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metal-organic compounds
The title compound, [TiCl(C5H5)2(CH3O)], is a `bent metallocene' structural type typically found in Cp2MXY complexes. The Ti-O-C bond angle of 141.4 (3)° is significantly greater than the corresponding angle in the ethoxy analog, resulting in a shortened O-Ti bond and indicating a greater -character in the O-Ti bond of the title compound.