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The crystal and molecular structure of the title compound, [CoCl2(C14H32N4)]ClO4, has been determined. The CoIII ion is six-coordinate with a distorted octahedral geometry consisting of the four N atoms of the macrocyclic ligand in equatorial positions and the two Cl atoms in axial positions. The quadridentate macrocyclic ligand adopts its most stable configuration, with two six-membered rings in chair conformations and two five-membered rings in gauche forms.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks I, global

hkl

Structure factor file (CIF format)
Contains datablock n1162

CCDC reference: 130093

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