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Single crystals of the new compounds CdLn[B5O10] (Ln = La3+, Sm3+, Eu3+) were obtained in a silver ampoule at 1073 K by using a B2O3 flux technique. The compounds are isotypic with CoSm[B5O10] and contain two-dimensional infinite [B5O10]5- ion chains. Three of five boron sites are tetrahedrally coordinated. Cd2+ occupies distorted CdO6 polyhedra while Ln3+ is tenfold coordinated by O atoms.
Supporting information
| Crystallographic Information File (CIF) Contains datablocks CdLa, CdSm, CdEu, global |
| Structure factor file (CIF format) Contains datablock cdla |
| Structure factor file (CIF format) Contains datablock cdsm |
| Structure factor file (CIF format) Contains datablock cdeu |
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