Bis{μ-3-methoxy-N′-[1-(2-oxido­phenyl)­ethyl­idene]­benzohydrazidato}bis­[pyridine­zinc(II)] pyridine solvate

The title compound, [Zn₂(C₂₁H₁₄N₂O₃)₂(C₅H₅N)₂]·C₅H₅N, is dimeric via Zn—O bridging, with an average value for the Zn—O bonds of 2.027 (2) Å. The Zn...Zn separation is 3.1546 (5) Å. The mol­ecule has a center of inversion and the coordination geometry of both Zn atoms is square pyramidal.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.004 Å
• R factor = 0.032
• wR factor = 0.087
• Data-to-parameter ratio = 13.0

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given .......          ?
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.65 Ratio
PLAT243_ALERT_4_C High Solvent U(eq) as Compared to Neighbors  for         N4
PLAT244_ALERT_4_C Low  Solvent U(eq) as Compared to Neighbors  for        C26

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   5 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   1 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   3 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: SMART (Siemens, 1996); cell refinement: SAINT (Siemens, 1996); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 1997); software used to prepare material for publication: SHELXTL, PARST (Nardelli, 1995) and PLATON (Spek, 2003).

Bis{µ-N'-[1-(2-oxidophenyl)ethylidene]-3- methoxybenzohydrazidato}bis[pyridinezinc(II)] pyridine solvate

Crystal data

[Zn2(C21H14N2O3)2(C5H5N)2]·C5H5N	Z = 1
Mr = 1011.76	F(000) = 524
Triclinic, P1	Dx = 1.437 Mg m^−3
a = 8.5896 (8) Å	Mo Kα radiation, λ = 0.71073 Å
b = 10.6112 (10) Å	Cell parameters from 5617 reflections
c = 14.2017 (13) Å	θ = 1.5–25.0°
α = 71.360 (2)°	µ = 1.09 mm^−1
β = 73.261 (1)°	T = 293 K
γ = 79.670 (2)°	Block, pale yellow
V = 1169.11 (19) Å^3	0.46 × 0.37 × 0.20 mm

Data collection

Bruker SMART APEX area-detector diffractometer	4005 independent reflections
Radiation source: fine-focus sealed tube	3771 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.016
Detector resolution: 83.66 pixels mm^-1	θmax = 25.0°, θmin = 1.5°
ω scans	h = −10→10
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	k = −9→12
Tmin = 0.635, Tmax = 0.812	l = −16→16
7209 measured reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.032	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.087	H-atom parameters constrained
S = 1.04	w = 1/[σ^2(Fo^2) + (0.0495P)^2 + 0.6076P] where P = (Fo^2 + 2Fc^2)/3
4005 reflections	(Δ/σ)max < 0.001
307 parameters	Δρmax = 0.36 e Å^−3
0 restraints	Δρmin = −0.36 e Å^−3

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Zn1	0.95855 (3)	0.85027 (2)	0.048601 (17)	0.03121 (10)
O1	0.9978 (2)	0.69718 (16)	0.16963 (12)	0.0425 (4)
O2	1.4357 (3)	0.1951 (2)	0.25276 (16)	0.0713 (6)
O3	0.96360 (19)	1.01310 (15)	0.09080 (11)	0.0354 (3)
N1	1.1554 (2)	0.59591 (19)	0.04708 (14)	0.0396 (4)
N2	1.1000 (2)	0.71092 (18)	−0.02085 (14)	0.0354 (4)
N3	0.7146 (2)	0.84692 (19)	0.06404 (15)	0.0389 (4)
N4	0.4623 (6)	0.5889 (4)	0.3501 (3)	0.1126 (12)
C1	1.0658 (3)	0.4811 (3)	0.32637 (19)	0.0472 (6)
H1B	0.9825	0.5460	0.3420	0.057*
C2	1.1120 (4)	0.3775 (3)	0.4037 (2)	0.0545 (7)
H2A	1.0592	0.3735	0.4715	0.065*
C3	1.2342 (3)	0.2801 (3)	0.3830 (2)	0.0524 (6)
H3A	1.2643	0.2110	0.4362	0.063*
C4	1.3118 (3)	0.2863 (3)	0.2821 (2)	0.0482 (6)
C5	1.2672 (3)	0.3898 (2)	0.20338 (19)	0.0443 (5)
H5A	1.3202	0.3934	0.1356	0.053*
C6	1.1445 (3)	0.4881 (2)	0.22467 (17)	0.0368 (5)
C7	1.4839 (5)	0.0873 (4)	0.3319 (3)	0.0861 (12)
H7A	1.5713	0.0307	0.3020	0.129*
H7B	1.3927	0.0366	0.3711	0.129*
H7C	1.5202	0.1217	0.3759	0.129*
C8	1.0948 (3)	0.6021 (2)	0.14183 (17)	0.0345 (5)
C9	1.1412 (3)	0.7157 (2)	−0.11667 (17)	0.0386 (5)
C10	1.2440 (4)	0.6015 (3)	−0.1520 (2)	0.0579 (7)
H10A	1.2624	0.6218	−0.2250	0.087*
H10B	1.1884	0.5220	−0.1192	0.087*
H10C	1.3468	0.5877	−0.1344	0.087*
C11	0.9568 (3)	1.0369 (2)	0.17917 (15)	0.0325 (4)
C12	0.9122 (3)	1.1662 (2)	0.19299 (16)	0.0372 (5)
C13	0.9165 (4)	1.1811 (3)	0.28695 (19)	0.0553 (7)
H13A	0.8903	1.2656	0.2969	0.066*
C14	0.9575 (4)	1.0766 (3)	0.3643 (2)	0.0644 (8)
H14A	0.9605	1.0906	0.4251	0.077*
C15	0.9944 (4)	0.9506 (3)	0.35181 (19)	0.0538 (7)
H15A	1.0198	0.8787	0.4048	0.065*
C16	0.9939 (3)	0.9310 (2)	0.26048 (17)	0.0411 (5)
H16A	1.0188	0.8453	0.2528	0.049*
C17	0.6616 (3)	0.7589 (3)	0.0342 (2)	0.0503 (6)
H17A	0.7379	0.7048	−0.0008	0.060*
C18	0.4990 (4)	0.7450 (3)	0.0531 (3)	0.0659 (8)
H18A	0.4656	0.6830	0.0310	0.079*
C19	0.3864 (3)	0.8238 (4)	0.1052 (3)	0.0683 (9)
H19A	0.2754	0.8158	0.1191	0.082*
C20	0.4383 (3)	0.9140 (3)	0.1364 (2)	0.0607 (7)
H20A	0.3637	0.9682	0.1721	0.073*
C21	0.6037 (3)	0.9236 (3)	0.1142 (2)	0.0492 (6)
H21A	0.6393	0.9858	0.1349	0.059*
C22	0.3426 (5)	0.6271 (5)	0.4249 (4)	0.0988 (13)
H22A	0.2401	0.5963	0.4436	0.119*
C23	0.3710 (7)	0.7081 (5)	0.4713 (3)	0.1066 (16)
H23A	0.2874	0.7323	0.5227	0.128*
C24	0.5152 (6)	0.7560 (4)	0.4469 (3)	0.0836 (11)
H24A	0.5331	0.8141	0.4790	0.100*
C25	0.6296 (5)	0.7178 (4)	0.3760 (4)	0.0887 (12)
H25A	0.7316	0.7491	0.3584	0.106*
C26	0.6083 (5)	0.6359 (4)	0.3273 (3)	0.0782 (10)
H26A	0.6945	0.6112	0.2775	0.094*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Zn1	0.03251 (15)	0.02758 (16)	0.03318 (15)	−0.00126 (10)	−0.00870 (10)	−0.00852 (10)
O1	0.0549 (10)	0.0312 (9)	0.0359 (8)	0.0061 (7)	−0.0105 (7)	−0.0082 (7)
O2	0.0849 (15)	0.0499 (12)	0.0604 (12)	0.0287 (11)	−0.0182 (11)	−0.0090 (10)
O3	0.0507 (9)	0.0283 (8)	0.0289 (7)	−0.0045 (7)	−0.0105 (6)	−0.0096 (6)
N1	0.0470 (11)	0.0303 (10)	0.0380 (10)	0.0049 (8)	−0.0128 (8)	−0.0077 (8)
N2	0.0405 (10)	0.0292 (10)	0.0351 (9)	0.0012 (8)	−0.0115 (8)	−0.0080 (8)
N3	0.0352 (9)	0.0350 (10)	0.0454 (11)	−0.0017 (8)	−0.0118 (8)	−0.0090 (8)
N4	0.122 (3)	0.107 (3)	0.116 (3)	−0.008 (2)	−0.032 (3)	−0.040 (2)
C1	0.0521 (14)	0.0419 (14)	0.0429 (13)	0.0051 (11)	−0.0118 (11)	−0.0110 (11)
C2	0.0653 (17)	0.0520 (16)	0.0375 (13)	0.0018 (13)	−0.0109 (12)	−0.0063 (12)
C3	0.0633 (16)	0.0413 (14)	0.0458 (14)	0.0028 (12)	−0.0204 (12)	−0.0012 (11)
C4	0.0525 (14)	0.0359 (13)	0.0517 (14)	0.0047 (11)	−0.0158 (12)	−0.0087 (11)
C5	0.0525 (14)	0.0368 (13)	0.0405 (12)	0.0017 (11)	−0.0124 (11)	−0.0092 (10)
C6	0.0424 (12)	0.0304 (12)	0.0382 (11)	−0.0044 (9)	−0.0132 (9)	−0.0071 (9)
C7	0.099 (3)	0.058 (2)	0.077 (2)	0.0375 (19)	−0.027 (2)	−0.0064 (17)
C8	0.0366 (11)	0.0276 (11)	0.0400 (12)	−0.0044 (9)	−0.0120 (9)	−0.0076 (9)
C9	0.0461 (12)	0.0326 (12)	0.0382 (12)	−0.0022 (10)	−0.0092 (10)	−0.0133 (9)
C10	0.081 (2)	0.0388 (15)	0.0481 (15)	0.0118 (13)	−0.0114 (14)	−0.0190 (12)
C11	0.0342 (10)	0.0360 (12)	0.0282 (10)	−0.0071 (9)	−0.0064 (8)	−0.0094 (9)
C12	0.0464 (12)	0.0340 (12)	0.0321 (11)	−0.0043 (9)	−0.0089 (9)	−0.0109 (9)
C13	0.091 (2)	0.0407 (15)	0.0399 (13)	−0.0050 (14)	−0.0200 (13)	−0.0173 (11)
C14	0.112 (3)	0.0545 (18)	0.0371 (13)	−0.0075 (17)	−0.0301 (15)	−0.0165 (12)
C15	0.0789 (19)	0.0473 (16)	0.0351 (12)	−0.0033 (13)	−0.0219 (12)	−0.0060 (11)
C16	0.0520 (13)	0.0348 (12)	0.0355 (11)	−0.0014 (10)	−0.0121 (10)	−0.0092 (10)
C17	0.0444 (13)	0.0434 (15)	0.0675 (17)	−0.0030 (11)	−0.0167 (12)	−0.0197 (13)
C18	0.0515 (16)	0.0614 (19)	0.097 (2)	−0.0117 (14)	−0.0265 (16)	−0.0288 (17)
C19	0.0367 (14)	0.077 (2)	0.090 (2)	−0.0102 (14)	−0.0172 (14)	−0.0181 (18)
C20	0.0389 (13)	0.0671 (19)	0.0707 (19)	0.0047 (13)	−0.0082 (13)	−0.0224 (15)
C21	0.0415 (13)	0.0505 (16)	0.0565 (15)	−0.0011 (11)	−0.0114 (11)	−0.0192 (12)
C22	0.067 (2)	0.107 (3)	0.116 (3)	−0.019 (2)	0.003 (2)	−0.041 (3)
C23	0.120 (4)	0.103 (4)	0.071 (2)	0.039 (3)	−0.004 (2)	−0.035 (2)
C24	0.122 (3)	0.055 (2)	0.096 (3)	0.013 (2)	−0.060 (3)	−0.032 (2)
C25	0.074 (2)	0.065 (2)	0.121 (3)	−0.0137 (19)	−0.044 (2)	0.003 (2)
C26	0.071 (2)	0.078 (3)	0.073 (2)	−0.0039 (18)	−0.0039 (17)	−0.0187 (19)

Geometric parameters (Å, º)

Zn1—O3	2.0125 (14)	C9—C10	1.499 (3)
Zn1—O1	2.0147 (16)	C10—H10A	0.9600
Zn1—N3	2.0488 (19)	C10—H10B	0.9600
Zn1—O3^i	2.0540 (15)	C10—H10C	0.9600
Zn1—N2	2.0576 (18)	C11—C16	1.397 (3)
Zn1—Zn1^i	3.1546 (5)	C11—C12	1.416 (3)
O1—C8	1.277 (3)	C12—C13	1.404 (3)
O2—C4	1.369 (3)	C12—C9^i	1.473 (3)
O2—C7	1.421 (4)	C13—C14	1.366 (4)
O3—C11	1.341 (2)	C13—H13A	0.9300
O3—Zn1^i	2.0540 (15)	C14—C15	1.373 (4)
N1—C8	1.314 (3)	C14—H14A	0.9300
N1—N2	1.396 (3)	C15—C16	1.379 (3)
N2—C9	1.290 (3)	C15—H15A	0.9300
N3—C21	1.333 (3)	C16—H16A	0.9300
N3—C17	1.333 (3)	C17—C18	1.370 (4)
N4—C26	1.347 (5)	C17—H17A	0.9300
N4—C22	1.358 (6)	C18—C19	1.370 (5)
C1—C2	1.376 (4)	C18—H18A	0.9300
C1—C6	1.391 (3)	C19—C20	1.360 (5)
C1—H1B	0.9300	C19—H19A	0.9300
C2—C3	1.373 (4)	C20—C21	1.379 (4)
C2—H2A	0.9300	C20—H20A	0.9300
C3—C4	1.382 (4)	C21—H21A	0.9300
C3—H3A	0.9300	C22—C23	1.329 (7)
C4—C5	1.383 (3)	C22—H22A	0.9300
C5—C6	1.383 (3)	C23—C24	1.333 (7)
C5—H5A	0.9300	C23—H23A	0.9300
C6—C8	1.492 (3)	C24—C25	1.301 (6)
C7—H7A	0.9600	C24—H24A	0.9300
C7—H7B	0.9600	C25—C26	1.335 (6)
C7—H7C	0.9600	C25—H25A	0.9300
C9—C12^i	1.473 (3)	C26—H26A	0.9300
O3—Zn1—O1	103.59 (6)	N2—C9—C10	120.7 (2)
O3—Zn1—N3	102.82 (7)	C12^i—C9—C10	119.1 (2)
O1—Zn1—N3	101.35 (7)	C9—C10—H10A	109.5
O3—Zn1—O3^i	78.26 (6)	C9—C10—H10B	109.5
O1—Zn1—O3^i	152.68 (7)	H10A—C10—H10B	109.5
N3—Zn1—O3^i	104.80 (7)	C9—C10—H10C	109.5
O3—Zn1—N2	144.21 (7)	H10A—C10—H10C	109.5
O1—Zn1—N2	77.77 (7)	H10B—C10—H10C	109.5
N3—Zn1—N2	112.05 (8)	O3—C11—C16	119.1 (2)
O3^i—Zn1—N2	85.17 (7)	O3—C11—C12	122.06 (19)
O3—Zn1—Zn1^i	39.61 (4)	C16—C11—C12	118.8 (2)
O1—Zn1—Zn1^i	136.75 (5)	C13—C12—C11	117.3 (2)
N3—Zn1—Zn1^i	107.93 (6)	C13—C12—C9^i	118.2 (2)
O3^i—Zn1—Zn1^i	38.65 (4)	C11—C12—C9^i	124.46 (19)
N2—Zn1—Zn1^i	117.56 (5)	C14—C13—C12	122.7 (2)
C8—O1—Zn1	111.95 (14)	C14—C13—H13A	118.6
C4—O2—C7	117.2 (2)	C12—C13—H13A	118.6
C11—O3—Zn1	135.28 (13)	C13—C14—C15	119.6 (2)
C11—O3—Zn1^i	121.66 (13)	C13—C14—H14A	120.2
Zn1—O3—Zn1^i	101.74 (6)	C15—C14—H14A	120.2
C8—N1—N2	109.91 (18)	C14—C15—C16	119.9 (2)
C9—N2—N1	117.12 (18)	C14—C15—H15A	120.0
C9—N2—Zn1	128.84 (16)	C16—C15—H15A	120.0
N1—N2—Zn1	114.04 (13)	C15—C16—C11	121.5 (2)
C21—N3—C17	118.0 (2)	C15—C16—H16A	119.2
C21—N3—Zn1	120.41 (17)	C11—C16—H16A	119.2
C17—N3—Zn1	121.19 (17)	N3—C17—C18	122.5 (3)
C26—N4—C22	116.9 (4)	N3—C17—H17A	118.8
C2—C1—C6	119.6 (2)	C18—C17—H17A	118.8
C2—C1—H1B	120.2	C19—C18—C17	118.9 (3)
C6—C1—H1B	120.2	C19—C18—H18A	120.5
C3—C2—C1	121.6 (2)	C17—C18—H18A	120.5
C3—C2—H2A	119.2	C20—C19—C18	119.4 (3)
C1—C2—H2A	119.2	C20—C19—H19A	120.3
C2—C3—C4	119.0 (2)	C18—C19—H19A	120.3
C2—C3—H3A	120.5	C19—C20—C21	118.7 (3)
C4—C3—H3A	120.5	C19—C20—H20A	120.6
O2—C4—C3	123.9 (2)	C21—C20—H20A	120.6
O2—C4—C5	115.9 (2)	N3—C21—C20	122.5 (3)
C3—C4—C5	120.3 (2)	N3—C21—H21A	118.8
C4—C5—C6	120.5 (2)	C20—C21—H21A	118.8
C4—C5—H5A	119.7	C23—C22—N4	120.4 (4)
C6—C5—H5A	119.7	C23—C22—H22A	119.8
C5—C6—C1	119.1 (2)	N4—C22—H22A	119.8
C5—C6—C8	122.0 (2)	C22—C23—C24	122.3 (4)
C1—C6—C8	118.9 (2)	C22—C23—H23A	118.8
O2—C7—H7A	109.5	C24—C23—H23A	118.8
O2—C7—H7B	109.5	C25—C24—C23	116.9 (4)
H7A—C7—H7B	109.5	C25—C24—H24A	121.6
O2—C7—H7C	109.5	C23—C24—H24A	121.6
H7A—C7—H7C	109.5	C24—C25—C26	123.4 (4)
H7B—C7—H7C	109.5	C24—C25—H25A	118.3
O1—C8—N1	126.0 (2)	C26—C25—H25A	118.3
O1—C8—C6	116.88 (19)	C25—C26—N4	120.2 (4)
N1—C8—C6	117.1 (2)	C25—C26—H26A	119.9
N2—C9—C12^i	120.3 (2)	N4—C26—H26A	119.9
O3—Zn1—O1—C8	−138.65 (15)	C4—C5—C6—C8	179.2 (2)
N3—Zn1—O1—C8	115.01 (15)	C2—C1—C6—C5	0.4 (4)
O3^i—Zn1—O1—C8	−48.0 (2)	C2—C1—C6—C8	−179.0 (2)
N2—Zn1—O1—C8	4.62 (15)	Zn1—O1—C8—N1	−4.7 (3)
Zn1^i—Zn1—O1—C8	−112.79 (14)	Zn1—O1—C8—C6	174.90 (14)
O1—Zn1—O3—C11	−14.3 (2)	N2—N1—C8—O1	0.9 (3)
N3—Zn1—O3—C11	90.92 (19)	N2—N1—C8—C6	−178.71 (17)
O3^i—Zn1—O3—C11	−166.4 (2)	C5—C6—C8—O1	−170.0 (2)
N2—Zn1—O3—C11	−102.2 (2)	C1—C6—C8—O1	9.4 (3)
Zn1^i—Zn1—O3—C11	−166.4 (2)	C5—C6—C8—N1	9.6 (3)
O1—Zn1—O3—Zn1^i	152.05 (7)	C1—C6—C8—N1	−170.9 (2)
N3—Zn1—O3—Zn1^i	−102.73 (8)	N1—N2—C9—C12^i	−179.88 (19)
O3^i—Zn1—O3—Zn1^i	0.000 (1)	Zn1—N2—C9—C12^i	1.1 (3)
N2—Zn1—O3—Zn1^i	64.20 (13)	N1—N2—C9—C10	0.1 (3)
C8—N1—N2—C9	−175.8 (2)	Zn1—N2—C9—C10	−178.96 (19)
C8—N1—N2—Zn1	3.4 (2)	Zn1—O3—C11—C16	19.9 (3)
O3—Zn1—N2—C9	−89.0 (2)	Zn1^i—O3—C11—C16	−144.36 (17)
O1—Zn1—N2—C9	174.7 (2)	Zn1—O3—C11—C12	−159.77 (16)
N3—Zn1—N2—C9	77.2 (2)	Zn1^i—O3—C11—C12	36.0 (3)
O3^i—Zn1—N2—C9	−26.8 (2)	O3—C11—C12—C13	−177.1 (2)
Zn1^i—Zn1—N2—C9	−48.7 (2)	C16—C11—C12—C13	3.3 (3)
O3—Zn1—N2—N1	91.94 (17)	O3—C11—C12—C9^i	4.3 (3)
O1—Zn1—N2—N1	−4.40 (14)	C16—C11—C12—C9^i	−175.4 (2)
N3—Zn1—N2—N1	−101.83 (15)	C11—C12—C13—C14	−1.6 (4)
O3^i—Zn1—N2—N1	154.14 (15)	C9^i—C12—C13—C14	177.1 (3)
Zn1^i—Zn1—N2—N1	132.28 (13)	C12—C13—C14—C15	−0.9 (5)
O3—Zn1—N3—C21	−13.2 (2)	C13—C14—C15—C16	1.6 (5)
O1—Zn1—N3—C21	93.77 (19)	C14—C15—C16—C11	0.2 (4)
O3^i—Zn1—N3—C21	−94.22 (19)	O3—C11—C16—C15	177.7 (2)
N2—Zn1—N3—C21	175.04 (18)	C12—C11—C16—C15	−2.6 (4)
Zn1^i—Zn1—N3—C21	−54.0 (2)	C21—N3—C17—C18	0.0 (4)
O3—Zn1—N3—C17	173.95 (19)	Zn1—N3—C17—C18	173.1 (2)
O1—Zn1—N3—C17	−79.1 (2)	N3—C17—C18—C19	−0.4 (5)
O3^i—Zn1—N3—C17	92.9 (2)	C17—C18—C19—C20	0.2 (5)
N2—Zn1—N3—C17	2.2 (2)	C18—C19—C20—C21	0.3 (5)
Zn1^i—Zn1—N3—C17	133.14 (19)	C17—N3—C21—C20	0.5 (4)
C6—C1—C2—C3	−0.2 (4)	Zn1—N3—C21—C20	−172.6 (2)
C1—C2—C3—C4	−0.3 (4)	C19—C20—C21—N3	−0.6 (5)
C7—O2—C4—C3	1.1 (5)	C26—N4—C22—C23	0.7 (7)
C7—O2—C4—C5	−179.8 (3)	N4—C22—C23—C24	0.5 (8)
C2—C3—C4—O2	179.5 (3)	C22—C23—C24—C25	−1.3 (7)
C2—C3—C4—C5	0.4 (4)	C23—C24—C25—C26	0.8 (6)
O2—C4—C5—C6	−179.3 (2)	C24—C25—C26—N4	0.4 (7)
C3—C4—C5—C6	−0.1 (4)	C22—N4—C26—C25	−1.1 (7)
C4—C5—C6—C1	−0.3 (4)

Symmetry code: (i) −x+2, −y+2, −z.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C16—H16A···O1	0.93	2.30	3.133 (3)	148