Chloro{2-[2-(dimethylamino)ethyliminomethyl]phenol}triphenyltin(IV) Benzene Hemisolvate, [SnCl(C6H5)3(C11H16N2O)].0.5C6H6

Hazell, A.; Hu, H.; Khoo, L.E.

doi:10.1107/S0108270195014107

Chloro{2-[2-(dimethylamino)ethyliminomethyl]phenol}triphenyltin(IV) Benzene Hemisolvate, [SnCl(C₆H₅)₃(C₁₁H₁₆N₂O)].0.5C₆H₆

The coordination geometry of the Sn atom in the title compound is trigonal bipyramid, with the ipso C atoms of the phenyl groups in equatorial and the Cl and O atoms in apical positions. The ligand is bonded to the Sn atom through the phenolic O atom; the hydroxy H atom is shifted towards the imino N atom to give rise to a zwitterion, i.e. 2-[2-(dimethylamino)ethyliminiomethyl]phenolate.

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Chloro{2-[2-(dimethylamino)ethyliminomethyl]phenol}triphenyltin(IV) Benzene Hemisolvate, [SnCl(C₆H₅)₃(C₁₁H₁₆N₂O)].0.5C₆H₆

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