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The structure of hexakis-[mu]-acetato-1:2[kappa]4O:O'; 2:3[kappa]4O:O'; 1:3[kappa]4O:O'-triaqua-1[kappa]O,2[kappa]O, 3[kappa]O-[mu]3-oxo-cobalt(II)diiron(III) dihydrate, [CoFe2O(C2H3O2)6(H2O)3].2H2O, is reported. The compound is isostructural with the related mixed-valence trinuclear iron(II,III,III) acetate-aqua complex, [Fe3O(C2H3O2)6(H2O)3].2H2O. The coordination geometries around the three metal atoms of the cobalt-iron complex are almost identical to those of the trinuclear iron complex, and the Co and Fe atoms cannot be distinguished.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks default, COFECH3

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 128343

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