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The coordination geometry about the palladium(II) ion in [PdCl2{Ph2P(CH2)2NH2}] is distorted square planar. Individual atoms are displaced from the PdCl2PN coordination plane by no more than 0.094 Å, while in-plane distortion of the bond angles at the metal atom is more marked. The greater trans influence of phosphine over amine is reflected in the mean Pd-Cl bond lengths of 2.383, trans to P, and 2.293 Å, trans to N.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks I, PdPNCl2

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 129732

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