Tetra­carbonyl­tungsten(0)-bis(μ-di­methyl­phosphido)-bis­[di­cyclo­penta­dienyl­hydridomolybdenum(IV)]

The title trinuclear WMo₂ compound, [Mo₂WH₂(C₅H₅)₄(C₂H₆P)₂(CO)₄], was obtained by opening of the hydride bridge in the dinuclear dibridged (μ-PMe₂,H){(C₅H₅)₂Mo}{W(CO)₄} complex (Mo^IV) upon the action of (C₅H₅)₂Mo(PMe₂H) (Mo^II) in THF solution. This involves the formal conversion of Mo^II to Mo^IV.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.019 Å
• R factor = 0.042
• wR factor = 0.084
• Data-to-parameter ratio = 16.6

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry

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Computing details

Data collection: CAD-4 EXPRESS (Enraf-Nonius, 1992); cell refinement: CAD-4 EXPRESS; data reduction: PROCESS in MolEN (Fair, 1990); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.

tetracarbonyltungsten(0)-bis(µ-dimethylphosphido-dicyclopentadienyl hydridomolybdenum(IV))

Crystal data

[Mo2WH2(C5H5)4(C2H6P)2(CO)4]	F(000) = 1688
Mr = 872.21	Dx = 1.993 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 25 reflections
a = 15.342 (5) Å	θ = 7.8–14.2°
b = 17.087 (2) Å	µ = 4.94 mm^−1
c = 11.274 (2) Å	T = 293 K
β = 100.40 (2)°	Irregular, yellow
V = 2907.0 (11) Å^3	0.2 × 0.10 × 0.08 mm
Z = 4

Data collection

Enraf-Nonius CAD-4 diffractometer	2986 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.049
Graphite monochromator	θmax = 26.0°, θmin = 1.8°
ω scans	h = 0→18
Absorption correction: empirical (using intensity measurements) (DIFABS; Walker & Stuart, 1983)	k = 0→21
Tmin = 0.595, Tmax = 0.674	l = −13→13
5899 measured reflections	3 standard reflections every 120 min
5683 independent reflections	intensity decay: −4.1%

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.042	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.084	H-atom parameters constrained
S = 1.00	w = 1/[σ^2(Fo^2) + (0.0466P)^2] where P = (Fo^2 + 2Fc^2)/3
5683 reflections	(Δ/σ)max = 0.001
342 parameters	Δρmax = 1.43 e Å^−3
0 restraints	Δρmin = −1.46 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)

are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
W	0.28109 (3)	0.20651 (3)	0.40935 (4)	0.03317 (13)
Mo1	0.37836 (7)	0.11592 (6)	0.79222 (8)	0.0369 (2)
Mo2	0.42308 (7)	0.38935 (5)	0.22112 (8)	0.0336 (2)
P1	0.3234 (2)	0.2277 (2)	0.6423 (2)	0.0353 (7)
P2	0.4191 (2)	0.2542 (2)	0.3228 (2)	0.0338 (7)
C1	0.2278 (9)	0.1853 (7)	0.2403 (12)	0.057 (4)
C2	0.1684 (9)	0.1692 (6)	0.4437 (10)	0.042 (3)
C3	0.3401 (8)	0.1007 (8)	0.4251 (10)	0.049 (3)
C4	0.2390 (8)	0.3187 (6)	0.4036 (11)	0.046 (3)
O1	0.1897 (8)	0.1687 (7)	0.1449 (9)	0.095 (4)
O2	0.0979 (6)	0.1472 (5)	0.4560 (8)	0.060 (2)
O3	0.3742 (7)	0.0399 (5)	0.4335 (9)	0.077 (3)
O4	0.2183 (6)	0.3826 (5)	0.4062 (9)	0.070 (3)
C5	0.3962 (9)	0.3136 (6)	0.6866 (11)	0.059 (4)
H5A	0.4542	0.3031	0.6699	0.077*
H5B	0.4001	0.3235	0.7712	0.077*
H5C	0.3718	0.3587	0.6416	0.077*
C6	0.2249 (9)	0.2734 (8)	0.6890 (13)	0.072 (4)
H6A	0.1759	0.2377	0.6738	0.093*
H6B	0.2099	0.3207	0.6439	0.093*
H6C	0.2382	0.2855	0.7735	0.093*
C7	0.5258 (8)	0.2404 (7)	0.4260 (10)	0.054 (3)
H7A	0.5294	0.2757	0.4929	0.070*
H7B	0.5736	0.2509	0.3837	0.070*
H7C	0.5301	0.1875	0.4550	0.070*
C8	0.4429 (9)	0.1781 (6)	0.2161 (11)	0.057 (4)
H8A	0.3938	0.1741	0.1502	0.073*
H8B	0.4519	0.1287	0.2570	0.073*
H8C	0.4954	0.1921	0.1857	0.073*
C9	0.5044 (9)	0.1505 (9)	0.7150 (13)	0.067 (4)
H9	0.5025	0.1811	0.6463	0.087*
C10	0.5004 (9)	0.0696 (9)	0.7186 (12)	0.067 (4)
H10	0.4946	0.0366	0.6520	0.087*
C11	0.5064 (10)	0.0453 (8)	0.8386 (12)	0.067 (4)
H11	0.5062	−0.0060	0.8661	0.087*
C12	0.5129 (8)	0.1140 (9)	0.9095 (12)	0.061 (4)
H12	0.5171	0.1157	0.9928	0.079*
C13	0.5120 (8)	0.1781 (8)	0.8347 (12)	0.055 (3)
H13	0.5157	0.2303	0.8587	0.071*
C14	0.2776 (11)	0.0202 (9)	0.7184 (13)	0.075 (5)
H14	0.2820	−0.0056	0.6471	0.097*
C15	0.3210 (10)	−0.0001 (8)	0.8368 (15)	0.077 (5)
H15	0.3574	−0.0433	0.8577	0.100*
C16	0.2999 (11)	0.0549 (10)	0.9141 (13)	0.079 (5)
H16	0.3198	0.0545	0.9971	0.103*
C17	0.2439 (9)	0.1126 (10)	0.8515 (14)	0.073 (4)
H17	0.2222	0.1578	0.8818	0.095*
C18	0.2288 (9)	0.0846 (10)	0.7305 (15)	0.072 (5)
H18	0.1900	0.1078	0.6674	0.094*
C19	0.3964 (10)	0.3349 (8)	0.0322 (10)	0.057 (4)
H19	0.4341	0.2977	0.0087	0.074*
C20	0.4054 (11)	0.4164 (8)	0.0248 (10)	0.060 (4)
H20	0.4511	0.4427	−0.0024	0.078*
C21	0.3340 (11)	0.4511 (8)	0.0655 (11)	0.068 (4)
H21	0.3222	0.5045	0.0676	0.088*
C22	0.2816 (9)	0.3892 (8)	0.1039 (10)	0.054 (3)
H22	0.2310	0.3950	0.1377	0.070*
C23	0.3210 (9)	0.3195 (7)	0.0809 (10)	0.051 (3)
H23	0.3003	0.2699	0.0957	0.066*
C24	0.4375 (9)	0.5171 (7)	0.2845 (10)	0.050 (3)
H24	0.4169	0.5587	0.2339	0.066*
C25	0.3900 (9)	0.4782 (7)	0.3622 (12)	0.055 (3)
H25	0.3318	0.4883	0.3702	0.071*
C26	0.4458 (9)	0.4214 (7)	0.4253 (9)	0.048 (3)
H26	0.4315	0.3880	0.4841	0.063*
C27	0.5283 (8)	0.4236 (7)	0.3838 (10)	0.048 (3)
H27	0.5774	0.3920	0.4097	0.062*
C28	0.5208 (9)	0.4826 (7)	0.2964 (11)	0.050 (3)
H28	0.5647	0.4966	0.2532	0.065*
H1	0.365 (6)	0.192 (5)	0.872 (7)	0.03 (2)*
H2	0.488 (9)	0.329 (7)	0.179 (12)	0.10 (5)*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
W	0.0314 (2)	0.0343 (2)	0.0334 (2)	−0.0009 (3)	0.0049 (2)	−0.0012 (2)
Mo1	0.0404 (6)	0.0368 (5)	0.0328 (5)	−0.0031 (5)	0.0047 (5)	0.0010 (4)
Mo2	0.0386 (6)	0.0353 (5)	0.0270 (5)	−0.0033 (5)	0.0061 (4)	−0.0034 (4)
P1	0.039 (2)	0.035 (2)	0.0319 (15)	−0.0005 (13)	0.0079 (14)	−0.0016 (12)
P2	0.035 (2)	0.036 (2)	0.032 (2)	0.0006 (14)	0.0082 (14)	−0.0037 (13)
C1	0.069 (10)	0.058 (9)	0.047 (8)	−0.029 (7)	0.022 (8)	−0.004 (6)
C2	0.054 (9)	0.032 (6)	0.037 (7)	0.004 (6)	0.003 (6)	−0.005 (5)
C3	0.047 (8)	0.066 (9)	0.038 (7)	−0.015 (7)	0.016 (6)	−0.017 (6)
C4	0.045 (8)	0.028 (6)	0.072 (9)	−0.007 (5)	0.031 (7)	−0.002 (6)
O1	0.105 (9)	0.123 (9)	0.047 (6)	−0.053 (7)	−0.014 (6)	−0.001 (6)
O2	0.040 (6)	0.071 (6)	0.069 (6)	−0.008 (5)	0.013 (5)	−0.004 (5)
O3	0.087 (8)	0.040 (6)	0.109 (8)	0.024 (5)	0.030 (7)	−0.004 (5)
O4	0.053 (6)	0.039 (5)	0.118 (8)	0.007 (5)	0.020 (6)	0.013 (5)
C5	0.099 (11)	0.032 (7)	0.046 (7)	−0.023 (7)	0.011 (8)	−0.008 (5)
C6	0.074 (11)	0.075 (10)	0.075 (10)	0.024 (8)	0.037 (9)	0.003 (8)
C7	0.050 (8)	0.066 (8)	0.046 (7)	0.000 (7)	0.010 (7)	0.021 (6)
C8	0.076 (10)	0.040 (7)	0.060 (8)	0.001 (7)	0.031 (8)	−0.018 (6)
C9	0.049 (9)	0.092 (12)	0.067 (10)	0.018 (8)	0.026 (8)	0.012 (9)
C10	0.063 (10)	0.076 (11)	0.058 (9)	0.032 (9)	0.006 (8)	−0.010 (8)
C11	0.077 (11)	0.067 (10)	0.054 (9)	0.009 (8)	0.004 (8)	0.008 (8)
C12	0.034 (8)	0.101 (12)	0.042 (7)	0.005 (8)	−0.007 (6)	0.020 (8)
C13	0.028 (7)	0.062 (8)	0.071 (9)	−0.012 (6)	0.002 (7)	−0.011 (7)
C14	0.089 (13)	0.072 (11)	0.055 (9)	−0.034 (10)	−0.008 (9)	0.011 (8)
C15	0.081 (12)	0.039 (8)	0.093 (12)	−0.031 (8)	−0.032 (10)	0.028 (8)
C16	0.099 (14)	0.085 (11)	0.053 (9)	−0.058 (11)	0.014 (10)	0.015 (9)
C17	0.050 (10)	0.100 (13)	0.072 (11)	−0.023 (9)	0.021 (8)	0.004 (10)
C18	0.037 (9)	0.085 (12)	0.088 (12)	−0.022 (8)	−0.005 (8)	0.040 (10)
C19	0.076 (11)	0.069 (9)	0.024 (6)	−0.008 (8)	0.003 (7)	−0.017 (6)
C20	0.092 (12)	0.055 (8)	0.028 (7)	−0.029 (8)	0.000 (7)	0.005 (6)
C21	0.095 (12)	0.054 (9)	0.044 (8)	0.021 (9)	−0.014 (8)	0.003 (7)
C22	0.043 (8)	0.069 (9)	0.041 (7)	0.005 (7)	−0.014 (6)	0.002 (7)
C23	0.066 (10)	0.049 (8)	0.036 (7)	−0.018 (7)	0.000 (7)	0.008 (6)
C24	0.067 (10)	0.036 (7)	0.044 (7)	−0.003 (7)	−0.001 (7)	−0.012 (6)
C25	0.043 (8)	0.046 (8)	0.075 (9)	−0.005 (7)	0.013 (7)	−0.020 (7)
C26	0.069 (10)	0.051 (8)	0.025 (6)	−0.021 (7)	0.012 (6)	−0.009 (5)
C27	0.046 (8)	0.053 (8)	0.041 (7)	0.004 (7)	−0.003 (6)	−0.010 (6)
C28	0.051 (9)	0.052 (8)	0.047 (8)	−0.013 (7)	0.008 (7)	−0.006 (6)

Geometric parameters (Å, º)

W—C2	1.946 (13)	C7—H7A	0.96
W—C1	1.967 (14)	C7—H7B	0.96
W—C3	2.015 (14)	C7—H7C	0.96
W—C4	2.020 (12)	C8—H8A	0.96
W—P1	2.614 (3)	C8—H8B	0.96
W—P2	2.617 (3)	C8—H8C	0.96
W—Mo2	4.5474 (12)	C9—C10	1.39 (2)
W—Mo1	4.5749 (14)	C9—C13	1.41 (2)
Mo1—C16	2.241 (12)	C9—H9	0.93
Mo1—C12	2.241 (12)	C10—C11	1.40 (2)
Mo1—C15	2.261 (12)	C10—H10	0.93
Mo1—C17	2.281 (13)	C11—C12	1.41 (2)
Mo1—C13	2.282 (12)	C11—H11	0.93
Mo1—C11	2.284 (14)	C12—C13	1.38 (2)
Mo1—C14	2.300 (14)	C12—H12	0.93
Mo1—C10	2.320 (13)	C13—H13	0.93
Mo1—C9	2.336 (13)	C14—C18	1.35 (2)
Mo1—C18	2.336 (13)	C14—C15	1.42 (2)
Mo1—P1	2.589 (3)	C14—H14	0.93
Mo1—H1	1.62 (8)	C15—C16	1.36 (2)
Mo2—C20	2.229 (11)	C15—H15	0.93
Mo2—C28	2.248 (12)	C16—C17	1.41 (2)
Mo2—C21	2.279 (12)	C16—H16	0.93
Mo2—C27	2.290 (12)	C17—C18	1.42 (2)
Mo2—C19	2.292 (11)	C17—H17	0.93
Mo2—C24	2.296 (11)	C18—H18	0.93
Mo2—C25	2.320 (12)	C19—C23	1.39 (2)
Mo2—C22	2.329 (12)	C19—C20	1.40 (2)
Mo2—C26	2.330 (10)	C19—H19	0.93
Mo2—C23	2.341 (12)	C20—C21	1.39 (2)
Mo2—P2	2.583 (3)	C20—H20	0.93
Mo2—H2	1.56 (13)	C21—C22	1.44 (2)
P1—C5	1.857 (11)	C21—H21	0.93
P1—C6	1.859 (12)	C22—C23	1.38 (2)
P2—C7	1.845 (12)	C22—H22	0.93
P2—C8	1.852 (10)	C23—H23	0.93
C1—O1	1.163 (14)	C24—C28	1.39 (2)
C2—O2	1.178 (13)	C24—C25	1.40 (2)
C3—O3	1.159 (14)	C24—H24	0.93
C4—O4	1.138 (12)	C25—C26	1.40 (2)
C5—H5A	0.96	C25—H25	0.93
C5—H5B	0.96	C26—C27	1.43 (2)
C5—H5C	0.96	C26—H26	0.93
C6—H6A	0.96	C27—C28	1.40 (2)
C6—H6B	0.96	C27—H27	0.93
C6—H6C	0.96	C28—H28	0.93
C2—W—C1	84.5 (5)	C20—Mo2—H2	79 (5)
C2—W—C3	95.1 (5)	C28—Mo2—H2	99 (5)
C1—W—C3	91.2 (5)	C21—Mo2—H2	113 (5)
C2—W—C4	91.5 (4)	C27—Mo2—H2	91 (5)
C1—W—C4	94.0 (5)	C19—Mo2—H2	58 (5)
C3—W—C4	171.9 (5)	C24—Mo2—H2	134 (5)
C2—W—P1	85.0 (3)	C25—Mo2—H2	150 (5)
C1—W—P1	169.5 (4)	C22—Mo2—H2	114 (5)
C3—W—P1	90.6 (3)	C26—Mo2—H2	118 (5)
C4—W—P1	85.4 (4)	C23—Mo2—H2	81 (5)
C2—W—P2	169.8 (3)	P2—Mo2—H2	67 (5)
C1—W—P2	85.4 (4)	W—Mo2—H2	94 (5)
C3—W—P2	86.1 (3)	C5—P1—C6	94.1 (6)
C4—W—P2	88.2 (3)	C5—P1—Mo1	107.4 (4)
P1—W—P2	105.11 (9)	C6—P1—Mo1	108.1 (4)
C2—W—Mo2	146.7 (3)	C5—P1—W	114.1 (4)
C1—W—Mo2	79.9 (3)	C6—P1—W	106.0 (5)
C3—W—Mo2	114.3 (3)	Mo1—P1—W	123.08 (11)
C4—W—Mo2	60.7 (3)	C7—P2—C8	93.6 (6)
P1—W—Mo2	108.69 (6)	C7—P2—Mo2	107.7 (4)
P2—W—Mo2	28.81 (7)	C8—P2—Mo2	108.4 (4)
C2—W—Mo1	81.4 (3)	C7—P2—W	114.3 (4)
C1—W—Mo1	149.3 (4)	C8—P2—W	106.9 (4)
C3—W—Mo1	63.2 (3)	Mo2—P2—W	121.97 (12)
C4—W—Mo1	113.5 (4)	O1—C1—W	173.1 (11)
P1—W—Mo1	28.31 (6)	O2—C2—W	175.3 (10)
P2—W—Mo1	108.02 (7)	O3—C3—W	179.6 (10)
Mo2—W—Mo1	124.79 (2)	O4—C4—W	176.3 (12)
C16—Mo1—C12	99.8 (5)	P1—C5—H5A	109.5
C16—Mo1—C15	35.1 (5)	P1—C5—H5B	109.5
C12—Mo1—C15	102.1 (5)	H5A—C5—H5B	109.5
C16—Mo1—C17	36.4 (5)	P1—C5—H5C	109.5
C12—Mo1—C17	127.7 (5)	H5A—C5—H5C	109.5
C15—Mo1—C17	60.3 (6)	H5B—C5—H5C	109.5
C16—Mo1—C13	130.5 (5)	P1—C6—H6A	109.5
C12—Mo1—C13	35.5 (4)	P1—C6—H6B	109.5
C15—Mo1—C13	137.1 (5)	H6A—C6—H6B	109.5
C17—Mo1—C13	140.9 (5)	P1—C6—H6C	109.5
C16—Mo1—C11	98.6 (6)	H6A—C6—H6C	109.5
C12—Mo1—C11	36.4 (4)	H6B—C6—H6C	109.5
C15—Mo1—C11	80.8 (6)	P2—C7—H7A	109.5
C17—Mo1—C11	134.9 (6)	P2—C7—H7B	109.5
C13—Mo1—C11	59.7 (5)	H7A—C7—H7B	109.5
C16—Mo1—C14	59.4 (5)	P2—C7—H7C	109.5
C12—Mo1—C14	133.6 (6)	H7A—C7—H7C	109.5
C15—Mo1—C14	36.4 (5)	H7B—C7—H7C	109.5
C17—Mo1—C14	60.3 (6)	P2—C8—H8A	109.5
C13—Mo1—C14	157.9 (6)	P2—C8—H8B	109.5
C11—Mo1—C14	101.6 (6)	H8A—C8—H8B	109.5
C16—Mo1—C10	128.2 (6)	P2—C8—H8C	109.5
C12—Mo1—C10	59.3 (5)	H8A—C8—H8C	109.5
C15—Mo1—C10	98.7 (6)	H8B—C8—H8C	109.5
C17—Mo1—C10	158.0 (6)	C10—C9—C13	107.5 (13)
C13—Mo1—C10	58.8 (5)	C10—C9—Mo1	72.0 (8)
C11—Mo1—C10	35.4 (4)	C13—C9—Mo1	70.1 (7)
C14—Mo1—C10	99.2 (6)	C10—C9—H9	126.2
C16—Mo1—C9	156.8 (6)	C13—C9—H9	126.2
C12—Mo1—C9	59.2 (5)	Mo1—C9—H9	123.3
C15—Mo1—C9	133.3 (6)	C9—C10—C11	109.2 (13)
C17—Mo1—C9	165.7 (6)	C9—C10—Mo1	73.3 (8)
C13—Mo1—C9	35.6 (4)	C11—C10—Mo1	70.9 (8)
C11—Mo1—C9	58.9 (5)	C9—C10—H10	125.4
C14—Mo1—C9	126.3 (6)	C11—C10—H10	125.4
C10—Mo1—C9	34.6 (5)	Mo1—C10—H10	122.0
C16—Mo1—C18	57.9 (5)	C10—C11—C12	106.6 (12)
C12—Mo1—C18	157.3 (5)	C10—C11—Mo1	73.7 (8)
C15—Mo1—C18	57.7 (5)	C12—C11—Mo1	70.2 (7)
C17—Mo1—C18	35.9 (5)	C10—C11—H11	126.7
C13—Mo1—C18	165.0 (5)	C12—C11—H11	126.7
C11—Mo1—C18	134.8 (6)	Mo1—C11—H11	121.3
C14—Mo1—C18	33.9 (5)	C13—C12—C11	108.7 (12)
C10—Mo1—C18	128.9 (6)	C13—C12—Mo1	73.8 (7)
C9—Mo1—C18	141.4 (5)	C11—C12—Mo1	73.5 (8)
C16—Mo1—P1	126.6 (5)	C13—C12—H12	125.6
C12—Mo1—P1	123.5 (4)	C11—C12—H12	125.6
C15—Mo1—P1	134.3 (4)	Mo1—C12—H12	118.9
C17—Mo1—P1	90.2 (4)	C12—C13—C9	107.9 (12)
C13—Mo1—P1	88.1 (4)	C12—C13—Mo1	70.6 (7)
C11—Mo1—P1	134.8 (4)	C9—C13—Mo1	74.3 (8)
C14—Mo1—P1	99.8 (4)	C12—C13—H13	126.0
C10—Mo1—P1	102.0 (4)	C9—C13—H13	126.0
C9—Mo1—P1	76.4 (4)	Mo1—C13—H13	120.9
C18—Mo1—P1	77.8 (4)	C18—C14—C15	106.1 (15)
C16—Mo1—W	128.1 (4)	C18—C14—Mo1	74.5 (9)
C12—Mo1—W	132.1 (3)	C15—C14—Mo1	70.4 (7)
C15—Mo1—W	115.6 (4)	C18—C14—H14	126.9
C17—Mo1—W	97.3 (4)	C15—C14—H14	126.9
C13—Mo1—W	99.7 (3)	Mo1—C14—H14	120.1
C11—Mo1—W	121.0 (3)	C16—C15—C14	107.9 (15)
C14—Mo1—W	79.4 (4)	C16—C15—Mo1	71.6 (7)
C10—Mo1—W	85.7 (3)	C14—C15—Mo1	73.3 (7)
C9—Mo1—W	73.4 (4)	C16—C15—H15	126.0
C18—Mo1—W	70.2 (4)	C14—C15—H15	126.0
P1—Mo1—W	28.61 (6)	Mo1—C15—H15	120.8
C16—Mo1—H1	84 (3)	C15—C16—C17	110.9 (14)
C12—Mo1—H1	83 (3)	C15—C16—Mo1	73.3 (8)
C15—Mo1—H1	119 (3)	C17—C16—Mo1	73.4 (7)
C17—Mo1—H1	69 (3)	C15—C16—H16	124.6
C13—Mo1—H1	73 (3)	C17—C16—H16	124.6
C11—Mo1—H1	119 (3)	Mo1—C16—H16	120.4
C14—Mo1—H1	129 (3)	C16—C17—C18	102.9 (15)
C10—Mo1—H1	132 (3)	C16—C17—Mo1	70.3 (8)
C9—Mo1—H1	102 (3)	C18—C17—Mo1	74.1 (8)
C18—Mo1—H1	98 (3)	C16—C17—H17	128.6
P1—Mo1—H1	73 (3)	C18—C17—H17	128.6
W—Mo1—H1	102 (3)	Mo1—C17—H17	119.4
C20—Mo2—C28	100.4 (4)	C14—C18—C17	111.9 (15)
C20—Mo2—C21	36.0 (5)	C14—C18—Mo1	71.6 (8)
C28—Mo2—C21	103.2 (5)	C17—C18—Mo1	69.9 (8)
C20—Mo2—C27	133.2 (5)	C14—C18—H18	124.0
C28—Mo2—C27	35.9 (4)	C17—C18—H18	124.1
C21—Mo2—C27	137.4 (5)	Mo1—C18—H18	126.1
C20—Mo2—C19	36.2 (4)	C23—C19—C20	108.0 (13)
C28—Mo2—C19	129.4 (5)	C23—C19—Mo2	74.5 (7)
C21—Mo2—C19	59.4 (5)	C20—C19—Mo2	69.5 (6)
C27—Mo2—C19	146.1 (5)	C23—C19—H19	126.0
C20—Mo2—C24	95.7 (4)	C20—C19—H19	126.0
C28—Mo2—C24	35.7 (4)	Mo2—C19—H19	121.8
C21—Mo2—C24	79.0 (5)	C21—C20—C19	108.1 (13)
C27—Mo2—C24	59.6 (4)	C21—C20—Mo2	73.9 (7)
C19—Mo2—C24	131.8 (4)	C19—C20—Mo2	74.4 (6)
C20—Mo2—C25	122.8 (5)	C21—C20—H20	126.0
C28—Mo2—C25	59.4 (4)	C19—C20—H20	126.0
C21—Mo2—C25	92.8 (5)	Mo2—C20—H20	117.7
C27—Mo2—C25	59.6 (4)	C20—C21—C22	107.5 (12)
C19—Mo2—C25	151.4 (5)	C20—C21—Mo2	70.0 (7)
C24—Mo2—C25	35.4 (4)	C22—C21—Mo2	73.6 (7)
C20—Mo2—C22	60.2 (5)	C20—C21—H21	126.3
C28—Mo2—C22	134.9 (5)	C22—C21—H21	126.3
C21—Mo2—C22	36.4 (4)	Mo2—C21—H21	121.8
C27—Mo2—C22	154.8 (4)	C23—C22—C21	106.9 (12)
C19—Mo2—C22	58.7 (5)	C23—C22—Mo2	73.3 (7)
C24—Mo2—C22	101.9 (5)	C21—C22—Mo2	69.9 (7)
C25—Mo2—C22	95.3 (5)	C23—C22—H22	126.6
C20—Mo2—C26	154.4 (4)	C21—C22—H22	126.6
C28—Mo2—C26	59.3 (4)	Mo2—C22—H22	122.0
C21—Mo2—C26	127.8 (5)	C22—C23—C19	109.5 (11)
C27—Mo2—C26	36.0 (4)	C22—C23—Mo2	72.3 (7)
C19—Mo2—C26	169.4 (4)	C19—C23—Mo2	70.6 (7)
C24—Mo2—C26	58.7 (4)	C22—C23—H23	125.2
C25—Mo2—C26	35.1 (4)	C19—C23—H23	125.2
C22—Mo2—C26	121.2 (5)	Mo2—C23—H23	123.5
C20—Mo2—C23	59.3 (4)	C28—C24—C25	108.1 (11)
C28—Mo2—C23	159.4 (4)	C28—C24—Mo2	70.3 (7)
C21—Mo2—C23	58.8 (5)	C25—C24—Mo2	73.2 (7)
C27—Mo2—C23	163.7 (4)	C28—C24—H24	126.0
C19—Mo2—C23	34.9 (4)	C25—C24—H24	126.0
C24—Mo2—C23	135.2 (5)	Mo2—C24—H24	122.2
C25—Mo2—C23	126.4 (5)	C26—C25—C24	107.9 (11)
C22—Mo2—C23	34.4 (4)	C26—C25—Mo2	72.9 (7)
C26—Mo2—C23	138.5 (4)	C24—C25—Mo2	71.4 (7)
C20—Mo2—P2	128.1 (3)	C26—C25—H25	126.0
C28—Mo2—P2	122.3 (3)	C24—C25—H25	126.0
C21—Mo2—P2	134.1 (4)	Mo2—C25—H25	121.4
C27—Mo2—P2	86.7 (3)	C25—C26—C27	108.2 (11)
C19—Mo2—P2	92.0 (3)	C25—C26—Mo2	72.1 (7)
C24—Mo2—P2	136.1 (3)	C27—C26—Mo2	70.5 (6)
C25—Mo2—P2	104.8 (3)	C25—C26—H26	125.9
C22—Mo2—P2	99.0 (3)	C27—C26—H26	125.9
C26—Mo2—P2	77.5 (3)	Mo2—C26—H26	123.2
C23—Mo2—P2	77.1 (3)	C28—C27—C26	106.6 (11)
C20—Mo2—W	128.6 (3)	C28—C27—Mo2	70.4 (7)
C28—Mo2—W	130.9 (3)	C26—C27—Mo2	73.6 (7)
C21—Mo2—W	113.9 (4)	C28—C27—H27	126.7
C27—Mo2—W	97.4 (3)	C26—C27—H27	126.7
C19—Mo2—W	97.7 (3)	Mo2—C27—H27	121.1
C24—Mo2—W	122.4 (3)	C24—C28—C27	109.2 (11)
C25—Mo2—W	87.0 (3)	C24—C28—Mo2	74.0 (7)
C22—Mo2—W	77.8 (3)	C27—C28—Mo2	73.7 (7)
C26—Mo2—W	72.5 (3)	C24—C28—H28	125.4
C23—Mo2—W	69.3 (3)	C27—C28—H28	125.4
P2—Mo2—W	29.22 (7)	Mo2—C28—H28	118.7