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The structures of the zinc and cadmium complexes of 4-acyl-3-methyl-1-phenyl-5-pyrazolones, [Zn(C18H23N2O2)2(H2O)] and [Cd(C28H43N2O2)2(C2H6O)2], show remarkable differences. In the case of zinc the coordination number is five and a square pyramidal structure was found, which is realised by the coordination of one molecule of water in the apical position. The coordination polyhedron is significantly distorted towards a trigonal-bipyramidal arrangement. The cadmium compound contains two coordinated ethanol molecules and is octahedral.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks zncdpyr, znpyr, cdpyr

hkl

Structure factor file (CIF format)
Contains datablock znpyr

hkl

Structure factor file (CIF format)
Contains datablock cdmpsp

CCDC references: 130095; 130096

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