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metal-organic compounds
The Mn atom in [Mn(C11H15N7S2)(H2O)2](ClO4)2 is in a distorted pentagonal bipyramidal environment with three N and two S atoms of the open-chain ligand forming the pentagonal girdle and O atoms of the water molecules occupying the apical positions. The ClO4- ions are involved in hydrogen bonding with the H2O molecules and with the terminal amino groups of the ligand [3.002 (5) and 2.962 (8) Å].