The title compound, (C5H6N)[Mn(C7H4O2)2(C5H5N)(H2O)], is a mononuclear manganese complex in which the Mn atom is six-coordinated by two carboxylate O atoms and two hydroxy O atoms of two salicylates, one O atom of water and one N atom of pyridine.
Supporting information
CCDC reference: 650591
Key indicators
- Single-crystal X-ray study
- T = 295 K
- Mean (C-C)= 0.004 Å
- R factor = 0.048
- wR factor = 0.122
- Data-to-parameter ratio = 15.7
checkCIF/PLATON results
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Data collection: CrystalClear (Rigaku, 2000); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1997); software used to prepare material for publication: SHELXTL.
Pyridinium aquapyridinebis(salicylato-
κ2O,
O')manganese(III)
top
Crystal data top
(C5H6N)[Mn(C7H4O2)2(C5H5N)(H2O)] | F(000) = 1040 |
Mr = 504.37 | Dx = 1.533 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P2yn | Cell parameters from 4113 reflections |
a = 12.0499 (9) Å | θ = 2.2–27.5° |
b = 11.3964 (7) Å | µ = 0.65 mm−1 |
c = 16.4446 (11) Å | T = 295 K |
β = 104.579 (2)° | Prism, dark brown |
V = 2185.5 (3) Å3 | 0.3 × 0.2 × 0.1 mm |
Z = 4 | |
Data collection top
Rigaku MERCURY CCD diffractometer | 5015 independent reflections |
Radiation source: fine-focus sealed tube | 3770 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.040 |
ω scans | θmax = 27.5°, θmin = 2.4° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −12→15 |
Tmin = 0.808, Tmax = 1.000 | k = −14→12 |
16400 measured reflections | l = −21→19 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.048 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.122 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.08 | w = 1/[σ2(Fo2) + (0.0591P)2 + 0.2983P] where P = (Fo2 + 2Fc2)/3 |
5015 reflections | (Δ/σ)max = 0.001 |
319 parameters | Δρmax = 0.35 e Å−3 |
0 restraints | Δρmin = −0.35 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Mn | 0.73667 (3) | 0.81871 (3) | 0.98464 (2) | 0.03360 (13) | |
O1 | 0.78748 (15) | 0.82648 (15) | 1.10238 (10) | 0.0451 (4) | |
O2 | 0.89258 (14) | 0.81669 (13) | 0.97417 (10) | 0.0382 (4) | |
O3 | 1.07537 (14) | 0.85439 (15) | 1.00196 (11) | 0.0459 (4) | |
O4 | 0.68969 (14) | 0.80995 (14) | 0.86739 (10) | 0.0386 (4) | |
O5 | 0.58054 (14) | 0.81959 (14) | 0.99278 (11) | 0.0419 (4) | |
O6 | 0.39422 (16) | 0.84936 (16) | 0.95298 (14) | 0.0571 (5) | |
O7 | 0.73164 (18) | 1.01470 (17) | 0.97321 (13) | 0.0538 (5) | |
C1 | 0.8891 (2) | 0.8647 (2) | 1.14617 (14) | 0.0363 (5) | |
C2 | 0.9006 (2) | 0.8895 (2) | 1.23191 (15) | 0.0461 (6) | |
H2A | 0.8366 | 0.8795 | 1.2551 | 0.055* | |
C3 | 1.0026 (3) | 0.9280 (2) | 1.28206 (15) | 0.0540 (7) | |
H3A | 1.0085 | 0.9426 | 1.3399 | 0.065* | |
C4 | 1.0973 (3) | 0.9459 (2) | 1.25041 (16) | 0.0547 (7) | |
H4A | 1.1673 | 0.9741 | 1.2856 | 0.066* | |
C5 | 1.0881 (2) | 0.9221 (2) | 1.16692 (16) | 0.0438 (6) | |
H5A | 1.1528 | 0.9338 | 1.1447 | 0.053* | |
C6 | 0.9853 (2) | 0.88076 (18) | 1.11365 (14) | 0.0342 (5) | |
C7 | 0.98561 (19) | 0.85043 (18) | 1.02654 (14) | 0.0326 (5) | |
C8 | 0.5944 (2) | 0.8604 (2) | 0.82185 (14) | 0.0362 (5) | |
C9 | 0.5906 (2) | 0.8885 (2) | 0.73793 (15) | 0.0487 (6) | |
H9A | 0.6552 | 0.8725 | 0.7164 | 0.058* | |
C10 | 0.4947 (3) | 0.9386 (3) | 0.68677 (18) | 0.0612 (8) | |
H10A | 0.4933 | 0.9557 | 0.6300 | 0.073* | |
C11 | 0.4000 (3) | 0.9648 (3) | 0.71645 (18) | 0.0620 (8) | |
H11A | 0.3346 | 1.0012 | 0.6809 | 0.074* | |
C12 | 0.4019 (2) | 0.9376 (2) | 0.79782 (18) | 0.0516 (7) | |
H12A | 0.3367 | 0.9549 | 0.8183 | 0.062* | |
C13 | 0.4978 (2) | 0.88459 (19) | 0.85187 (15) | 0.0375 (5) | |
C14 | 0.4893 (2) | 0.85055 (19) | 0.93675 (16) | 0.0394 (6) | |
C15 | 0.6636 (2) | 0.5543 (2) | 1.02244 (17) | 0.0489 (6) | |
H15A | 0.6089 | 0.5981 | 1.0425 | 0.059* | |
C16 | 0.6601 (3) | 0.4340 (2) | 1.02669 (18) | 0.0562 (7) | |
H16A | 0.6038 | 0.3960 | 1.0488 | 0.067* | |
C17 | 0.7390 (3) | 0.3696 (3) | 0.99850 (17) | 0.0556 (7) | |
H17A | 0.7387 | 0.2863 | 1.0006 | 0.067* | |
C18 | 0.8181 (3) | 0.4285 (2) | 0.96733 (18) | 0.0571 (7) | |
H18A | 0.8743 | 0.3867 | 0.9477 | 0.069* | |
C19 | 0.8152 (2) | 0.5494 (2) | 0.96471 (16) | 0.0497 (7) | |
H19A | 0.8703 | 0.5893 | 0.9424 | 0.060* | |
C20 | 1.1134 (3) | 0.7948 (3) | 0.8006 (2) | 0.0605 (8) | |
H20A | 1.1857 | 0.8196 | 0.8342 | 0.073* | |
C21 | 1.1028 (3) | 0.7619 (3) | 0.7205 (2) | 0.0658 (9) | |
H21A | 1.1670 | 0.7656 | 0.6969 | 0.079* | |
C22 | 0.9997 (3) | 0.7233 (3) | 0.67344 (18) | 0.0636 (9) | |
H22A | 0.9922 | 0.6979 | 0.6173 | 0.076* | |
C23 | 0.9066 (3) | 0.7210 (3) | 0.70732 (19) | 0.0667 (9) | |
H23A | 0.8342 | 0.6941 | 0.6751 | 0.080* | |
C24 | 0.9201 (3) | 0.7585 (3) | 0.78877 (19) | 0.0597 (8) | |
H24A | 0.8565 | 0.7597 | 0.8131 | 0.072* | |
N1 | 0.73941 (17) | 0.61282 (18) | 0.99179 (12) | 0.0402 (5) | |
N2 | 1.0221 (2) | 0.7927 (2) | 0.83277 (16) | 0.0541 (6) | |
H7B | 0.799 (3) | 1.054 (3) | 0.9837 (19) | 0.074 (10)* | |
H7A | 0.686 (3) | 1.053 (3) | 1.0003 (19) | 0.075 (10)* | |
H2B | 1.033 (4) | 0.817 (3) | 0.890 (3) | 0.127 (16)* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Mn | 0.0301 (2) | 0.0432 (2) | 0.0303 (2) | −0.00304 (15) | 0.01285 (15) | −0.00283 (14) |
O1 | 0.0374 (10) | 0.0698 (12) | 0.0308 (9) | −0.0105 (8) | 0.0139 (7) | −0.0052 (8) |
O2 | 0.0300 (9) | 0.0533 (10) | 0.0344 (9) | −0.0061 (7) | 0.0141 (7) | −0.0086 (7) |
O3 | 0.0332 (10) | 0.0598 (11) | 0.0488 (10) | −0.0068 (8) | 0.0181 (8) | −0.0108 (8) |
O4 | 0.0317 (9) | 0.0529 (10) | 0.0324 (9) | 0.0045 (7) | 0.0101 (7) | −0.0030 (7) |
O5 | 0.0336 (9) | 0.0536 (10) | 0.0427 (10) | −0.0013 (7) | 0.0178 (8) | 0.0040 (7) |
O6 | 0.0390 (11) | 0.0579 (11) | 0.0854 (15) | 0.0042 (9) | 0.0361 (10) | 0.0076 (10) |
O7 | 0.0470 (12) | 0.0447 (11) | 0.0794 (14) | −0.0085 (9) | 0.0339 (11) | −0.0129 (9) |
C1 | 0.0417 (14) | 0.0361 (12) | 0.0301 (12) | 0.0011 (10) | 0.0073 (10) | 0.0003 (9) |
C2 | 0.0513 (17) | 0.0554 (16) | 0.0327 (13) | −0.0029 (12) | 0.0126 (12) | 0.0002 (11) |
C3 | 0.070 (2) | 0.0631 (18) | 0.0251 (12) | −0.0018 (14) | 0.0047 (13) | −0.0017 (11) |
C4 | 0.0535 (19) | 0.0618 (18) | 0.0403 (15) | −0.0108 (13) | −0.0040 (13) | 0.0004 (12) |
C5 | 0.0364 (14) | 0.0468 (14) | 0.0455 (15) | −0.0038 (11) | 0.0055 (11) | 0.0023 (11) |
C6 | 0.0359 (13) | 0.0327 (12) | 0.0336 (12) | 0.0009 (9) | 0.0076 (10) | 0.0023 (9) |
C7 | 0.0305 (12) | 0.0301 (11) | 0.0393 (13) | 0.0003 (9) | 0.0126 (10) | −0.0008 (9) |
C8 | 0.0348 (13) | 0.0357 (12) | 0.0356 (13) | −0.0052 (10) | 0.0045 (10) | −0.0024 (9) |
C9 | 0.0478 (17) | 0.0616 (17) | 0.0360 (14) | 0.0000 (12) | 0.0093 (12) | 0.0005 (11) |
C10 | 0.062 (2) | 0.076 (2) | 0.0396 (15) | 0.0053 (15) | 0.0018 (14) | 0.0043 (13) |
C11 | 0.0500 (19) | 0.0692 (19) | 0.0546 (18) | 0.0062 (15) | −0.0097 (14) | 0.0070 (15) |
C12 | 0.0356 (15) | 0.0478 (15) | 0.0692 (19) | 0.0007 (11) | 0.0088 (13) | −0.0008 (13) |
C13 | 0.0320 (13) | 0.0330 (12) | 0.0469 (14) | −0.0036 (9) | 0.0086 (11) | −0.0005 (10) |
C14 | 0.0346 (13) | 0.0305 (12) | 0.0570 (16) | −0.0022 (9) | 0.0188 (12) | −0.0023 (10) |
C15 | 0.0412 (15) | 0.0529 (16) | 0.0535 (16) | −0.0019 (12) | 0.0138 (13) | 0.0001 (12) |
C16 | 0.0526 (18) | 0.0515 (17) | 0.0655 (19) | −0.0111 (13) | 0.0167 (15) | 0.0068 (13) |
C17 | 0.067 (2) | 0.0420 (15) | 0.0549 (18) | −0.0033 (13) | 0.0096 (15) | 0.0006 (12) |
C18 | 0.065 (2) | 0.0502 (17) | 0.0613 (18) | 0.0067 (13) | 0.0252 (16) | 0.0001 (13) |
C19 | 0.0553 (18) | 0.0456 (15) | 0.0513 (16) | −0.0026 (12) | 0.0194 (14) | 0.0032 (12) |
C20 | 0.059 (2) | 0.0655 (19) | 0.0599 (19) | 0.0000 (14) | 0.0195 (16) | 0.0086 (14) |
C21 | 0.072 (2) | 0.071 (2) | 0.066 (2) | 0.0186 (17) | 0.0398 (18) | 0.0157 (16) |
C22 | 0.094 (3) | 0.0613 (18) | 0.0424 (16) | 0.0114 (17) | 0.0290 (17) | −0.0040 (13) |
C23 | 0.066 (2) | 0.073 (2) | 0.0567 (19) | −0.0052 (16) | 0.0069 (17) | 0.0001 (15) |
C24 | 0.060 (2) | 0.071 (2) | 0.0579 (19) | 0.0125 (16) | 0.0321 (16) | 0.0157 (15) |
N1 | 0.0386 (12) | 0.0439 (12) | 0.0366 (11) | −0.0012 (9) | 0.0066 (9) | 0.0016 (8) |
N2 | 0.0702 (19) | 0.0531 (14) | 0.0428 (13) | 0.0072 (12) | 0.0210 (13) | −0.0018 (10) |
Geometric parameters (Å, º) top
Mn—O4 | 1.8705 (16) | C9—H9A | 0.9500 |
Mn—O1 | 1.8800 (16) | C10—C11 | 1.382 (4) |
Mn—O5 | 1.9194 (16) | C10—H10A | 0.9500 |
Mn—O2 | 1.9294 (16) | C11—C12 | 1.368 (4) |
Mn—O2 | 1.9294 (16) | C11—H11A | 0.9500 |
Mn—O7 | 2.241 (2) | C12—C13 | 1.405 (4) |
Mn—N1 | 2.349 (2) | C12—H12A | 0.9500 |
O1—C1 | 1.328 (3) | C13—C14 | 1.477 (3) |
O2—C7 | 1.288 (3) | C15—N1 | 1.328 (3) |
O3—C7 | 1.247 (3) | C15—C16 | 1.375 (4) |
O4—C8 | 1.334 (3) | C15—H15A | 0.9500 |
O5—C14 | 1.293 (3) | C16—C17 | 1.370 (4) |
O6—C14 | 1.240 (3) | C16—H16A | 0.9500 |
O7—H7B | 0.90 (3) | C17—C18 | 1.367 (4) |
O7—H7A | 0.90 (3) | C17—H17A | 0.9500 |
C1—C6 | 1.405 (3) | C18—C19 | 1.378 (4) |
C1—C2 | 1.410 (3) | C18—H18A | 0.9500 |
C2—C3 | 1.368 (4) | C19—N1 | 1.327 (3) |
C2—H2A | 0.9500 | C19—H19A | 0.9500 |
C3—C4 | 1.384 (4) | C20—N2 | 1.336 (4) |
C3—H3A | 0.9500 | C20—C21 | 1.344 (4) |
C4—C5 | 1.376 (3) | C20—H20A | 0.9500 |
C4—H4A | 0.9500 | C21—C22 | 1.361 (5) |
C5—C6 | 1.407 (3) | C21—H21A | 0.9500 |
C5—H5A | 0.9500 | C22—C23 | 1.373 (4) |
C6—C7 | 1.475 (3) | C22—H22A | 0.9500 |
C7—O3 | 1.247 (3) | C23—C24 | 1.376 (4) |
C7—O2 | 1.288 (3) | C23—H23A | 0.9500 |
C8—C13 | 1.401 (3) | C24—N2 | 1.318 (4) |
C8—C9 | 1.406 (3) | C24—H24A | 0.9500 |
C9—C10 | 1.372 (4) | N2—H2B | 0.95 (4) |
| | | |
O4—Mn—O1 | 178.62 (7) | C9—C10—C11 | 121.1 (3) |
O4—Mn—O5 | 91.41 (7) | C9—C10—H10A | 119.4 |
O1—Mn—O5 | 89.93 (7) | C11—C10—H10A | 119.4 |
O4—Mn—O2 | 87.49 (7) | C12—C11—C10 | 119.0 (3) |
O1—Mn—O2 | 91.17 (7) | C12—C11—H11A | 120.5 |
O5—Mn—O2 | 178.85 (7) | C10—C11—H11A | 120.5 |
O4—Mn—O7 | 88.39 (7) | C11—C12—C13 | 121.7 (3) |
O1—Mn—O7 | 91.97 (8) | C11—C12—H12A | 119.2 |
O5—Mn—O7 | 89.68 (7) | C13—C12—H12A | 119.2 |
O2—Mn—O7 | 90.62 (7) | C8—C13—C12 | 119.1 (2) |
O4—Mn—N1 | 89.72 (7) | C8—C13—C14 | 122.9 (2) |
O1—Mn—N1 | 89.93 (7) | C12—C13—C14 | 117.9 (2) |
O5—Mn—N1 | 90.20 (7) | O6—C14—O5 | 120.6 (2) |
O2—Mn—N1 | 89.47 (7) | O6—C14—C13 | 119.6 (2) |
O7—Mn—N1 | 178.10 (7) | O5—C14—C13 | 119.7 (2) |
C1—O1—Mn | 126.20 (14) | N1—C15—C16 | 123.6 (3) |
C7—O2—Mn | 129.76 (14) | N1—C15—H15A | 118.2 |
C8—O4—Mn | 123.39 (14) | C16—C15—H15A | 118.2 |
C8—O4—H24A | 124.3 | C17—C16—C15 | 118.9 (3) |
Mn—O4—H24A | 108.9 | C17—C16—H16A | 120.5 |
C14—O5—Mn | 128.63 (15) | C15—C16—H16A | 120.5 |
Mn—O7—H7B | 118 (2) | C18—C17—C16 | 118.2 (3) |
Mn—O7—H7A | 117 (2) | C18—C17—H17A | 120.9 |
H7B—O7—H7A | 107 (3) | C16—C17—H17A | 120.9 |
O1—C1—C6 | 124.9 (2) | C17—C18—C19 | 119.3 (3) |
O1—C1—C2 | 116.9 (2) | C17—C18—H18A | 120.4 |
C6—C1—C2 | 118.2 (2) | C19—C18—H18A | 120.4 |
C3—C2—C1 | 120.9 (3) | N1—C19—C18 | 123.2 (3) |
C3—C2—H2A | 119.5 | N1—C19—H19A | 118.4 |
C1—C2—H2A | 119.5 | C18—C19—H19A | 118.4 |
C2—C3—C4 | 121.4 (2) | N2—C20—C21 | 119.9 (3) |
C2—C3—H3A | 119.3 | N2—C20—H20A | 120.0 |
C4—C3—H3A | 119.3 | C21—C20—H20A | 120.0 |
C5—C4—C3 | 118.6 (3) | C20—C21—C22 | 119.7 (3) |
C5—C4—H4A | 120.7 | C20—C21—H21A | 120.1 |
C3—C4—H4A | 120.7 | C22—C21—H21A | 120.1 |
C4—C5—C6 | 121.6 (3) | C21—C22—C23 | 119.8 (3) |
C4—C5—H5A | 119.2 | C21—C22—H22A | 120.1 |
C6—C5—H5A | 119.2 | C23—C22—H22A | 120.1 |
C1—C6—C5 | 119.2 (2) | C22—C23—C24 | 118.7 (3) |
C1—C6—C7 | 122.9 (2) | C22—C23—H23A | 120.6 |
C5—C6—C7 | 117.8 (2) | C24—C23—H23A | 120.6 |
O3—C7—O2 | 118.3 (2) | N2—C24—C23 | 119.5 (3) |
O3—C7—C6 | 121.4 (2) | N2—C24—H24A | 120.3 |
O2—C7—C6 | 120.3 (2) | C23—C24—H24A | 120.3 |
O4—C8—C13 | 124.1 (2) | C15—N1—C19 | 116.8 (2) |
O4—C8—C9 | 117.4 (2) | C15—N1—Mn | 121.18 (18) |
C13—C8—C9 | 118.5 (2) | C19—N1—Mn | 121.97 (17) |
C10—C9—C8 | 120.7 (3) | C24—N2—C20 | 122.3 (3) |
C10—C9—H9A | 119.6 | C24—N2—H2B | 121 (3) |
C8—C9—H9A | 119.6 | C20—N2—H2B | 117 (3) |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
O7—H7B···O3i | 0.90 (3) | 1.81 (3) | 2.706 (3) | 173 (3) |
O7—H7A···O6ii | 0.90 (3) | 1.77 (3) | 2.665 (3) | 170 (3) |
N2—H2B···O3 | 0.95 (4) | 1.84 (4) | 2.783 (3) | 172 (4) |
C24—H24A···O4 | 0.95 | 2.46 | 3.396 (3) | 167 |
C21—H21A···O1iii | 0.95 | 2.60 | 3.452 (3) | 150 |
Symmetry codes: (i) −x+2, −y+2, −z+2; (ii) −x+1, −y+2, −z+2; (iii) x+1/2, −y+3/2, z−1/2. |