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The unit cell contains two crystallographically independent formula units, CH6N3+.C4HO4-, that are connected via a three-dimensional network of hydrogen bonds. Two crystallographically independent anion-cation chains are formed and arranged in two crystallographically independent layers and stacked along the b axis. The guanidine molecule accepts a proton from the squaric acid. Anions and cations are nearly planar. In the anions, the C-O and especially the C-C bond lengths differ significantly and the C-C-C angles deviate significantly from 90°.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock nic412

fcf

Structure factor file (CIF format)
Contains datablock nic412

CCDC reference: 128746

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