[R-(R*,R*)]-(η5-Cyclopentadienyl)[1,2-phenylenebis(methylphenylphosphine-P)](1-phenylphosphirane-P)iron(II) Hexafluorophosphate

Pabel, M.; Willis, A.C.; Wild, S.B.

doi:10.1107/S0108270195011784

[R-(R,R)]-(⁵-Cyclopentadienyl)[1,2-phenylenebis(methylphenylphosphine-P)](1-phenylphosphirane-P)iron(II) Hexafluorophosphate

The title compound, [Fe(C₅H₅)(C₈H₉P)(C₂₀H₂₀P₂)]PF₆, was obtained by spontaneous resolution of the racemate from acetone/diethyl ether solution. The cationic piano-stool iron(II) complex exhibits pseudooctahedral coordination geometry, with Fe-P distances of 2.189 (3) and 2.178 (4) Å for the bidentate ligand, and 2.170 (3) Å for the phosphirane ligand. The bond parameters for the phosphirane ligand are in good agreement with those found for related complexes.

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[R-(R,R)]-(⁵-Cyclopentadienyl)[1,2-phenylenebis(methylphenylphosphine-P)](1-phenylphosphirane-P)iron(II) Hexafluorophosphate

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	Crystallographic Information File (CIF) Contains datablocks global, mxp6
	Structure factor file (CIF format) Supplementary material

[R-(R*,R*)]-(5-Cyclopentadienyl)[1,2-phenylenebis(methylphenylphosphine-P)](1-phenylphosphirane-P)iron(II) Hexafluorophosphate

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[R-(R,R)]-(⁵-Cyclopentadienyl)[1,2-phenylenebis(methylphenylphosphine-P)](1-phenylphosphirane-P)iron(II) Hexafluorophosphate