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The structure of dicobalt(II) silicon bis[diphosphate(4-)], Co2Si(P2O7)2, consists of compressed CoO6 octahedra, SiO4 tetrahedra and P2O7 groups with a P-O-P angle of 132.3 (1)°. Co2O10 units built from two edge-sharing CoO6 octahedra are linked via four corners to other dimers thus forming a two-dimensional network parallel to the bc plane. These planes are separated by bands formed from diphosphate groups and SiO4 tetrahedra.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks cosipo, global

fcf

Structure factor file (CIF format)
Contains datablock cosipo

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