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The structure of the title compound, K3[Co(CN)6], has been redetermined using four-circle diffractometer in order to provide accurate parameters for further study by ab initio quantum chemical methods. When viewed along the c axis, the structure forms a sinusoidal two-dimensional layer with one rectangle-like interlayer and one distorted square-like intralayer channels in the three-dimensional network.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks qa0043, global

fcf

Structure factor file (CIF format)
Contains datablock QA0043

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