11—F15B | 65.3 (3) |
O7—C16—H16C | 109.5 | F14B—C11—F15A | 69.9 (2) |
H16A—C16—H16C | 109.5 | F13A—C11—F15A | 105.6 (3) |
H16B—C16—H16C | 109.5 | F15B—C11—F15A | 43.1 (2) |
O7—C17—C18 | 108.4 (2) | F14B—C11—F14A | 41.9 (2) |
O7—C17—H17A | 110.0 | F13A—C11—F14A | 105.8 (3) |
C18—C17—H17A | 110.0 | F15B—C11—F14A | 132.7 (3) |
O7—C17—H17B | 110.0 | F15A—C11—F14A | 108.2 (3) |
C18—C17—H17B | 110.0 | F14B—C11—F13B | 110.3 (3) |
H17A—C17—H17B | 108.4 | F13A—C11—F13B | 42.9 (2) |
O8—C18—C17 | 109.04 (18) | F15B—C11—F13B | 106.9 (3) |
O8—C18—H18A | 109.9 | F15A—C11—F13B | 139.5 (3) |
C17—C18—H18A | 109.9 | F14A—C11—F13B | 70.2 (3) |
O8—C18—H18B | 109.9 | F14B—C11—C12 | 112.8 (2) |
C17—C18—H18B | 109.9 | F13A—C11—C12 | 112.7 (2) |
H18A—C18—H18B | 108.3 | F15B—C11—C12 | 111.5 (2) |
O8—C19—C20 | 108.16 (19) | F15A—C11—C12 | 109.7 (2) |
O8—C19—H19A | 110.1 | F14A—C11—C12 | 114.3 (2) |
C20—C19—H19A | 110.1 | F13B—C11—C12 | 107.1 (2) |
O8—C19—H19B | 110.1 | F17—C15—F16 | 107.1 (2) |
C20—C19—H19B | 110.1 | F17—C15—F18 | 104.4 (2) |
H19A—C19—H19B | 108.4 | F16—C15—F18 | 104.5 (2) |
O9—C20—C19 | 109.01 (19) | F17—C15—C14 | 112.7 (2) |
O9—C20—H20A | 109.9 | F16—C15—C14 | 115.1 (2) |
C19—C20—H20A | 109.9 | F18—C15—C14 | 112.3 (2) |
| | | |
O4—Pr1—O1—C2 | 144.0 (2) | O7—Pr1—O9—C21 | −175.63 (16) |
O2—Pr1—O1—C2 | −10.1 (2) | Pr1—O1—C2—C3 | 9.6 (4) |
O3—Pr1—O1—C2 | 69.8 (2) | Pr1—O1—C2—C1 | −170.84 (15) |
O5—Pr1—O1—C2 | 91.5 (2) | O1—C2—C3—C4 | −0.4 (4) |
O6—Pr1—O1—C2 | −148.56 (19) | C1—C2—C3—C4 | −180.0 (2) |
O9—Pr1—O1—C2 | −137.1 (2) | Pr1—O2—C4—C3 | −4.5 (4) |
O8—Pr1—O1—C2 | −79.7 (2) | Pr1—O2—C4—C5 | 174.54 (15) |
O7—Pr1—O1—C2 | −19.3 (2) | C2—C3—C4—O2 | −2.2 (4) |
O4—Pr1—O2—C4 | −31.3 (2) | C2—C3—C4—C5 | 178.7 (2) |
O3—Pr1—O2—C4 | −69.0 (2) | Pr1—O3—C7—C8 | −4.8 (3) |
O5—Pr1—O2—C4 | −126.9 (2) | Pr1—O3—C7—C6 | 176.95 (12) |
O6—Pr1—O2—C4 | 149.04 (19) | O3—C7—C8—C9 | −0.4 (4) |
O1—Pr1—O2—C4 | 7.8 (2) | C6—C7—C8—C9 | 177.7 (2) |
O9—Pr1—O2—C4 | 60.8 (2) | Pr1—O4—C9—C8 | 1.9 (3) |
O8—Pr1—O2—C4 | 113.1 (2) | Pr1—O4—C9—C10 | 179.59 (12) |
O7—Pr1—O2—C4 | −179.5 (2) | C7—C8—C9—O4 | 1.9 (4) |
O4—Pr1—O3—C7 | 5.42 (18) | C7—C8—C9—C10 | −175.6 (2) |
O2—Pr1—O3—C7 | 159.48 (19) | Pr1—O5—C12—C13 | −8.3 (4) |
O5—Pr1—O3—C7 | −76.40 (18) | Pr1—O5—C12—C11 | 170.51 (15) |
O6—Pr1—O3—C7 | −57.1 (2) | O5—C12—C13—C14 | −2.0 (4) |
O1—Pr1—O3—C7 | 88.43 (19) | C11—C12—C13—C14 | 179.2 (2) |
O9—Pr1—O3—C7 | 54.0 (2) | Pr1—O6—C14—C13 | 13.1 (4) |
O8—Pr1—O3—C7 | 163.41 (16) | Pr1—O6—C14—C15 | −168.00 (15) |
O7—Pr1—O3—C7 | −139.54 (18) | C12—C13—C14—O6 | −0.6 (4) |
O2—Pr1—O4—C9 | −42.4 (2) | C12—C13—C14—C15 | −179.5 (2) |
O3—Pr1—O4—C9 | −4.01 (17) | C16—O7—C17—C18 | 175.21 (18) |
O5—Pr1—O4—C9 | 68.22 (17) | Pr1—O7—C17—C18 | −46.60 (19) |
O6—Pr1—O4—C9 | 137.37 (17) | C19—O8—C18—C17 | 179.7 (2) |
O1—Pr1—O4—C9 | −78.99 (17) | Pr1—O8—C18—C17 | −43.6 (2) |
O9—Pr1—O4—C9 | −149.04 (18) | O7—C17—C18—O8 | 58.4 (2) |
O8—Pr1—O4—C9 | −167.46 (16) | C18—O8—C19—C20 | −178.8 (2) |
O7—Pr1—O4—C9 | 79.35 (19) | Pr1—O8—C19—C20 | 44.2 (2) |
O4—Pr1—O5—C12 | 102.6 (2) | C21—O9—C20—C19 | −167.0 (2) |
O2—Pr1—O5—C12 | −121.4 (2) | Pr1—O9—C20—C19 | 47.3 (2) |
O3—Pr1—O5—C12 | 177.8 (2) | O8—C19—C20—O9 | −59.5 (3) |
O6—Pr1—O5—C12 | 12.2 (2) | O1—C2—C1—F2B | 40.0 (4) |
O1—Pr1—O5—C12 | 155.7 (2) | C3—C2—C1—F2B | −140.3 (3) |
O9—Pr1—O5—C12 | 48.8 (2) | O1—C2—C1—F1A | −153.9 (3) |
O8—Pr1—O5—C12 | −34.8 (2) | C3—C2—C1—F1A | 25.7 (4) |
O7—Pr1—O5—C12 | −70.7 (2) | O1—C2—C1—F3A | −28.6 (4) |
O4—Pr1—O6—C14 | −91.2 (2) | C3—C2—C1—F3A | 151.0 (3) |
O2—Pr1—O6—C14 | 88.6 (2) | O1—C2—C1—F3B | −77.0 (3) |
O3—Pr1—O6—C14 | −33.7 (2) | C3—C2—C1—F3B | 102.6 (3) |
O5—Pr1—O6—C14 | −14.29 (19) | O1—C2—C1—F1B | 162.7 (3) |
O1—Pr1—O6—C14 | −156.25 (18) | C3—C2—C1—F1B | −17.6 (4) |
O9—Pr1—O6—C14 | −167.4 (2) | O1—C2—C1—F2A | 85.5 (3) |
O8—Pr1—O6—C14 | 125.4 (2) | C3—C2—C1—F2A | −94.8 (3) |
O7—Pr1—O6—C14 | 59.2 (2) | O2—C4—C5—F6 | −81.6 (2) |
O4—Pr1—O7—C16 | −71.77 (18) | C3—C4—C5—F6 | 97.6 (3) |
O2—Pr1—O7—C16 | 69.17 (16) | O2—C4—C5—F4 | 37.6 (3) |
O3—Pr1—O7—C16 | 2.21 (17) | C3—C4—C5—F4 | −143.2 (2) |
O5—Pr1—O7—C16 | −60.27 (16) | O2—C4—C5—F5 | 158.7 (2) |
O6—Pr1—O7—C16 | −132.15 (17) | C3—C4—C5—F5 | −22.1 (3) |
O1—Pr1—O7—C16 | 78.49 (18) | O3—C7—C6—F9B | −50.4 (3) |
O9—Pr1—O7—C16 | 170.06 (16) | C8—C7—C6—F9B | 131.2 (2) |
O8—Pr1—O7—C16 | 152.98 (17) | O3—C7—C6—F9A | 12.5 (4) |
O4—Pr1—O7—C17 | 153.06 (13) | C8—C7—C6—F9A | −165.9 (4) |
O2—Pr1—O7—C17 | −65.99 (14) | O3—C7—C6—F8B | 67.5 (3) |
O3—Pr1—O7—C17 | −132.95 (14) | C8—C7—C6—F8B | −110.9 (3) |
O5—Pr1—O7—C17 | 164.57 (14) | O3—C7—C6—F7A | −108.4 (4) |
O6—Pr1—O7—C17 | 92.69 (14) | C8—C7—C6—F7A | 73.2 (5) |
O1—Pr1—O7—C17 | −56.68 (15) | O3—C7—C6—F8A | 130.1 (5) |
O9—Pr1—O7—C17 | 34.90 (15) | C8—C7—C6—F8A | −48.3 (5) |
O8—Pr1—O7—C17 | 17.82 (13) | O3—C7—C6—F7B | −171.50 (19) |
O4—Pr1—O8—C19 | 4.94 (16) | C8—C7—C6—F7B | 10.1 (3) |
O2—Pr1—O8—C19 | −139.87 (14) | O4—C9—C10—F12B | 60.3 (4) |
O3—Pr1—O8—C19 | −143.80 (14) | C8—C9—C10—F12B | −121.9 (3) |
O5—Pr1—O8—C19 | 111.27 (14) | O4—C9—C10—F11A | −101.7 (3) |
O6—Pr1—O8—C19 | 65.07 (14) | C8—C9—C10—F11A | 76.2 (3) |
O1—Pr1—O8—C19 | −75.72 (14) | O4—C9—C10—F10B | −169.1 (2) |
O9—Pr1—O8—C19 | −15.04 (13) | C8—C9—C10—F10B | 8.8 (3) |
O7—Pr1—O8—C19 | 149.33 (15) | O4—C9—C10—F12A | 19.0 (3) |
O4—Pr1—O8—C18 | −130.04 (14) | C8—C9—C10—F12A | −163.1 (2) |
O2—Pr1—O8—C18 | 85.14 (15) | O4—C9—C10—F11B | −55.6 (3) |
O3—Pr1—O8—C18 | 81.21 (17) | C8—C9—C10—F11B | 122.2 (2) |
O5—Pr1—O8—C18 | −23.72 (16) | O4—C9—C10—F10A | 133.6 (2) |
O6—Pr1—O8—C18 | −69.92 (15) | C8—C9—C10—F10A | −48.5 (3) |
O1—Pr1—O8—C18 | 149.30 (14) | O5—C12—C11—F14B | 148.4 (3) |
O9—Pr1—O8—C18 | −150.03 (15) | C13—C12—C11—F14B | −32.6 (3) |
O7—Pr1—O8—C18 | 14.34 (14) | O5—C12—C11—F13A | −44.7 (3) |
O4—Pr1—O9—C20 | 176.35 (15) | C13—C12—C11—F13A | 134.2 (3) |
O2—Pr1—O9—C20 | 40.77 (15) | O5—C12—C11—F15B | 26.5 (3) |
O3—Pr1—O9—C20 | 129.11 (14) | C13—C12—C11—F15B | −154.6 (3) |
O5—Pr1—O9—C20 | −129.57 (14) | O5—C12—C11—F15A | 72.7 (3) |
O6—Pr1—O9—C20 | −94.08 (15) | C13—C12—C11—F15A | −108.4 (3) |
O1—Pr1—O9—C20 | 93.58 (15) | O5—C12—C11—F14A | −165.7 (3) |
O8—Pr1—O9—C20 | −17.64 (14) | C13—C12—C11—F14A | 13.3 (4) |
O7—Pr1—O9—C20 | −34.71 (16) | O5—C12—C11—F13B | −90.1 (3) |
O4—Pr1—O9—C21 | 35.43 (17) | C13—C12—C11—F13B | 88.8 (3) |
O2—Pr1—O9—C21 | −100.15 (17) | O6—C14—C15—F17 | −85.3 (3) |
O3—Pr1—O9—C21 | −11.81 (19) | C13—C14—C15—F17 | 93.7 (3) |
O5—Pr1—O9—C21 | 89.51 (18) | O6—C14—C15—F16 | 151.5 (2) |
O6—Pr1—O9—C21 | 124.99 (18) | C13—C14—C15—F16 | −29.4 (3) |
O1—Pr1—O9—C21 | −47.34 (17) | O6—C14—C15—F18 | 32.2 (3) |
O8—Pr1—O9—C21 | −158.57 (18) | C13—C14—C15—F18 | −148.7 (2) |
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