[Ph4P]2[Sb2S15]

Rijnberk, H.; Näther, C.; Schur, M.; Jeß, I.

doi:10.1107/S0108270198001188

[Ph₄P]₂[Sb₂S₁₅]

H. Rijnberk, C. Näther, M. Schur and I. Jeß

The reaction of antimony chloride, sulfur and tetraphenylphosphonium bromide in an aqueous ammonia solution under hydrothermal conditions yields orange crystals of bis(tetraphenylphosphonium) -sufido--tetrasulfido-S¹:S⁴-bis[(pentasulfido-S¹,S⁵)antimonate], [(C₆H₅)₄P]₂[Sb₂S₁₅]. The structure contains tricyclic molecular Sb₂S₁₅^2- anions built up of two distorted -trigonal bipyramidally coordinated antimony centres which are connected by two S_x^2- units (x = 1,4) and bound to an additional S₅^2- ligand.

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[Ph₄P]₂[Sb₂S₁₅]

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	Crystallographic Information File (CIF) Contains datablocks I, global
	Structure factor file (SHELXL table format) Supplementary material