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In
trans-[Ir(C
6F
5){P(C
6F
5)(C
6H
5)
2}
2(CO)], the Ir-P and Ir-C distances are comparable to those of the triphenylphosphine analogue. F
F interactions appear to dominate the configuration, resulting in virtually eclipsed C
6F
5(Ir) and C
6F
5(P) rings.
Supporting information
| Crystallographic Information File (CIF) Contains datablocks lp9416, 24_3_98 |
| Structure factor file (CIF format) Contains datablock lp9416 |
CCDC reference: 130786
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