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Trans-dibromobis(triphenylphosphine)palladium(II), [(C6H5)3P]2PdBr2 (1), crystalizes in the triclinic space group P-1. Trans-dichlorobis(triphenylphosphine)palladium(II), [(C6H5)3P]2PdCl2 (2) also crystalizes in the triclinic space group P-1. [(C6H5)3P]2PdBr2 is solvated with one THF molecule and has a square planar geometry with the bromide ligands coordinated in a trans configuration. [(C6H5)3P]2PdCl2 is solvated with two chloroform molecules and has a square planar geometry with the palladium, Pd1, residing on an inversion center.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks 1, 2, global

fcf

Structure factor file (CIF format)
Contains datablock 1

fcf

Structure factor file (CIF format)
Contains datablock 2

CCDC references: 128766; 128767

-1

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