The title compound, [Zn(C2H3O2)(phen)2]BF4, where phen is 1,10-phenanthroline (C12H8N2), crystallizes in the monoclinic space group P21/n. Zinc is in a general crystallographic position and is coordinated by one acetate and two phenanthroline ligands in an approximate mm2 point-group symmetry. The two Zn-O bond distances are similar to each other, as are the Zn-N bond distances.
Supporting information
CCDC reference: 248750
Key indicators
- Single-crystal X-ray study
- T = 293 K
- Mean (C-C) = 0.006 Å
- R factor = 0.050
- wR factor = 0.116
- Data-to-parameter ratio = 12.6
checkCIF/PLATON results
No syntax errors found
Alert level B
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X) Zn1 - O1 .. 10.14 su
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X) Zn1 - O2 .. 14.55 su
Alert level C
PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ?
PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors for O1
PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors for O2
PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors for C41
PLAT244_ALERT_4_C Low Solvent U(eq) as Compared to Neighbors for B
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 2
B F4
0 ALERT level A = In general: serious problem
2 ALERT level B = Potentially serious problem
6 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
5 ALERT type 2 Indicator that the structure model may be wrong or deficient
0 ALERT type 3 Indicator that the structure quality may be low
3 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: COLLECT (Nonius, 1999); cell refinement: COLLECT; data reduction: COLLECT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).
acetatobis(1,10-phenantroline)zinc(II) tetrafluorborate
top
Crystal data top
[Zn(C2H3O2)(C12H8N2)2]BF4 | Dx = 1.542 Mg m−3 |
Mr = 571.63 | Melting point: not measured K |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
a = 8.2289 (5) Å | Cell parameters from 5441 reflections |
b = 19.2134 (11) Å | θ = 1.0–27.5° |
c = 15.6534 (5) Å | µ = 1.06 mm−1 |
β = 95.803 (3)° | T = 293 K |
V = 2462.2 (2) Å3 | Prism, colorless |
Z = 4 | 0.13 × 0.1 × 0.08 mm |
F(000) = 1160 | |
Data collection top
Nonius KappaCCD diffractometer | 2440 reflections with I > 2σ(I) |
Radiation source: fine focus sealed tube, nonius | Rint = 0.055 |
Horizonally mounted graphite crystal monochromator | θmax = 25°, θmin = 2.7° |
Detector resolution: 9 pixels mm-1 | h = −9→9 |
CCD scans | k = −21→22 |
7832 measured reflections | l = −18→18 |
4329 independent reflections | |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.050 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.116 | H atoms treated by a mixture of independent and constrained refinement |
S = 0.94 | w = 1/[σ2(Fo2) + (0.0543P)2] where P = (Fo2 + 2Fc2)/3 |
4329 reflections | (Δ/σ)max = 0.001 |
343 parameters | Δρmax = 0.4 e Å−3 |
0 restraints | Δρmin = −0.33 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
F1 | 1.1895 (4) | −0.04229 (19) | 0.20489 (18) | 0.1146 (11) | |
B | 1.3417 (9) | −0.0207 (3) | 0.1908 (4) | 0.0735 (17) | |
F4 | 1.4353 (4) | −0.01471 (19) | 0.26683 (17) | 0.1171 (11) | |
F3 | 1.4075 (4) | −0.07134 (19) | 0.1439 (2) | 0.1397 (14) | |
F2 | 1.3377 (5) | 0.03776 (19) | 0.1475 (2) | 0.1514 (15) | |
Zn1 | 0.93732 (6) | 0.16594 (2) | 0.32563 (2) | 0.04793 (19) | |
N3 | 0.8902 (4) | 0.09970 (18) | 0.21536 (18) | 0.0513 (9) | |
N2 | 1.0042 (4) | 0.23372 (17) | 0.43280 (17) | 0.0451 (8) | |
C41 | 0.6354 (5) | 0.1656 (2) | 0.3495 (2) | 0.0505 (10) | |
N1 | 1.0924 (4) | 0.10123 (17) | 0.40428 (17) | 0.0446 (8) | |
C9 | 1.0854 (4) | 0.1983 (2) | 0.4989 (2) | 0.0416 (9) | |
N4 | 1.0561 (4) | 0.21999 (17) | 0.23161 (17) | 0.0467 (8) | |
C5 | 1.1347 (4) | 0.1291 (2) | 0.4835 (2) | 0.0395 (9) | |
O2 | 0.6974 (4) | 0.21101 (16) | 0.30573 (16) | 0.0684 (9) | |
C11 | 0.9880 (5) | 0.3316 (2) | 0.5255 (3) | 0.0572 (11) | |
H11 | 0.9545 | 0.3773 | 0.5326 | 0.069* | |
C3 | 1.2739 (6) | 0.0247 (2) | 0.5303 (3) | 0.0660 (13) | |
H3 | 1.3346 | −0.0016 | 0.572 | 0.079* | |
C29 | 1.0321 (5) | 0.1904 (2) | 0.1519 (2) | 0.0446 (10) | |
O1 | 0.7223 (4) | 0.12268 (16) | 0.39153 (18) | 0.0709 (9) | |
C25 | 0.9451 (5) | 0.1270 (2) | 0.1439 (2) | 0.0458 (10) | |
C27 | 1.0530 (6) | 0.1886 (3) | −0.0018 (2) | 0.0650 (13) | |
H27 | 1.0899 | 0.2088 | −0.0503 | 0.078* | |
C30 | 1.1729 (5) | 0.2853 (2) | 0.0912 (3) | 0.0625 (12) | |
H30 | 1.2116 | 0.3076 | 0.0446 | 0.075* | |
C32 | 1.1371 (5) | 0.2793 (2) | 0.2393 (2) | 0.0547 (11) | |
H32 | 1.1544 | 0.2994 | 0.2935 | 0.066* | |
C12 | 0.9587 (5) | 0.2983 (2) | 0.4462 (2) | 0.0534 (11) | |
H12 | 0.9044 | 0.3228 | 0.4007 | 0.064* | |
C7 | 1.2076 (5) | 0.1870 (3) | 0.6465 (2) | 0.0612 (12) | |
H7 | 1.2287 | 0.2056 | 0.7013 | 0.073* | |
C10 | 1.0670 (5) | 0.2956 (2) | 0.5923 (3) | 0.0604 (12) | |
H10 | 1.0862 | 0.3166 | 0.6459 | 0.072* | |
C8 | 1.1189 (5) | 0.2281 (2) | 0.5810 (2) | 0.0480 (10) | |
C28 | 1.0881 (5) | 0.2222 (2) | 0.0798 (2) | 0.0524 (11) | |
C24 | 0.9117 (5) | 0.0955 (2) | 0.0627 (2) | 0.0535 (11) | |
C2 | 1.2333 (6) | −0.0026 (2) | 0.4506 (3) | 0.0756 (14) | |
H2 | 1.2667 | −0.0473 | 0.4374 | 0.091* | |
C4 | 1.2253 (5) | 0.0913 (2) | 0.5494 (2) | 0.0506 (11) | |
C21 | 0.8047 (6) | 0.0416 (2) | 0.2082 (3) | 0.0656 (13) | |
H21 | 0.7686 | 0.0224 | 0.2574 | 0.079* | |
C1 | 1.1408 (5) | 0.0375 (2) | 0.3888 (3) | 0.0593 (12) | |
H1 | 1.1124 | 0.0185 | 0.3347 | 0.071* | |
C6 | 1.2608 (5) | 0.1231 (3) | 0.6316 (2) | 0.0629 (13) | |
H6 | 1.3218 | 0.099 | 0.6753 | 0.075* | |
C26 | 0.9689 (6) | 0.1292 (3) | −0.0100 (2) | 0.0640 (13) | |
H26 | 0.947 | 0.1094 | −0.0642 | 0.077* | |
C23 | 0.8205 (6) | 0.0347 (3) | 0.0575 (3) | 0.0654 (13) | |
H23 | 0.7967 | 0.0125 | 0.005 | 0.079* | |
C31 | 1.1983 (5) | 0.3138 (2) | 0.1710 (3) | 0.0655 (13) | |
H31 | 1.2553 | 0.3554 | 0.1798 | 0.079* | |
C22 | 0.7659 (6) | 0.0077 (3) | 0.1301 (3) | 0.0740 (14) | |
H22 | 0.7037 | −0.0328 | 0.1274 | 0.089* | |
C42 | 0.4546 (5) | 0.1629 (3) | 0.3500 (3) | 0.0894 (17) | |
H42A | 0.4257 | 0.1237 | 0.3835 | 0.134* | |
H42B | 0.4044 | 0.1581 | 0.2922 | 0.134* | |
H42C | 0.4171 | 0.205 | 0.3746 | 0.134* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
F1 | 0.083 (2) | 0.151 (3) | 0.111 (2) | −0.016 (2) | 0.0131 (17) | −0.028 (2) |
B | 0.087 (5) | 0.073 (5) | 0.062 (4) | 0.001 (4) | 0.011 (3) | −0.005 (3) |
F4 | 0.103 (2) | 0.158 (3) | 0.0840 (19) | −0.006 (2) | −0.0215 (17) | 0.0035 (19) |
F3 | 0.146 (3) | 0.118 (3) | 0.166 (3) | −0.004 (3) | 0.069 (2) | −0.056 (3) |
F2 | 0.196 (4) | 0.103 (3) | 0.149 (3) | −0.004 (3) | −0.014 (3) | 0.059 (2) |
Zn1 | 0.0525 (3) | 0.0521 (3) | 0.0390 (3) | −0.0006 (3) | 0.00350 (19) | 0.0001 (2) |
N3 | 0.058 (2) | 0.050 (2) | 0.0460 (19) | −0.003 (2) | 0.0079 (16) | 0.0005 (16) |
N2 | 0.051 (2) | 0.042 (2) | 0.0428 (18) | 0.0001 (17) | 0.0057 (15) | 0.0027 (16) |
C41 | 0.050 (3) | 0.054 (3) | 0.047 (2) | −0.001 (3) | 0.006 (2) | −0.006 (2) |
N1 | 0.049 (2) | 0.042 (2) | 0.0428 (18) | 0.0008 (17) | 0.0072 (14) | −0.0051 (15) |
C9 | 0.039 (2) | 0.044 (3) | 0.043 (2) | −0.004 (2) | 0.0089 (17) | −0.0021 (19) |
N4 | 0.046 (2) | 0.049 (2) | 0.0445 (18) | −0.0031 (18) | 0.0053 (14) | 0.0020 (16) |
C5 | 0.036 (2) | 0.043 (3) | 0.040 (2) | −0.005 (2) | 0.0046 (17) | 0.0016 (19) |
O2 | 0.074 (2) | 0.075 (2) | 0.0556 (16) | −0.0100 (19) | 0.0034 (14) | 0.0174 (16) |
C11 | 0.061 (3) | 0.038 (3) | 0.072 (3) | 0.003 (2) | 0.007 (2) | −0.014 (2) |
C3 | 0.080 (3) | 0.054 (3) | 0.062 (3) | 0.009 (3) | −0.002 (2) | 0.017 (2) |
C29 | 0.045 (3) | 0.048 (3) | 0.041 (2) | 0.003 (2) | 0.0063 (17) | 0.0018 (19) |
O1 | 0.073 (2) | 0.059 (2) | 0.080 (2) | 0.0009 (18) | 0.0030 (16) | 0.0192 (17) |
C25 | 0.046 (3) | 0.051 (3) | 0.041 (2) | 0.005 (2) | 0.0050 (18) | −0.003 (2) |
C27 | 0.078 (4) | 0.076 (4) | 0.043 (2) | 0.008 (3) | 0.018 (2) | 0.004 (2) |
C30 | 0.070 (3) | 0.063 (3) | 0.057 (3) | 0.004 (3) | 0.020 (2) | 0.010 (2) |
C32 | 0.059 (3) | 0.051 (3) | 0.054 (2) | 0.000 (2) | 0.006 (2) | −0.005 (2) |
C12 | 0.061 (3) | 0.043 (3) | 0.055 (3) | 0.000 (2) | 0.0008 (19) | −0.001 (2) |
C7 | 0.071 (3) | 0.068 (4) | 0.042 (2) | −0.006 (3) | −0.007 (2) | −0.002 (2) |
C10 | 0.063 (3) | 0.062 (3) | 0.055 (3) | −0.012 (3) | 0.002 (2) | −0.012 (2) |
C8 | 0.050 (3) | 0.047 (3) | 0.046 (2) | −0.004 (2) | 0.0007 (18) | −0.005 (2) |
C28 | 0.054 (3) | 0.056 (3) | 0.049 (2) | 0.002 (2) | 0.0139 (19) | 0.002 (2) |
C24 | 0.056 (3) | 0.057 (3) | 0.047 (2) | 0.002 (2) | 0.0032 (19) | −0.010 (2) |
C2 | 0.101 (4) | 0.046 (3) | 0.080 (3) | 0.020 (3) | 0.012 (3) | −0.002 (3) |
C4 | 0.055 (3) | 0.045 (3) | 0.051 (3) | 0.001 (2) | 0.003 (2) | 0.006 (2) |
C21 | 0.081 (4) | 0.057 (3) | 0.060 (3) | −0.018 (3) | 0.013 (2) | 0.000 (2) |
C1 | 0.072 (3) | 0.046 (3) | 0.060 (3) | 0.004 (3) | 0.011 (2) | −0.007 (2) |
C6 | 0.067 (3) | 0.072 (4) | 0.047 (3) | −0.003 (3) | −0.009 (2) | 0.010 (2) |
C26 | 0.075 (3) | 0.080 (4) | 0.038 (2) | 0.008 (3) | 0.010 (2) | −0.008 (2) |
C23 | 0.072 (3) | 0.073 (4) | 0.051 (3) | 0.002 (3) | 0.002 (2) | −0.022 (2) |
C31 | 0.077 (4) | 0.054 (3) | 0.067 (3) | −0.015 (3) | 0.014 (2) | 0.006 (2) |
C22 | 0.087 (4) | 0.063 (3) | 0.072 (3) | −0.017 (3) | 0.009 (3) | −0.018 (3) |
C42 | 0.048 (3) | 0.108 (5) | 0.113 (4) | 0.005 (3) | 0.015 (3) | −0.003 (3) |
Geometric parameters (Å, º) top
F1—B | 1.359 (6) | C27—C26 | 1.334 (6) |
B—F2 | 1.311 (6) | C27—C28 | 1.434 (5) |
B—F4 | 1.356 (6) | C30—C31 | 1.360 (5) |
B—F3 | 1.363 (6) | C30—C28 | 1.401 (5) |
Zn1—O1 | 2.293 (3) | C32—C31 | 1.393 (5) |
Zn1—O2 | 2.149 (3) | C7—C6 | 1.331 (6) |
Zn1—N1 | 2.091 (3) | C7—C8 | 1.433 (5) |
Zn1—N2 | 2.151 (3) | C10—C8 | 1.383 (6) |
Zn1—N3 | 2.148 (3) | C24—C23 | 1.386 (6) |
Zn1—N4 | 2.119 (3) | C24—C26 | 1.430 (5) |
Zn1—C41 | 2.550 (4) | C2—C1 | 1.401 (6) |
N3—C21 | 1.319 (5) | C4—C6 | 1.428 (5) |
N3—C25 | 1.354 (4) | C21—C22 | 1.394 (5) |
N2—C12 | 1.319 (5) | C23—C22 | 1.365 (5) |
N2—C9 | 1.356 (4) | C3—H3 | 0.9300 |
C41—O1 | 1.237 (5) | C27—H27 | 0.9300 |
C41—O2 | 1.250 (5) | C30—H30 | 0.9300 |
C41—C42 | 1.489 (6) | C32—H32 | 0.9300 |
N1—C1 | 1.317 (5) | C12—H12 | 0.9300 |
N1—C5 | 1.364 (4) | C7—H7 | 0.9300 |
C9—C8 | 1.408 (5) | C10—H10 | 0.9300 |
C9—C5 | 1.419 (5) | C2—H2 | 0.9300 |
N4—C32 | 1.320 (5) | C21—H21 | 0.9300 |
N4—C29 | 1.367 (4) | C1—H1 | 0.9300 |
C5—C4 | 1.411 (5) | C6—H6 | 0.9300 |
C11—C10 | 1.363 (5) | C26—H26 | 0.9300 |
C11—C12 | 1.396 (5) | C23—H23 | 0.9300 |
C3—C2 | 1.364 (5) | C31—H31 | 0.9300 |
C3—C4 | 1.383 (5) | C22—H22 | 0.9300 |
C29—C28 | 1.402 (5) | C42—H42A | 0.9600 |
C29—C25 | 1.411 (5) | C42—H42B | 0.9600 |
C25—C24 | 1.410 (5) | C42—H42C | 0.9600 |
| | | |
F2—B—F4 | 111.3 (5) | N4—C32—C31 | 124.0 (4) |
F2—B—F1 | 111.7 (6) | N2—C12—C11 | 123.2 (4) |
F4—B—F1 | 109.5 (4) | C6—C7—C8 | 122.4 (4) |
F2—B—F3 | 108.9 (5) | C11—C10—C8 | 120.5 (4) |
F4—B—F3 | 108.2 (5) | C10—C8—C9 | 117.6 (4) |
F1—B—F3 | 107.0 (5) | C10—C8—C7 | 124.5 (4) |
N1—Zn1—O1 | 88.41 (11) | C9—C8—C7 | 117.9 (4) |
N1—Zn1—O2 | 145.25 (11) | C30—C28—C29 | 118.3 (4) |
N1—Zn1—N2 | 78.94 (12) | C30—C28—C27 | 123.8 (4) |
N1—Zn1—N3 | 99.82 (12) | C29—C28—C27 | 117.9 (4) |
N1—Zn1—N4 | 113.81 (12) | C23—C24—C25 | 118.0 (4) |
N2—Zn1—O1 | 90.95 (11) | C23—C24—C26 | 123.7 (4) |
N2—Zn1—O2 | 91.59 (11) | C25—C24—C26 | 118.2 (4) |
N2—Zn1—N3 | 175.29 (12) | C3—C2—C1 | 119.0 (4) |
N2—Zn1—N4 | 98.37 (12) | C3—C4—C5 | 117.4 (4) |
N3—Zn1—O1 | 93.56 (11) | C3—C4—C6 | 123.7 (4) |
N3—Zn1—O2 | 91.95 (11) | C5—C4—C6 | 118.9 (4) |
N3—Zn1—N4 | 77.92 (12) | N3—C21—C22 | 122.9 (4) |
N4—Zn1—O1 | 157.13 (11) | N1—C1—C2 | 122.6 (4) |
N4—Zn1—O2 | 100.56 (11) | C7—C6—C4 | 120.8 (4) |
O1—Zn1—O2 | 58.12 (11) | C27—C26—C24 | 121.3 (4) |
N1—Zn1—C41 | 117.24 (13) | C22—C23—C24 | 119.6 (4) |
N4—Zn1—C41 | 128.88 (13) | C30—C31—C32 | 118.6 (4) |
N3—Zn1—C41 | 90.98 (12) | C23—C22—C21 | 119.1 (4) |
O2—Zn1—C41 | 29.29 (11) | C10—C11—H11 | 120.8 |
N2—Zn1—C41 | 93.63 (12) | C12—C11—H11 | 120.8 |
O1—Zn1—C41 | 28.97 (11) | C2—C3—H3 | 119.8 |
C21—N3—C25 | 118.5 (3) | C4—C3—H3 | 119.8 |
C21—N3—Zn1 | 128.4 (3) | C26—C27—H27 | 119.1 |
C25—N3—Zn1 | 112.7 (3) | C28—C27—H27 | 119.1 |
C12—N2—C9 | 118.4 (3) | C31—C30—H30 | 120.2 |
C12—N2—Zn1 | 129.8 (3) | C28—C30—H30 | 120.2 |
C9—N2—Zn1 | 111.0 (3) | N4—C32—H32 | 118.0 |
O1—C41—O2 | 120.7 (4) | C31—C32—H32 | 118.0 |
O1—C41—C42 | 119.9 (4) | N2—C12—H12 | 118.4 |
O2—C41—C42 | 119.4 (4) | C11—C12—H12 | 118.4 |
O1—C41—Zn1 | 63.9 (2) | C6—C7—H7 | 118.8 |
O2—C41—Zn1 | 57.3 (2) | C8—C7—H7 | 118.8 |
C42—C41—Zn1 | 171.7 (3) | C11—C10—H10 | 119.8 |
C1—N1—C5 | 118.6 (3) | C8—C10—H10 | 119.8 |
C1—N1—Zn1 | 128.5 (3) | C3—C2—H2 | 120.5 |
C5—N1—Zn1 | 112.8 (3) | C1—C2—H2 | 120.5 |
N2—C9—C8 | 121.9 (4) | N3—C21—H21 | 118.5 |
N2—C9—C5 | 117.9 (3) | C22—C21—H21 | 118.5 |
C8—C9—C5 | 120.1 (3) | N1—C1—H1 | 118.7 |
C32—N4—C29 | 117.8 (3) | C2—C1—H1 | 118.7 |
C32—N4—Zn1 | 128.6 (3) | C7—C6—H6 | 119.6 |
C29—N4—Zn1 | 113.3 (3) | C4—C6—H6 | 119.6 |
N1—C5—C4 | 122.0 (4) | C27—C26—H26 | 119.3 |
N1—C5—C9 | 118.1 (3) | C24—C26—H26 | 119.3 |
C4—C5—C9 | 119.9 (3) | C22—C23—H23 | 120.2 |
C41—O2—Zn1 | 93.4 (3) | C24—C23—H23 | 120.2 |
C10—C11—C12 | 118.4 (4) | C30—C31—H31 | 120.7 |
C2—C3—C4 | 120.3 (4) | C32—C31—H31 | 120.7 |
N4—C29—C28 | 121.6 (4) | C23—C22—H22 | 120.5 |
N4—C29—C25 | 117.7 (3) | C21—C22—H22 | 120.5 |
C28—C29—C25 | 120.6 (3) | C41—C42—H42A | 109.5 |
C41—O1—Zn1 | 87.1 (2) | C41—C42—H42B | 109.5 |
N3—C25—C24 | 121.8 (4) | H42A—C42—H42B | 109.5 |
N3—C25—C29 | 118.0 (3) | C41—C42—H42C | 109.5 |
C24—C25—C29 | 120.1 (3) | H42A—C42—H42C | 109.5 |
C26—C27—C28 | 121.8 (4) | H42B—C42—H42C | 109.5 |
C31—C30—C28 | 119.6 (4) | | |
Comparative bond lengths (Å) for [Zn(ac)(phen)2]Y complexes top | Zn—N1 | Zn—N2 | Zn—N3 | Zn—N4 | Zn—O1 | Zn—O2 |
[[Zn(ac)(phen)2]BF4a | 2.091 (3) | 2.151 (3) | 2.148 (3) | 2.119 (3) | 2.293 (3) | 2.149 (3) |
[Zn(ac)(phen)2]BF4.2H2Ob | 2.116 (2) | 2.147 (2) | 2.147 (2) | 2.116 (2) | 2.184 (2) | 2.184 (2) |
[Zn(ac)(phen)2]ClO4c | 2.135 (6) | 2.143 (6) | 2.160 (5) | 2.100 (5) | 2.296 (5) | 2.156 (5) |
Notes: (a) this work; (b) Fitzgerald et al. (1985); (c) Chen et al. (1994). |
Comparative bond angles (°) for [Zn(ac)(phen)2]Y complexes top | N1—Zn—N2 | N3—Zn—N4 | O1—Zn—O2 |
[Zn(ac)(phen)2]BF4a | 78.94 (12) | 77.92 (12) | 58.12 (11) |
[Zn(ac)(phen)2]BF4.2H2Ob | 78.47 | 78.47 | 57.2 |
[Zn(ac)(phen)2]ClO4c | 78.1 (2) | 78.6 (2) | 57.8 (2) |
Notes: (a) this work; (b) Fitzgerald et al. (1985); (c) Chen et al. (1994). |