A Mixed Nickel–Lithium Pyrophosphate, LiNi1.5P2O7

Rissouli, K.; Benkhouja, K.; Sadel, A.; Bettach, M.; Zahir, M.; Giorgi, M.; Pierrot, M.

doi:10.1107/S0108270196002739

A Mixed Nickel-Lithium Pyrophosphate, LiNi_1.5P₂O₇

K. Rissouli, K. Benkhouja, A. Sadel, M. Bettach, M. Zahir, M. Giorgi and M. Pierrot

The title compound, dilithium trinickel bis(diphosphate), is composed of [P₂O₇] layers parallel to the crystallographic plane (001), separated by chains of [NiO₆] octahedra. The coordination polyhedra of the Li⁺ ions link the [P₂O₇] groups and the [NiO₆] octahedra, and so ensure the cohesion of the structure.

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A Mixed Nickel-Lithium Pyrophosphate, LiNi_1.5P₂O₇

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A Mixed Nickel-Lithium Pyrophosphate, LiNi1.5P2O7

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A Mixed Nickel-Lithium Pyrophosphate, LiNi_1.5P₂O₇