metal-organic compounds
The title palladium(II) compound [Pd(PPh3)2{S2C=C(CN)2}].2CH3CN or [Pd(C4N2S2)(C18H15P)2].2C2H3N, was obtained from the reaction of PPh3, PdCl2 and K2S2C=C(CN)2 (i-mnt) in CH3CN. The Pd atom is coordinated by two P and two S atoms in a distorted square-planar arrangement. The average Pd-P and Pd-S distances are 2.3184 (11) and 2.3420 (11) Å, respectively, the the P-Pd-P and S-Pd-S angles are 99.11 (4) and 74.68 (4)°, respectively.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (SHELXL table format) |
CCDC reference: 130554