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metal-organic compounds
The title compound, [Zn2(C21H14N2O3)2(C5H5N)2]·C5H5N, is dimeric via Zn—O bridging, with an average value for the Zn—O bonds of 2.027 (2) Å. The ZnZn separation is 3.1546 (5) Å. The molecule has a center of inversion and the coordination geometry of both Zn atoms is square pyramidal.
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804018100/cv6338sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536804018100/cv6338Isup2.hkl |
CCDC reference: 248759
Key indicators
- Single-crystal X-ray study
- T = 293 K
- Mean (C-C) = 0.004 Å
- R factor = 0.032
- wR factor = 0.087
- Data-to-parameter ratio = 13.0
checkCIF/PLATON results
No syntax errors found
Alert level C PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ? PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.65 Ratio PLAT243_ALERT_4_C High Solvent U(eq) as Compared to Neighbors for N4 PLAT244_ALERT_4_C Low Solvent U(eq) as Compared to Neighbors for C26
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 5 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 1 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 3 ALERT type 4 Improvement, methodology, query or suggestion
Computing details top
Data collection: SMART (Siemens, 1996); cell refinement: SAINT (Siemens, 1996); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 1997); software used to prepare material for publication: SHELXTL, PARST (Nardelli, 1995) and PLATON (Spek, 2003).
Bis{µ-N'-[1-(2-oxidophenyl)ethylidene]-3-
methoxybenzohydrazidato}bis[pyridinezinc(II)] pyridine solvate top
Crystal data top
[Zn2(C21H14N2O3)2(C5H5N)2]·C5H5N | Z = 1 |
Mr = 1011.76 | F(000) = 524 |
Triclinic, P1 | Dx = 1.437 Mg m−3 |
a = 8.5896 (8) Å | Mo Kα radiation, λ = 0.71073 Å |
b = 10.6112 (10) Å | Cell parameters from 5617 reflections |
c = 14.2017 (13) Å | θ = 1.5–25.0° |
α = 71.360 (2)° | µ = 1.09 mm−1 |
β = 73.261 (1)° | T = 293 K |
γ = 79.670 (2)° | Block, pale yellow |
V = 1169.11 (19) Å3 | 0.46 × 0.37 × 0.20 mm |
Data collection top
Bruker SMART APEX area-detector diffractometer | 4005 independent reflections |
Radiation source: fine-focus sealed tube | 3771 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.016 |
Detector resolution: 83.66 pixels mm-1 | θmax = 25.0°, θmin = 1.5° |
ω scans | h = −10→10 |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | k = −9→12 |
Tmin = 0.635, Tmax = 0.812 | l = −16→16 |
7209 measured reflections |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.032 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.087 | H-atom parameters constrained |
S = 1.04 | w = 1/[σ2(Fo2) + (0.0495P)2 + 0.6076P] where P = (Fo2 + 2Fc2)/3 |
4005 reflections | (Δ/σ)max < 0.001 |
307 parameters | Δρmax = 0.36 e Å−3 |
0 restraints | Δρmin = −0.36 e Å−3 |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
x | y | z | Uiso*/Ueq | ||
Zn1 | 0.95855 (3) | 0.85027 (2) | 0.048601 (17) | 0.03121 (10) | |
O1 | 0.9978 (2) | 0.69718 (16) | 0.16963 (12) | 0.0425 (4) | |
O2 | 1.4357 (3) | 0.1951 (2) | 0.25276 (16) | 0.0713 (6) | |
O3 | 0.96360 (19) | 1.01310 (15) | 0.09080 (11) | 0.0354 (3) | |
N1 | 1.1554 (2) | 0.59591 (19) | 0.04708 (14) | 0.0396 (4) | |
N2 | 1.1000 (2) | 0.71092 (18) | −0.02085 (14) | 0.0354 (4) | |
N3 | 0.7146 (2) | 0.84692 (19) | 0.06404 (15) | 0.0389 (4) | |
N4 | 0.4623 (6) | 0.5889 (4) | 0.3501 (3) | 0.1126 (12) | |
C1 | 1.0658 (3) | 0.4811 (3) | 0.32637 (19) | 0.0472 (6) | |
H1B | 0.9825 | 0.5460 | 0.3420 | 0.057* | |
C2 | 1.1120 (4) | 0.3775 (3) | 0.4037 (2) | 0.0545 (7) | |
H2A | 1.0592 | 0.3735 | 0.4715 | 0.065* | |
C3 | 1.2342 (3) | 0.2801 (3) | 0.3830 (2) | 0.0524 (6) | |
H3A | 1.2643 | 0.2110 | 0.4362 | 0.063* | |
C4 | 1.3118 (3) | 0.2863 (3) | 0.2821 (2) | 0.0482 (6) | |
C5 | 1.2672 (3) | 0.3898 (2) | 0.20338 (19) | 0.0443 (5) | |
H5A | 1.3202 | 0.3934 | 0.1356 | 0.053* | |
C6 | 1.1445 (3) | 0.4881 (2) | 0.22467 (17) | 0.0368 (5) | |
C7 | 1.4839 (5) | 0.0873 (4) | 0.3319 (3) | 0.0861 (12) | |
H7A | 1.5713 | 0.0307 | 0.3020 | 0.129* | |
H7B | 1.3927 | 0.0366 | 0.3711 | 0.129* | |
H7C | 1.5202 | 0.1217 | 0.3759 | 0.129* | |
C8 | 1.0948 (3) | 0.6021 (2) | 0.14183 (17) | 0.0345 (5) | |
C9 | 1.1412 (3) | 0.7157 (2) | −0.11667 (17) | 0.0386 (5) | |
C10 | 1.2440 (4) | 0.6015 (3) | −0.1520 (2) | 0.0579 (7) | |
H10A | 1.2624 | 0.6218 | −0.2250 | 0.087* | |
H10B | 1.1884 | 0.5220 | −0.1192 | 0.087* | |
H10C | 1.3468 | 0.5877 | −0.1344 | 0.087* | |
C11 | 0.9568 (3) | 1.0369 (2) | 0.17917 (15) | 0.0325 (4) | |
C12 | 0.9122 (3) | 1.1662 (2) | 0.19299 (16) | 0.0372 (5) | |
C13 | 0.9165 (4) | 1.1811 (3) | 0.28695 (19) | 0.0553 (7) | |
H13A | 0.8903 | 1.2656 | 0.2969 | 0.066* | |
C14 | 0.9575 (4) | 1.0766 (3) | 0.3643 (2) | 0.0644 (8) | |
H14A | 0.9605 | 1.0906 | 0.4251 | 0.077* | |
C15 | 0.9944 (4) | 0.9506 (3) | 0.35181 (19) | 0.0538 (7) | |
H15A | 1.0198 | 0.8787 | 0.4048 | 0.065* | |
C16 | 0.9939 (3) | 0.9310 (2) | 0.26048 (17) | 0.0411 (5) | |
H16A | 1.0188 | 0.8453 | 0.2528 | 0.049* | |
C17 | 0.6616 (3) | 0.7589 (3) | 0.0342 (2) | 0.0503 (6) | |
H17A | 0.7379 | 0.7048 | −0.0008 | 0.060* | |
C18 | 0.4990 (4) | 0.7450 (3) | 0.0531 (3) | 0.0659 (8) | |
H18A | 0.4656 | 0.6830 | 0.0310 | 0.079* | |
C19 | 0.3864 (3) | 0.8238 (4) | 0.1052 (3) | 0.0683 (9) | |
H19A | 0.2754 | 0.8158 | 0.1191 | 0.082* | |
C20 | 0.4383 (3) | 0.9140 (3) | 0.1364 (2) | 0.0607 (7) | |
H20A | 0.3637 | 0.9682 | 0.1721 | 0.073* | |
C21 | 0.6037 (3) | 0.9236 (3) | 0.1142 (2) | 0.0492 (6) | |
H21A | 0.6393 | 0.9858 | 0.1349 | 0.059* | |
C22 | 0.3426 (5) | 0.6271 (5) | 0.4249 (4) | 0.0988 (13) | |
H22A | 0.2401 | 0.5963 | 0.4436 | 0.119* | |
C23 | 0.3710 (7) | 0.7081 (5) | 0.4713 (3) | 0.1066 (16) | |
H23A | 0.2874 | 0.7323 | 0.5227 | 0.128* | |
C24 | 0.5152 (6) | 0.7560 (4) | 0.4469 (3) | 0.0836 (11) | |
H24A | 0.5331 | 0.8141 | 0.4790 | 0.100* | |
C25 | 0.6296 (5) | 0.7178 (4) | 0.3760 (4) | 0.0887 (12) | |
H25A | 0.7316 | 0.7491 | 0.3584 | 0.106* | |
C26 | 0.6083 (5) | 0.6359 (4) | 0.3273 (3) | 0.0782 (10) | |
H26A | 0.6945 | 0.6112 | 0.2775 | 0.094* |
Atomic displacement parameters (Å2) top
U11 | U22 | U33 | U12 | U13 | U23 | |
Zn1 | 0.03251 (15) | 0.02758 (16) | 0.03318 (15) | −0.00126 (10) | −0.00870 (10) | −0.00852 (10) |
O1 | 0.0549 (10) | 0.0312 (9) | 0.0359 (8) | 0.0061 (7) | −0.0105 (7) | −0.0082 (7) |
O2 | 0.0849 (15) | 0.0499 (12) | 0.0604 (12) | 0.0287 (11) | −0.0182 (11) | −0.0090 (10) |
O3 | 0.0507 (9) | 0.0283 (8) | 0.0289 (7) | −0.0045 (7) | −0.0105 (6) | −0.0096 (6) |
N1 | 0.0470 (11) | 0.0303 (10) | 0.0380 (10) | 0.0049 (8) | −0.0128 (8) | −0.0077 (8) |
N2 | 0.0405 (10) | 0.0292 (10) | 0.0351 (9) | 0.0012 (8) | −0.0115 (8) | −0.0080 (8) |
N3 | 0.0352 (9) | 0.0350 (10) | 0.0454 (11) | −0.0017 (8) | −0.0118 (8) | −0.0090 (8) |
N4 | 0.122 (3) | 0.107 (3) | 0.116 (3) | −0.008 (2) | −0.032 (3) | −0.040 (2) |
C1 | 0.0521 (14) | 0.0419 (14) | 0.0429 (13) | 0.0051 (11) | −0.0118 (11) | −0.0110 (11) |
C2 | 0.0653 (17) | 0.0520 (16) | 0.0375 (13) | 0.0018 (13) | −0.0109 (12) | −0.0063 (12) |
C3 | 0.0633 (16) | 0.0413 (14) | 0.0458 (14) | 0.0028 (12) | −0.0204 (12) | −0.0012 (11) |
C4 | 0.0525 (14) | 0.0359 (13) | 0.0517 (14) | 0.0047 (11) | −0.0158 (12) | −0.0087 (11) |
C5 | 0.0525 (14) | 0.0368 (13) | 0.0405 (12) | 0.0017 (11) | −0.0124 (11) | −0.0092 (10) |
C6 | 0.0424 (12) | 0.0304 (12) | 0.0382 (11) | −0.0044 (9) | −0.0132 (9) | −0.0071 (9) |
C7 | 0.099 (3) | 0.058 (2) | 0.077 (2) | 0.0375 (19) | −0.027 (2) | −0.0064 (17) |
C8 | 0.0366 (11) | 0.0276 (11) | 0.0400 (12) | −0.0044 (9) | −0.0120 (9) | −0.0076 (9) |
C9 | 0.0461 (12) | 0.0326 (12) | 0.0382 (12) | −0.0022 (10) | −0.0092 (10) | −0.0133 (9) |
C10 | 0.081 (2) | 0.0388 (15) | 0.0481 (15) | 0.0118 (13) | −0.0114 (14) | −0.0190 (12) |
C11 | 0.0342 (10) | 0.0360 (12) | 0.0282 (10) | −0.0071 (9) | −0.0064 (8) | −0.0094 (9) |
C12 | 0.0464 (12) | 0.0340 (12) | 0.0321 (11) | −0.0043 (9) | −0.0089 (9) | −0.0109 (9) |
C13 | 0.091 (2) | 0.0407 (15) | 0.0399 (13) | −0.0050 (14) | −0.0200 (13) | −0.0173 (11) |
C14 | 0.112 (3) | 0.0545 (18) | 0.0371 (13) | −0.0075 (17) | −0.0301 (15) | −0.0165 (12) |
C15 | 0.0789 (19) | 0.0473 (16) | 0.0351 (12) | −0.0033 (13) | −0.0219 (12) | −0.0060 (11) |
C16 | 0.0520 (13) | 0.0348 (12) | 0.0355 (11) | −0.0014 (10) | −0.0121 (10) | −0.0092 (10) |
C17 | 0.0444 (13) | 0.0434 (15) | 0.0675 (17) | −0.0030 (11) | −0.0167 (12) | −0.0197 (13) |
C18 | 0.0515 (16) | 0.0614 (19) | 0.097 (2) | −0.0117 (14) | −0.0265 (16) | −0.0288 (17) |
C19 | 0.0367 (14) | 0.077 (2) | 0.090 (2) | −0.0102 (14) | −0.0172 (14) | −0.0181 (18) |
C20 | 0.0389 (13) | 0.0671 (19) | 0.0707 (19) | 0.0047 (13) | −0.0082 (13) | −0.0224 (15) |
C21 | 0.0415 (13) | 0.0505 (16) | 0.0565 (15) | −0.0011 (11) | −0.0114 (11) | −0.0192 (12) |
C22 | 0.067 (2) | 0.107 (3) | 0.116 (3) | −0.019 (2) | 0.003 (2) | −0.041 (3) |
C23 | 0.120 (4) | 0.103 (4) | 0.071 (2) | 0.039 (3) | −0.004 (2) | −0.035 (2) |
C24 | 0.122 (3) | 0.055 (2) | 0.096 (3) | 0.013 (2) | −0.060 (3) | −0.032 (2) |
C25 | 0.074 (2) | 0.065 (2) | 0.121 (3) | −0.0137 (19) | −0.044 (2) | 0.003 (2) |
C26 | 0.071 (2) | 0.078 (3) | 0.073 (2) | −0.0039 (18) | −0.0039 (17) | −0.0187 (19) |
Geometric parameters (Å, º) top
Zn1—O3 | 2.0125 (14) | C9—C10 | 1.499 (3) |
Zn1—O1 | 2.0147 (16) | C10—H10A | 0.9600 |
Zn1—N3 | 2.0488 (19) | C10—H10B | 0.9600 |
Zn1—O3i | 2.0540 (15) | C10—H10C | 0.9600 |
Zn1—N2 | 2.0576 (18) | C11—C16 | 1.397 (3) |
Zn1—Zn1i | 3.1546 (5) | C11—C12 | 1.416 (3) |
O1—C8 | 1.277 (3) | C12—C13 | 1.404 (3) |
O2—C4 | 1.369 (3) | C12—C9i | 1.473 (3) |
O2—C7 | 1.421 (4) | C13—C14 | 1.366 (4) |
O3—C11 | 1.341 (2) | C13—H13A | 0.9300 |
O3—Zn1i | 2.0540 (15) | C14—C15 | 1.373 (4) |
N1—C8 | 1.314 (3) | C14—H14A | 0.9300 |
N1—N2 | 1.396 (3) | C15—C16 | 1.379 (3) |
N2—C9 | 1.290 (3) | C15—H15A | 0.9300 |
N3—C21 | 1.333 (3) | C16—H16A | 0.9300 |
N3—C17 | 1.333 (3) | C17—C18 | 1.370 (4) |
N4—C26 | 1.347 (5) | C17—H17A | 0.9300 |
N4—C22 | 1.358 (6) | C18—C19 | 1.370 (5) |
C1—C2 | 1.376 (4) | C18—H18A | 0.9300 |
C1—C6 | 1.391 (3) | C19—C20 | 1.360 (5) |
C1—H1B | 0.9300 | C19—H19A | 0.9300 |
C2—C3 | 1.373 (4) | C20—C21 | 1.379 (4) |
C2—H2A | 0.9300 | C20—H20A | 0.9300 |
C3—C4 | 1.382 (4) | C21—H21A | 0.9300 |
C3—H3A | 0.9300 | C22—C23 | 1.329 (7) |
C4—C5 | 1.383 (3) | C22—H22A | 0.9300 |
C5—C6 | 1.383 (3) | C23—C24 | 1.333 (7) |
C5—H5A | 0.9300 | C23—H23A | 0.9300 |
C6—C8 | 1.492 (3) | C24—C25 | 1.301 (6) |
C7—H7A | 0.9600 | C24—H24A | 0.9300 |
C7—H7B | 0.9600 | C25—C26 | 1.335 (6) |
C7—H7C | 0.9600 | C25—H25A | 0.9300 |
C9—C12i | 1.473 (3) | C26—H26A | 0.9300 |
O3—Zn1—O1 | 103.59 (6) | N2—C9—C10 | 120.7 (2) |
O3—Zn1—N3 | 102.82 (7) | C12i—C9—C10 | 119.1 (2) |
O1—Zn1—N3 | 101.35 (7) | C9—C10—H10A | 109.5 |
O3—Zn1—O3i | 78.26 (6) | C9—C10—H10B | 109.5 |
O1—Zn1—O3i | 152.68 (7) | H10A—C10—H10B | 109.5 |
N3—Zn1—O3i | 104.80 (7) | C9—C10—H10C | 109.5 |
O3—Zn1—N2 | 144.21 (7) | H10A—C10—H10C | 109.5 |
O1—Zn1—N2 | 77.77 (7) | H10B—C10—H10C | 109.5 |
N3—Zn1—N2 | 112.05 (8) | O3—C11—C16 | 119.1 (2) |
O3i—Zn1—N2 | 85.17 (7) | O3—C11—C12 | 122.06 (19) |
O3—Zn1—Zn1i | 39.61 (4) | C16—C11—C12 | 118.8 (2) |
O1—Zn1—Zn1i | 136.75 (5) | C13—C12—C11 | 117.3 (2) |
N3—Zn1—Zn1i | 107.93 (6) | C13—C12—C9i | 118.2 (2) |
O3i—Zn1—Zn1i | 38.65 (4) | C11—C12—C9i | 124.46 (19) |
N2—Zn1—Zn1i | 117.56 (5) | C14—C13—C12 | 122.7 (2) |
C8—O1—Zn1 | 111.95 (14) | C14—C13—H13A | 118.6 |
C4—O2—C7 | 117.2 (2) | C12—C13—H13A | 118.6 |
C11—O3—Zn1 | 135.28 (13) | C13—C14—C15 | 119.6 (2) |
C11—O3—Zn1i | 121.66 (13) | C13—C14—H14A | 120.2 |
Zn1—O3—Zn1i | 101.74 (6) | C15—C14—H14A | 120.2 |
C8—N1—N2 | 109.91 (18) | C14—C15—C16 | 119.9 (2) |
C9—N2—N1 | 117.12 (18) | C14—C15—H15A | 120.0 |
C9—N2—Zn1 | 128.84 (16) | C16—C15—H15A | 120.0 |
N1—N2—Zn1 | 114.04 (13) | C15—C16—C11 | 121.5 (2) |
C21—N3—C17 | 118.0 (2) | C15—C16—H16A | 119.2 |
C21—N3—Zn1 | 120.41 (17) | C11—C16—H16A | 119.2 |
C17—N3—Zn1 | 121.19 (17) | N3—C17—C18 | 122.5 (3) |
C26—N4—C22 | 116.9 (4) | N3—C17—H17A | 118.8 |
C2—C1—C6 | 119.6 (2) | C18—C17—H17A | 118.8 |
C2—C1—H1B | 120.2 | C19—C18—C17 | 118.9 (3) |
C6—C1—H1B | 120.2 | C19—C18—H18A | 120.5 |
C3—C2—C1 | 121.6 (2) | C17—C18—H18A | 120.5 |
C3—C2—H2A | 119.2 | C20—C19—C18 | 119.4 (3) |
C1—C2—H2A | 119.2 | C20—C19—H19A | 120.3 |
C2—C3—C4 | 119.0 (2) | C18—C19—H19A | 120.3 |
C2—C3—H3A | 120.5 | C19—C20—C21 | 118.7 (3) |
C4—C3—H3A | 120.5 | C19—C20—H20A | 120.6 |
O2—C4—C3 | 123.9 (2) | C21—C20—H20A | 120.6 |
O2—C4—C5 | 115.9 (2) | N3—C21—C20 | 122.5 (3) |
C3—C4—C5 | 120.3 (2) | N3—C21—H21A | 118.8 |
C4—C5—C6 | 120.5 (2) | C20—C21—H21A | 118.8 |
C4—C5—H5A | 119.7 | C23—C22—N4 | 120.4 (4) |
C6—C5—H5A | 119.7 | C23—C22—H22A | 119.8 |
C5—C6—C1 | 119.1 (2) | N4—C22—H22A | 119.8 |
C5—C6—C8 | 122.0 (2) | C22—C23—C24 | 122.3 (4) |
C1—C6—C8 | 118.9 (2) | C22—C23—H23A | 118.8 |
O2—C7—H7A | 109.5 | C24—C23—H23A | 118.8 |
O2—C7—H7B | 109.5 | C25—C24—C23 | 116.9 (4) |
H7A—C7—H7B | 109.5 | C25—C24—H24A | 121.6 |
O2—C7—H7C | 109.5 | C23—C24—H24A | 121.6 |
H7A—C7—H7C | 109.5 | C24—C25—C26 | 123.4 (4) |
H7B—C7—H7C | 109.5 | C24—C25—H25A | 118.3 |
O1—C8—N1 | 126.0 (2) | C26—C25—H25A | 118.3 |
O1—C8—C6 | 116.88 (19) | C25—C26—N4 | 120.2 (4) |
N1—C8—C6 | 117.1 (2) | C25—C26—H26A | 119.9 |
N2—C9—C12i | 120.3 (2) | N4—C26—H26A | 119.9 |
O3—Zn1—O1—C8 | −138.65 (15) | C4—C5—C6—C8 | 179.2 (2) |
N3—Zn1—O1—C8 | 115.01 (15) | C2—C1—C6—C5 | 0.4 (4) |
O3i—Zn1—O1—C8 | −48.0 (2) | C2—C1—C6—C8 | −179.0 (2) |
N2—Zn1—O1—C8 | 4.62 (15) | Zn1—O1—C8—N1 | −4.7 (3) |
Zn1i—Zn1—O1—C8 | −112.79 (14) | Zn1—O1—C8—C6 | 174.90 (14) |
O1—Zn1—O3—C11 | −14.3 (2) | N2—N1—C8—O1 | 0.9 (3) |
N3—Zn1—O3—C11 | 90.92 (19) | N2—N1—C8—C6 | −178.71 (17) |
O3i—Zn1—O3—C11 | −166.4 (2) | C5—C6—C8—O1 | −170.0 (2) |
N2—Zn1—O3—C11 | −102.2 (2) | C1—C6—C8—O1 | 9.4 (3) |
Zn1i—Zn1—O3—C11 | −166.4 (2) | C5—C6—C8—N1 | 9.6 (3) |
O1—Zn1—O3—Zn1i | 152.05 (7) | C1—C6—C8—N1 | −170.9 (2) |
N3—Zn1—O3—Zn1i | −102.73 (8) | N1—N2—C9—C12i | −179.88 (19) |
O3i—Zn1—O3—Zn1i | 0.000 (1) | Zn1—N2—C9—C12i | 1.1 (3) |
N2—Zn1—O3—Zn1i | 64.20 (13) | N1—N2—C9—C10 | 0.1 (3) |
C8—N1—N2—C9 | −175.8 (2) | Zn1—N2—C9—C10 | −178.96 (19) |
C8—N1—N2—Zn1 | 3.4 (2) | Zn1—O3—C11—C16 | 19.9 (3) |
O3—Zn1—N2—C9 | −89.0 (2) | Zn1i—O3—C11—C16 | −144.36 (17) |
O1—Zn1—N2—C9 | 174.7 (2) | Zn1—O3—C11—C12 | −159.77 (16) |
N3—Zn1—N2—C9 | 77.2 (2) | Zn1i—O3—C11—C12 | 36.0 (3) |
O3i—Zn1—N2—C9 | −26.8 (2) | O3—C11—C12—C13 | −177.1 (2) |
Zn1i—Zn1—N2—C9 | −48.7 (2) | C16—C11—C12—C13 | 3.3 (3) |
O3—Zn1—N2—N1 | 91.94 (17) | O3—C11—C12—C9i | 4.3 (3) |
O1—Zn1—N2—N1 | −4.40 (14) | C16—C11—C12—C9i | −175.4 (2) |
N3—Zn1—N2—N1 | −101.83 (15) | C11—C12—C13—C14 | −1.6 (4) |
O3i—Zn1—N2—N1 | 154.14 (15) | C9i—C12—C13—C14 | 177.1 (3) |
Zn1i—Zn1—N2—N1 | 132.28 (13) | C12—C13—C14—C15 | −0.9 (5) |
O3—Zn1—N3—C21 | −13.2 (2) | C13—C14—C15—C16 | 1.6 (5) |
O1—Zn1—N3—C21 | 93.77 (19) | C14—C15—C16—C11 | 0.2 (4) |
O3i—Zn1—N3—C21 | −94.22 (19) | O3—C11—C16—C15 | 177.7 (2) |
N2—Zn1—N3—C21 | 175.04 (18) | C12—C11—C16—C15 | −2.6 (4) |
Zn1i—Zn1—N3—C21 | −54.0 (2) | C21—N3—C17—C18 | 0.0 (4) |
O3—Zn1—N3—C17 | 173.95 (19) | Zn1—N3—C17—C18 | 173.1 (2) |
O1—Zn1—N3—C17 | −79.1 (2) | N3—C17—C18—C19 | −0.4 (5) |
O3i—Zn1—N3—C17 | 92.9 (2) | C17—C18—C19—C20 | 0.2 (5) |
N2—Zn1—N3—C17 | 2.2 (2) | C18—C19—C20—C21 | 0.3 (5) |
Zn1i—Zn1—N3—C17 | 133.14 (19) | C17—N3—C21—C20 | 0.5 (4) |
C6—C1—C2—C3 | −0.2 (4) | Zn1—N3—C21—C20 | −172.6 (2) |
C1—C2—C3—C4 | −0.3 (4) | C19—C20—C21—N3 | −0.6 (5) |
C7—O2—C4—C3 | 1.1 (5) | C26—N4—C22—C23 | 0.7 (7) |
C7—O2—C4—C5 | −179.8 (3) | N4—C22—C23—C24 | 0.5 (8) |
C2—C3—C4—O2 | 179.5 (3) | C22—C23—C24—C25 | −1.3 (7) |
C2—C3—C4—C5 | 0.4 (4) | C23—C24—C25—C26 | 0.8 (6) |
O2—C4—C5—C6 | −179.3 (2) | C24—C25—C26—N4 | 0.4 (7) |
C3—C4—C5—C6 | −0.1 (4) | C22—N4—C26—C25 | −1.1 (7) |
C4—C5—C6—C1 | −0.3 (4) |
Symmetry code: (i) −x+2, −y+2, −z. |
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