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The structure of the title compound, [Zn(C12H8N2)2(H2O)2][Zn(S2O3)2(C12H8N2)].H2O, consists of cationic [Zn(phen)2(H2O)2]2+ and anionic [Zn(phen)(S2O3)2]2- moieties. They are connected by hydrogen bonding into a three-dimensional network with the participation of a disordered solvant water molecule. The thiosulfate groups, one of which is disordered, are coordinated through sulfur. The phenanthroline groups coordinate as usual through both N atoms. One of them is planar, and the remaining two present a shallow-boat conformation.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, sb2

hkl

Structure factor file (CIF format)
Contains datablock tmp

CCDC reference: 126567

-1

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