Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536802004865/cv6099sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536802004865/cv6099Isup2.hkl |
CCDC reference: 183766
Data collection: CAD-4 EXPRESS (Enraf-Nonius, 1992); cell refinement: CAD-4 EXPRESS; data reduction: PROCESS in MolEN (Fair, 1990); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.
[Mo2WH2(C5H5)4(C2H6P)2(CO)4] | F(000) = 1688 |
Mr = 872.21 | Dx = 1.993 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2yn | Cell parameters from 25 reflections |
a = 15.342 (5) Å | θ = 7.8–14.2° |
b = 17.087 (2) Å | µ = 4.94 mm−1 |
c = 11.274 (2) Å | T = 293 K |
β = 100.40 (2)° | Irregular, yellow |
V = 2907.0 (11) Å3 | 0.2 × 0.10 × 0.08 mm |
Z = 4 |
Enraf-Nonius CAD-4 diffractometer | 2986 reflections with I > 2σ(I) |
Radiation source: fine-focus sealed tube | Rint = 0.049 |
Graphite monochromator | θmax = 26.0°, θmin = 1.8° |
ω scans | h = 0→18 |
Absorption correction: empirical (using intensity measurements) (DIFABS; Walker & Stuart, 1983) | k = 0→21 |
Tmin = 0.595, Tmax = 0.674 | l = −13→13 |
5899 measured reflections | 3 standard reflections every 120 min |
5683 independent reflections | intensity decay: −4.1% |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.042 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.084 | H-atom parameters constrained |
S = 1.00 | w = 1/[σ2(Fo2) + (0.0466P)2] where P = (Fo2 + 2Fc2)/3 |
5683 reflections | (Δ/σ)max = 0.001 |
342 parameters | Δρmax = 1.43 e Å−3 |
0 restraints | Δρmin = −1.46 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
x | y | z | Uiso*/Ueq | ||
W | 0.28109 (3) | 0.20651 (3) | 0.40935 (4) | 0.03317 (13) | |
Mo1 | 0.37836 (7) | 0.11592 (6) | 0.79222 (8) | 0.0369 (2) | |
Mo2 | 0.42308 (7) | 0.38935 (5) | 0.22112 (8) | 0.0336 (2) | |
P1 | 0.3234 (2) | 0.2277 (2) | 0.6423 (2) | 0.0353 (7) | |
P2 | 0.4191 (2) | 0.2542 (2) | 0.3228 (2) | 0.0338 (7) | |
C1 | 0.2278 (9) | 0.1853 (7) | 0.2403 (12) | 0.057 (4) | |
C2 | 0.1684 (9) | 0.1692 (6) | 0.4437 (10) | 0.042 (3) | |
C3 | 0.3401 (8) | 0.1007 (8) | 0.4251 (10) | 0.049 (3) | |
C4 | 0.2390 (8) | 0.3187 (6) | 0.4036 (11) | 0.046 (3) | |
O1 | 0.1897 (8) | 0.1687 (7) | 0.1449 (9) | 0.095 (4) | |
O2 | 0.0979 (6) | 0.1472 (5) | 0.4560 (8) | 0.060 (2) | |
O3 | 0.3742 (7) | 0.0399 (5) | 0.4335 (9) | 0.077 (3) | |
O4 | 0.2183 (6) | 0.3826 (5) | 0.4062 (9) | 0.070 (3) | |
C5 | 0.3962 (9) | 0.3136 (6) | 0.6866 (11) | 0.059 (4) | |
H5A | 0.4542 | 0.3031 | 0.6699 | 0.077* | |
H5B | 0.4001 | 0.3235 | 0.7712 | 0.077* | |
H5C | 0.3718 | 0.3587 | 0.6416 | 0.077* | |
C6 | 0.2249 (9) | 0.2734 (8) | 0.6890 (13) | 0.072 (4) | |
H6A | 0.1759 | 0.2377 | 0.6738 | 0.093* | |
H6B | 0.2099 | 0.3207 | 0.6439 | 0.093* | |
H6C | 0.2382 | 0.2855 | 0.7735 | 0.093* | |
C7 | 0.5258 (8) | 0.2404 (7) | 0.4260 (10) | 0.054 (3) | |
H7A | 0.5294 | 0.2757 | 0.4929 | 0.070* | |
H7B | 0.5736 | 0.2509 | 0.3837 | 0.070* | |
H7C | 0.5301 | 0.1875 | 0.4550 | 0.070* | |
C8 | 0.4429 (9) | 0.1781 (6) | 0.2161 (11) | 0.057 (4) | |
H8A | 0.3938 | 0.1741 | 0.1502 | 0.073* | |
H8B | 0.4519 | 0.1287 | 0.2570 | 0.073* | |
H8C | 0.4954 | 0.1921 | 0.1857 | 0.073* | |
C9 | 0.5044 (9) | 0.1505 (9) | 0.7150 (13) | 0.067 (4) | |
H9 | 0.5025 | 0.1811 | 0.6463 | 0.087* | |
C10 | 0.5004 (9) | 0.0696 (9) | 0.7186 (12) | 0.067 (4) | |
H10 | 0.4946 | 0.0366 | 0.6520 | 0.087* | |
C11 | 0.5064 (10) | 0.0453 (8) | 0.8386 (12) | 0.067 (4) | |
H11 | 0.5062 | −0.0060 | 0.8661 | 0.087* | |
C12 | 0.5129 (8) | 0.1140 (9) | 0.9095 (12) | 0.061 (4) | |
H12 | 0.5171 | 0.1157 | 0.9928 | 0.079* | |
C13 | 0.5120 (8) | 0.1781 (8) | 0.8347 (12) | 0.055 (3) | |
H13 | 0.5157 | 0.2303 | 0.8587 | 0.071* | |
C14 | 0.2776 (11) | 0.0202 (9) | 0.7184 (13) | 0.075 (5) | |
H14 | 0.2820 | −0.0056 | 0.6471 | 0.097* | |
C15 | 0.3210 (10) | −0.0001 (8) | 0.8368 (15) | 0.077 (5) | |
H15 | 0.3574 | −0.0433 | 0.8577 | 0.100* | |
C16 | 0.2999 (11) | 0.0549 (10) | 0.9141 (13) | 0.079 (5) | |
H16 | 0.3198 | 0.0545 | 0.9971 | 0.103* | |
C17 | 0.2439 (9) | 0.1126 (10) | 0.8515 (14) | 0.073 (4) | |
H17 | 0.2222 | 0.1578 | 0.8818 | 0.095* | |
C18 | 0.2288 (9) | 0.0846 (10) | 0.7305 (15) | 0.072 (5) | |
H18 | 0.1900 | 0.1078 | 0.6674 | 0.094* | |
C19 | 0.3964 (10) | 0.3349 (8) | 0.0322 (10) | 0.057 (4) | |
H19 | 0.4341 | 0.2977 | 0.0087 | 0.074* | |
C20 | 0.4054 (11) | 0.4164 (8) | 0.0248 (10) | 0.060 (4) | |
H20 | 0.4511 | 0.4427 | −0.0024 | 0.078* | |
C21 | 0.3340 (11) | 0.4511 (8) | 0.0655 (11) | 0.068 (4) | |
H21 | 0.3222 | 0.5045 | 0.0676 | 0.088* | |
C22 | 0.2816 (9) | 0.3892 (8) | 0.1039 (10) | 0.054 (3) | |
H22 | 0.2310 | 0.3950 | 0.1377 | 0.070* | |
C23 | 0.3210 (9) | 0.3195 (7) | 0.0809 (10) | 0.051 (3) | |
H23 | 0.3003 | 0.2699 | 0.0957 | 0.066* | |
C24 | 0.4375 (9) | 0.5171 (7) | 0.2845 (10) | 0.050 (3) | |
H24 | 0.4169 | 0.5587 | 0.2339 | 0.066* | |
C25 | 0.3900 (9) | 0.4782 (7) | 0.3622 (12) | 0.055 (3) | |
H25 | 0.3318 | 0.4883 | 0.3702 | 0.071* | |
C26 | 0.4458 (9) | 0.4214 (7) | 0.4253 (9) | 0.048 (3) | |
H26 | 0.4315 | 0.3880 | 0.4841 | 0.063* | |
C27 | 0.5283 (8) | 0.4236 (7) | 0.3838 (10) | 0.048 (3) | |
H27 | 0.5774 | 0.3920 | 0.4097 | 0.062* | |
C28 | 0.5208 (9) | 0.4826 (7) | 0.2964 (11) | 0.050 (3) | |
H28 | 0.5647 | 0.4966 | 0.2532 | 0.065* | |
H1 | 0.365 (6) | 0.192 (5) | 0.872 (7) | 0.03 (2)* | |
H2 | 0.488 (9) | 0.329 (7) | 0.179 (12) | 0.10 (5)* |
U11 | U22 | U33 | U12 | U13 | U23 | |
W | 0.0314 (2) | 0.0343 (2) | 0.0334 (2) | −0.0009 (3) | 0.0049 (2) | −0.0012 (2) |
Mo1 | 0.0404 (6) | 0.0368 (5) | 0.0328 (5) | −0.0031 (5) | 0.0047 (5) | 0.0010 (4) |
Mo2 | 0.0386 (6) | 0.0353 (5) | 0.0270 (5) | −0.0033 (5) | 0.0061 (4) | −0.0034 (4) |
P1 | 0.039 (2) | 0.035 (2) | 0.0319 (15) | −0.0005 (13) | 0.0079 (14) | −0.0016 (12) |
P2 | 0.035 (2) | 0.036 (2) | 0.032 (2) | 0.0006 (14) | 0.0082 (14) | −0.0037 (13) |
C1 | 0.069 (10) | 0.058 (9) | 0.047 (8) | −0.029 (7) | 0.022 (8) | −0.004 (6) |
C2 | 0.054 (9) | 0.032 (6) | 0.037 (7) | 0.004 (6) | 0.003 (6) | −0.005 (5) |
C3 | 0.047 (8) | 0.066 (9) | 0.038 (7) | −0.015 (7) | 0.016 (6) | −0.017 (6) |
C4 | 0.045 (8) | 0.028 (6) | 0.072 (9) | −0.007 (5) | 0.031 (7) | −0.002 (6) |
O1 | 0.105 (9) | 0.123 (9) | 0.047 (6) | −0.053 (7) | −0.014 (6) | −0.001 (6) |
O2 | 0.040 (6) | 0.071 (6) | 0.069 (6) | −0.008 (5) | 0.013 (5) | −0.004 (5) |
O3 | 0.087 (8) | 0.040 (6) | 0.109 (8) | 0.024 (5) | 0.030 (7) | −0.004 (5) |
O4 | 0.053 (6) | 0.039 (5) | 0.118 (8) | 0.007 (5) | 0.020 (6) | 0.013 (5) |
C5 | 0.099 (11) | 0.032 (7) | 0.046 (7) | −0.023 (7) | 0.011 (8) | −0.008 (5) |
C6 | 0.074 (11) | 0.075 (10) | 0.075 (10) | 0.024 (8) | 0.037 (9) | 0.003 (8) |
C7 | 0.050 (8) | 0.066 (8) | 0.046 (7) | 0.000 (7) | 0.010 (7) | 0.021 (6) |
C8 | 0.076 (10) | 0.040 (7) | 0.060 (8) | 0.001 (7) | 0.031 (8) | −0.018 (6) |
C9 | 0.049 (9) | 0.092 (12) | 0.067 (10) | 0.018 (8) | 0.026 (8) | 0.012 (9) |
C10 | 0.063 (10) | 0.076 (11) | 0.058 (9) | 0.032 (9) | 0.006 (8) | −0.010 (8) |
C11 | 0.077 (11) | 0.067 (10) | 0.054 (9) | 0.009 (8) | 0.004 (8) | 0.008 (8) |
C12 | 0.034 (8) | 0.101 (12) | 0.042 (7) | 0.005 (8) | −0.007 (6) | 0.020 (8) |
C13 | 0.028 (7) | 0.062 (8) | 0.071 (9) | −0.012 (6) | 0.002 (7) | −0.011 (7) |
C14 | 0.089 (13) | 0.072 (11) | 0.055 (9) | −0.034 (10) | −0.008 (9) | 0.011 (8) |
C15 | 0.081 (12) | 0.039 (8) | 0.093 (12) | −0.031 (8) | −0.032 (10) | 0.028 (8) |
C16 | 0.099 (14) | 0.085 (11) | 0.053 (9) | −0.058 (11) | 0.014 (10) | 0.015 (9) |
C17 | 0.050 (10) | 0.100 (13) | 0.072 (11) | −0.023 (9) | 0.021 (8) | 0.004 (10) |
C18 | 0.037 (9) | 0.085 (12) | 0.088 (12) | −0.022 (8) | −0.005 (8) | 0.040 (10) |
C19 | 0.076 (11) | 0.069 (9) | 0.024 (6) | −0.008 (8) | 0.003 (7) | −0.017 (6) |
C20 | 0.092 (12) | 0.055 (8) | 0.028 (7) | −0.029 (8) | 0.000 (7) | 0.005 (6) |
C21 | 0.095 (12) | 0.054 (9) | 0.044 (8) | 0.021 (9) | −0.014 (8) | 0.003 (7) |
C22 | 0.043 (8) | 0.069 (9) | 0.041 (7) | 0.005 (7) | −0.014 (6) | 0.002 (7) |
C23 | 0.066 (10) | 0.049 (8) | 0.036 (7) | −0.018 (7) | 0.000 (7) | 0.008 (6) |
C24 | 0.067 (10) | 0.036 (7) | 0.044 (7) | −0.003 (7) | −0.001 (7) | −0.012 (6) |
C25 | 0.043 (8) | 0.046 (8) | 0.075 (9) | −0.005 (7) | 0.013 (7) | −0.020 (7) |
C26 | 0.069 (10) | 0.051 (8) | 0.025 (6) | −0.021 (7) | 0.012 (6) | −0.009 (5) |
C27 | 0.046 (8) | 0.053 (8) | 0.041 (7) | 0.004 (7) | −0.003 (6) | −0.010 (6) |
C28 | 0.051 (9) | 0.052 (8) | 0.047 (8) | −0.013 (7) | 0.008 (7) | −0.006 (6) |
W—C2 | 1.946 (13) | C7—H7A | 0.96 |
W—C1 | 1.967 (14) | C7—H7B | 0.96 |
W—C3 | 2.015 (14) | C7—H7C | 0.96 |
W—C4 | 2.020 (12) | C8—H8A | 0.96 |
W—P1 | 2.614 (3) | C8—H8B | 0.96 |
W—P2 | 2.617 (3) | C8—H8C | 0.96 |
W—Mo2 | 4.5474 (12) | C9—C10 | 1.39 (2) |
W—Mo1 | 4.5749 (14) | C9—C13 | 1.41 (2) |
Mo1—C16 | 2.241 (12) | C9—H9 | 0.93 |
Mo1—C12 | 2.241 (12) | C10—C11 | 1.40 (2) |
Mo1—C15 | 2.261 (12) | C10—H10 | 0.93 |
Mo1—C17 | 2.281 (13) | C11—C12 | 1.41 (2) |
Mo1—C13 | 2.282 (12) | C11—H11 | 0.93 |
Mo1—C11 | 2.284 (14) | C12—C13 | 1.38 (2) |
Mo1—C14 | 2.300 (14) | C12—H12 | 0.93 |
Mo1—C10 | 2.320 (13) | C13—H13 | 0.93 |
Mo1—C9 | 2.336 (13) | C14—C18 | 1.35 (2) |
Mo1—C18 | 2.336 (13) | C14—C15 | 1.42 (2) |
Mo1—P1 | 2.589 (3) | C14—H14 | 0.93 |
Mo1—H1 | 1.62 (8) | C15—C16 | 1.36 (2) |
Mo2—C20 | 2.229 (11) | C15—H15 | 0.93 |
Mo2—C28 | 2.248 (12) | C16—C17 | 1.41 (2) |
Mo2—C21 | 2.279 (12) | C16—H16 | 0.93 |
Mo2—C27 | 2.290 (12) | C17—C18 | 1.42 (2) |
Mo2—C19 | 2.292 (11) | C17—H17 | 0.93 |
Mo2—C24 | 2.296 (11) | C18—H18 | 0.93 |
Mo2—C25 | 2.320 (12) | C19—C23 | 1.39 (2) |
Mo2—C22 | 2.329 (12) | C19—C20 | 1.40 (2) |
Mo2—C26 | 2.330 (10) | C19—H19 | 0.93 |
Mo2—C23 | 2.341 (12) | C20—C21 | 1.39 (2) |
Mo2—P2 | 2.583 (3) | C20—H20 | 0.93 |
Mo2—H2 | 1.56 (13) | C21—C22 | 1.44 (2) |
P1—C5 | 1.857 (11) | C21—H21 | 0.93 |
P1—C6 | 1.859 (12) | C22—C23 | 1.38 (2) |
P2—C7 | 1.845 (12) | C22—H22 | 0.93 |
P2—C8 | 1.852 (10) | C23—H23 | 0.93 |
C1—O1 | 1.163 (14) | C24—C28 | 1.39 (2) |
C2—O2 | 1.178 (13) | C24—C25 | 1.40 (2) |
C3—O3 | 1.159 (14) | C24—H24 | 0.93 |
C4—O4 | 1.138 (12) | C25—C26 | 1.40 (2) |
C5—H5A | 0.96 | C25—H25 | 0.93 |
C5—H5B | 0.96 | C26—C27 | 1.43 (2) |
C5—H5C | 0.96 | C26—H26 | 0.93 |
C6—H6A | 0.96 | C27—C28 | 1.40 (2) |
C6—H6B | 0.96 | C27—H27 | 0.93 |
C6—H6C | 0.96 | C28—H28 | 0.93 |
C2—W—C1 | 84.5 (5) | C20—Mo2—H2 | 79 (5) |
C2—W—C3 | 95.1 (5) | C28—Mo2—H2 | 99 (5) |
C1—W—C3 | 91.2 (5) | C21—Mo2—H2 | 113 (5) |
C2—W—C4 | 91.5 (4) | C27—Mo2—H2 | 91 (5) |
C1—W—C4 | 94.0 (5) | C19—Mo2—H2 | 58 (5) |
C3—W—C4 | 171.9 (5) | C24—Mo2—H2 | 134 (5) |
C2—W—P1 | 85.0 (3) | C25—Mo2—H2 | 150 (5) |
C1—W—P1 | 169.5 (4) | C22—Mo2—H2 | 114 (5) |
C3—W—P1 | 90.6 (3) | C26—Mo2—H2 | 118 (5) |
C4—W—P1 | 85.4 (4) | C23—Mo2—H2 | 81 (5) |
C2—W—P2 | 169.8 (3) | P2—Mo2—H2 | 67 (5) |
C1—W—P2 | 85.4 (4) | W—Mo2—H2 | 94 (5) |
C3—W—P2 | 86.1 (3) | C5—P1—C6 | 94.1 (6) |
C4—W—P2 | 88.2 (3) | C5—P1—Mo1 | 107.4 (4) |
P1—W—P2 | 105.11 (9) | C6—P1—Mo1 | 108.1 (4) |
C2—W—Mo2 | 146.7 (3) | C5—P1—W | 114.1 (4) |
C1—W—Mo2 | 79.9 (3) | C6—P1—W | 106.0 (5) |
C3—W—Mo2 | 114.3 (3) | Mo1—P1—W | 123.08 (11) |
C4—W—Mo2 | 60.7 (3) | C7—P2—C8 | 93.6 (6) |
P1—W—Mo2 | 108.69 (6) | C7—P2—Mo2 | 107.7 (4) |
P2—W—Mo2 | 28.81 (7) | C8—P2—Mo2 | 108.4 (4) |
C2—W—Mo1 | 81.4 (3) | C7—P2—W | 114.3 (4) |
C1—W—Mo1 | 149.3 (4) | C8—P2—W | 106.9 (4) |
C3—W—Mo1 | 63.2 (3) | Mo2—P2—W | 121.97 (12) |
C4—W—Mo1 | 113.5 (4) | O1—C1—W | 173.1 (11) |
P1—W—Mo1 | 28.31 (6) | O2—C2—W | 175.3 (10) |
P2—W—Mo1 | 108.02 (7) | O3—C3—W | 179.6 (10) |
Mo2—W—Mo1 | 124.79 (2) | O4—C4—W | 176.3 (12) |
C16—Mo1—C12 | 99.8 (5) | P1—C5—H5A | 109.5 |
C16—Mo1—C15 | 35.1 (5) | P1—C5—H5B | 109.5 |
C12—Mo1—C15 | 102.1 (5) | H5A—C5—H5B | 109.5 |
C16—Mo1—C17 | 36.4 (5) | P1—C5—H5C | 109.5 |
C12—Mo1—C17 | 127.7 (5) | H5A—C5—H5C | 109.5 |
C15—Mo1—C17 | 60.3 (6) | H5B—C5—H5C | 109.5 |
C16—Mo1—C13 | 130.5 (5) | P1—C6—H6A | 109.5 |
C12—Mo1—C13 | 35.5 (4) | P1—C6—H6B | 109.5 |
C15—Mo1—C13 | 137.1 (5) | H6A—C6—H6B | 109.5 |
C17—Mo1—C13 | 140.9 (5) | P1—C6—H6C | 109.5 |
C16—Mo1—C11 | 98.6 (6) | H6A—C6—H6C | 109.5 |
C12—Mo1—C11 | 36.4 (4) | H6B—C6—H6C | 109.5 |
C15—Mo1—C11 | 80.8 (6) | P2—C7—H7A | 109.5 |
C17—Mo1—C11 | 134.9 (6) | P2—C7—H7B | 109.5 |
C13—Mo1—C11 | 59.7 (5) | H7A—C7—H7B | 109.5 |
C16—Mo1—C14 | 59.4 (5) | P2—C7—H7C | 109.5 |
C12—Mo1—C14 | 133.6 (6) | H7A—C7—H7C | 109.5 |
C15—Mo1—C14 | 36.4 (5) | H7B—C7—H7C | 109.5 |
C17—Mo1—C14 | 60.3 (6) | P2—C8—H8A | 109.5 |
C13—Mo1—C14 | 157.9 (6) | P2—C8—H8B | 109.5 |
C11—Mo1—C14 | 101.6 (6) | H8A—C8—H8B | 109.5 |
C16—Mo1—C10 | 128.2 (6) | P2—C8—H8C | 109.5 |
C12—Mo1—C10 | 59.3 (5) | H8A—C8—H8C | 109.5 |
C15—Mo1—C10 | 98.7 (6) | H8B—C8—H8C | 109.5 |
C17—Mo1—C10 | 158.0 (6) | C10—C9—C13 | 107.5 (13) |
C13—Mo1—C10 | 58.8 (5) | C10—C9—Mo1 | 72.0 (8) |
C11—Mo1—C10 | 35.4 (4) | C13—C9—Mo1 | 70.1 (7) |
C14—Mo1—C10 | 99.2 (6) | C10—C9—H9 | 126.2 |
C16—Mo1—C9 | 156.8 (6) | C13—C9—H9 | 126.2 |
C12—Mo1—C9 | 59.2 (5) | Mo1—C9—H9 | 123.3 |
C15—Mo1—C9 | 133.3 (6) | C9—C10—C11 | 109.2 (13) |
C17—Mo1—C9 | 165.7 (6) | C9—C10—Mo1 | 73.3 (8) |
C13—Mo1—C9 | 35.6 (4) | C11—C10—Mo1 | 70.9 (8) |
C11—Mo1—C9 | 58.9 (5) | C9—C10—H10 | 125.4 |
C14—Mo1—C9 | 126.3 (6) | C11—C10—H10 | 125.4 |
C10—Mo1—C9 | 34.6 (5) | Mo1—C10—H10 | 122.0 |
C16—Mo1—C18 | 57.9 (5) | C10—C11—C12 | 106.6 (12) |
C12—Mo1—C18 | 157.3 (5) | C10—C11—Mo1 | 73.7 (8) |
C15—Mo1—C18 | 57.7 (5) | C12—C11—Mo1 | 70.2 (7) |
C17—Mo1—C18 | 35.9 (5) | C10—C11—H11 | 126.7 |
C13—Mo1—C18 | 165.0 (5) | C12—C11—H11 | 126.7 |
C11—Mo1—C18 | 134.8 (6) | Mo1—C11—H11 | 121.3 |
C14—Mo1—C18 | 33.9 (5) | C13—C12—C11 | 108.7 (12) |
C10—Mo1—C18 | 128.9 (6) | C13—C12—Mo1 | 73.8 (7) |
C9—Mo1—C18 | 141.4 (5) | C11—C12—Mo1 | 73.5 (8) |
C16—Mo1—P1 | 126.6 (5) | C13—C12—H12 | 125.6 |
C12—Mo1—P1 | 123.5 (4) | C11—C12—H12 | 125.6 |
C15—Mo1—P1 | 134.3 (4) | Mo1—C12—H12 | 118.9 |
C17—Mo1—P1 | 90.2 (4) | C12—C13—C9 | 107.9 (12) |
C13—Mo1—P1 | 88.1 (4) | C12—C13—Mo1 | 70.6 (7) |
C11—Mo1—P1 | 134.8 (4) | C9—C13—Mo1 | 74.3 (8) |
C14—Mo1—P1 | 99.8 (4) | C12—C13—H13 | 126.0 |
C10—Mo1—P1 | 102.0 (4) | C9—C13—H13 | 126.0 |
C9—Mo1—P1 | 76.4 (4) | Mo1—C13—H13 | 120.9 |
C18—Mo1—P1 | 77.8 (4) | C18—C14—C15 | 106.1 (15) |
C16—Mo1—W | 128.1 (4) | C18—C14—Mo1 | 74.5 (9) |
C12—Mo1—W | 132.1 (3) | C15—C14—Mo1 | 70.4 (7) |
C15—Mo1—W | 115.6 (4) | C18—C14—H14 | 126.9 |
C17—Mo1—W | 97.3 (4) | C15—C14—H14 | 126.9 |
C13—Mo1—W | 99.7 (3) | Mo1—C14—H14 | 120.1 |
C11—Mo1—W | 121.0 (3) | C16—C15—C14 | 107.9 (15) |
C14—Mo1—W | 79.4 (4) | C16—C15—Mo1 | 71.6 (7) |
C10—Mo1—W | 85.7 (3) | C14—C15—Mo1 | 73.3 (7) |
C9—Mo1—W | 73.4 (4) | C16—C15—H15 | 126.0 |
C18—Mo1—W | 70.2 (4) | C14—C15—H15 | 126.0 |
P1—Mo1—W | 28.61 (6) | Mo1—C15—H15 | 120.8 |
C16—Mo1—H1 | 84 (3) | C15—C16—C17 | 110.9 (14) |
C12—Mo1—H1 | 83 (3) | C15—C16—Mo1 | 73.3 (8) |
C15—Mo1—H1 | 119 (3) | C17—C16—Mo1 | 73.4 (7) |
C17—Mo1—H1 | 69 (3) | C15—C16—H16 | 124.6 |
C13—Mo1—H1 | 73 (3) | C17—C16—H16 | 124.6 |
C11—Mo1—H1 | 119 (3) | Mo1—C16—H16 | 120.4 |
C14—Mo1—H1 | 129 (3) | C16—C17—C18 | 102.9 (15) |
C10—Mo1—H1 | 132 (3) | C16—C17—Mo1 | 70.3 (8) |
C9—Mo1—H1 | 102 (3) | C18—C17—Mo1 | 74.1 (8) |
C18—Mo1—H1 | 98 (3) | C16—C17—H17 | 128.6 |
P1—Mo1—H1 | 73 (3) | C18—C17—H17 | 128.6 |
W—Mo1—H1 | 102 (3) | Mo1—C17—H17 | 119.4 |
C20—Mo2—C28 | 100.4 (4) | C14—C18—C17 | 111.9 (15) |
C20—Mo2—C21 | 36.0 (5) | C14—C18—Mo1 | 71.6 (8) |
C28—Mo2—C21 | 103.2 (5) | C17—C18—Mo1 | 69.9 (8) |
C20—Mo2—C27 | 133.2 (5) | C14—C18—H18 | 124.0 |
C28—Mo2—C27 | 35.9 (4) | C17—C18—H18 | 124.1 |
C21—Mo2—C27 | 137.4 (5) | Mo1—C18—H18 | 126.1 |
C20—Mo2—C19 | 36.2 (4) | C23—C19—C20 | 108.0 (13) |
C28—Mo2—C19 | 129.4 (5) | C23—C19—Mo2 | 74.5 (7) |
C21—Mo2—C19 | 59.4 (5) | C20—C19—Mo2 | 69.5 (6) |
C27—Mo2—C19 | 146.1 (5) | C23—C19—H19 | 126.0 |
C20—Mo2—C24 | 95.7 (4) | C20—C19—H19 | 126.0 |
C28—Mo2—C24 | 35.7 (4) | Mo2—C19—H19 | 121.8 |
C21—Mo2—C24 | 79.0 (5) | C21—C20—C19 | 108.1 (13) |
C27—Mo2—C24 | 59.6 (4) | C21—C20—Mo2 | 73.9 (7) |
C19—Mo2—C24 | 131.8 (4) | C19—C20—Mo2 | 74.4 (6) |
C20—Mo2—C25 | 122.8 (5) | C21—C20—H20 | 126.0 |
C28—Mo2—C25 | 59.4 (4) | C19—C20—H20 | 126.0 |
C21—Mo2—C25 | 92.8 (5) | Mo2—C20—H20 | 117.7 |
C27—Mo2—C25 | 59.6 (4) | C20—C21—C22 | 107.5 (12) |
C19—Mo2—C25 | 151.4 (5) | C20—C21—Mo2 | 70.0 (7) |
C24—Mo2—C25 | 35.4 (4) | C22—C21—Mo2 | 73.6 (7) |
C20—Mo2—C22 | 60.2 (5) | C20—C21—H21 | 126.3 |
C28—Mo2—C22 | 134.9 (5) | C22—C21—H21 | 126.3 |
C21—Mo2—C22 | 36.4 (4) | Mo2—C21—H21 | 121.8 |
C27—Mo2—C22 | 154.8 (4) | C23—C22—C21 | 106.9 (12) |
C19—Mo2—C22 | 58.7 (5) | C23—C22—Mo2 | 73.3 (7) |
C24—Mo2—C22 | 101.9 (5) | C21—C22—Mo2 | 69.9 (7) |
C25—Mo2—C22 | 95.3 (5) | C23—C22—H22 | 126.6 |
C20—Mo2—C26 | 154.4 (4) | C21—C22—H22 | 126.6 |
C28—Mo2—C26 | 59.3 (4) | Mo2—C22—H22 | 122.0 |
C21—Mo2—C26 | 127.8 (5) | C22—C23—C19 | 109.5 (11) |
C27—Mo2—C26 | 36.0 (4) | C22—C23—Mo2 | 72.3 (7) |
C19—Mo2—C26 | 169.4 (4) | C19—C23—Mo2 | 70.6 (7) |
C24—Mo2—C26 | 58.7 (4) | C22—C23—H23 | 125.2 |
C25—Mo2—C26 | 35.1 (4) | C19—C23—H23 | 125.2 |
C22—Mo2—C26 | 121.2 (5) | Mo2—C23—H23 | 123.5 |
C20—Mo2—C23 | 59.3 (4) | C28—C24—C25 | 108.1 (11) |
C28—Mo2—C23 | 159.4 (4) | C28—C24—Mo2 | 70.3 (7) |
C21—Mo2—C23 | 58.8 (5) | C25—C24—Mo2 | 73.2 (7) |
C27—Mo2—C23 | 163.7 (4) | C28—C24—H24 | 126.0 |
C19—Mo2—C23 | 34.9 (4) | C25—C24—H24 | 126.0 |
C24—Mo2—C23 | 135.2 (5) | Mo2—C24—H24 | 122.2 |
C25—Mo2—C23 | 126.4 (5) | C26—C25—C24 | 107.9 (11) |
C22—Mo2—C23 | 34.4 (4) | C26—C25—Mo2 | 72.9 (7) |
C26—Mo2—C23 | 138.5 (4) | C24—C25—Mo2 | 71.4 (7) |
C20—Mo2—P2 | 128.1 (3) | C26—C25—H25 | 126.0 |
C28—Mo2—P2 | 122.3 (3) | C24—C25—H25 | 126.0 |
C21—Mo2—P2 | 134.1 (4) | Mo2—C25—H25 | 121.4 |
C27—Mo2—P2 | 86.7 (3) | C25—C26—C27 | 108.2 (11) |
C19—Mo2—P2 | 92.0 (3) | C25—C26—Mo2 | 72.1 (7) |
C24—Mo2—P2 | 136.1 (3) | C27—C26—Mo2 | 70.5 (6) |
C25—Mo2—P2 | 104.8 (3) | C25—C26—H26 | 125.9 |
C22—Mo2—P2 | 99.0 (3) | C27—C26—H26 | 125.9 |
C26—Mo2—P2 | 77.5 (3) | Mo2—C26—H26 | 123.2 |
C23—Mo2—P2 | 77.1 (3) | C28—C27—C26 | 106.6 (11) |
C20—Mo2—W | 128.6 (3) | C28—C27—Mo2 | 70.4 (7) |
C28—Mo2—W | 130.9 (3) | C26—C27—Mo2 | 73.6 (7) |
C21—Mo2—W | 113.9 (4) | C28—C27—H27 | 126.7 |
C27—Mo2—W | 97.4 (3) | C26—C27—H27 | 126.7 |
C19—Mo2—W | 97.7 (3) | Mo2—C27—H27 | 121.1 |
C24—Mo2—W | 122.4 (3) | C24—C28—C27 | 109.2 (11) |
C25—Mo2—W | 87.0 (3) | C24—C28—Mo2 | 74.0 (7) |
C22—Mo2—W | 77.8 (3) | C27—C28—Mo2 | 73.7 (7) |
C26—Mo2—W | 72.5 (3) | C24—C28—H28 | 125.4 |
C23—Mo2—W | 69.3 (3) | C27—C28—H28 | 125.4 |
P2—Mo2—W | 29.22 (7) | Mo2—C28—H28 | 118.7 |