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In the past, crystal structure determination of solids consisting of molecules (or atom groups) whose geometry and size are known approximately has often been attempted using neutron powder diffraction profile refinement techniques, but without inclusion of this information. A method of structure solution has therefore been developed to include it. The proposed method does not require a set of structure factors and thus avoids the problems encountered in separating peaks in a powder diffraction scan. A successful test was conducted with a previously determined (yet treated as unknown) crystal structure, where direct methods had failed to solve the structure due to incorrect peak separation. Two computer programs, MODEL and PARAM, that implement the method are described.