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The eight-membered dioxaphosphocine ring in C28H21O3PS, adopts a distorted boat conformation with the phosphoryl S atom axial and the phenoxy group equatorial. The phenyl ring takes a perpendicular orientation with respect to the two naphthalene ring systems; the dihedral angle between the naphthalene planes is 64.78 (7)°. The structure is stabilized by van der Waals interactions.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks text, de1007a

CCDC reference: 126796

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