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The reaction of an aqueous slurry of HgI2 and an acetone solution of (Et3S)I (molar ratio 1:2) gives the title compound, [(C2H5)3S]2[HgI4], which contains discrete pyramidal Et3S+ and tetrahedral HgI42- ions. The bond distances of the anion (Hg1-I1 and Hg1-I2) are 2.780 (1) and 2.790 (1) Å.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks os1033, global

sft

Structure factor file (SHELXL table format)
Supplementary material

CCDC reference: 130791

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