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The asymmetric unit of the title complex, [SbPc]I (Pc = C32H16N8), consists of an [SbPc]+ cation and an I- anion. A combination of ionic and acceptor-donor interactions links the [SbPc]I moieties to form pseudo dimers in the unit cell. The pseudo dimers are linked through I...H-Cbenzole hydrogen-bonded interactions to form a two-dimensional network. As a result of these interactions, the four Sb-Nisoindole bonds in the [SbPc]+ moiety are not equivalent and the symmetry of Sb-N core is only close to Cs.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock global

hkl

Structure factor file (CIF format)
Contains datablock sb

CCDC reference: 129901

-1

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