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The title compound, bis(piperazine-1,4-diylium) bis(phenylphosphonato)-1[kappa]O,2:3[kappa]2O',4:5[kappa]2O'';1:2[kappa]2O,3:4[kappa]2O',5[kappa]O''- penta-[mu]-oxo-1:2[kappa]2O;1:5[kappa]2O;2:3[kappa]2O;3:4[kappa]2O;4:5[kappa]2O-decaoxo- 1[kappa]2O,2[kappa]2O,3[kappa]2O,4[kappa]2O,5[kappa]2O-pentamolybdenum(4-) dihydrate, (C4H12N2)2[Mo5O15(C6H5O3P)2].2H2O contains isolated five-unit rings of vertex- and edge-sharing distorted octahedral MoO6 units, doubly capped by PC6H5 entities (as [PO3C6H5]2- phenylphosphonate groups), to result in [(MoO3)5{(C6H5)PO3}2]4- {or [Mo5P2O21(C6H5)2]4-} anions. Doubly protonated piperazinium cations and water molecules complete the structure.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock mophen

hkl

Structure factor file (CIF format)
Contains datablock mophen

CCDC reference: 128857

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