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We have synthesized and characterized five new chlorochromate(VI) complexes of organic bases: 4,4′-bipyridinium bis[chlorochromate(VI)], (C10H10N2)[CrO3Cl]2, 4-methylquinolinium chlorochromate(VI), (C10H10N)[CrO3Cl], 6-methylquinolinium chlorochromate(VI), (C10H10N)[CrO3Cl], N,N'-ethylenediaminium chloride chlorochromate(VI), (C2H10N2)(Cl)[CrO3Cl] and (5-chloro-2-pyridyl)(2-pyridyl)aminium chlorochromate(VI), (C10H9ClN3)[CrO3Cl]. The crystal and molecular structures of these compounds have been determined by X-ray crystallography and show that organic cations are bound to [CrO3Cl] anions by significant N...O and C...O hydrogen-bonding interactions.

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Contains datablocks text, 1, 2, 3, 4, 5

CCDC references: 126838; 126839; 126840; 126841; 126842

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